A review of functional group selection and design strategies for gel polymer electrolytes for metal batteries

Materials Science and Engineering R Reports, Год журнала: 2025, Номер 164, С. 100973 - 100973

Опубликована: Март 9, 2025

Язык: Английский

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Covalent organic frameworks for high-performance rechargeable lithium metal batteries: Strategy, mechanism, and application

Progress in Materials Science, Год журнала: 2025, Номер unknown, С. 101455 - 101455

Опубликована: Фев. 1, 2025

Язык: Английский

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A Solvent-Induced Solid Polymer Electrolyte with Controllable Polymerization for Low-Temperature Lithium Metal Batteries

Nano Letters, Год журнала: 2025, Номер unknown

Опубликована: Март 24, 2025

Solid-state electrolytes based on in situ ring-opening polymerization of 1,3-dioxolane (DOL) have attracted widespread attention Li metal batteries because their high interface compatibility. However, its conventional cationic mechanism frequently results the formation long polymer chains during polymerization, thereby impeding Li+ transport. Here, we regulate ring opening DOL by introducing N,N-dimethyltrifluoroacetamide (FDMA), thus avoiding chains. Meanwhile, FDMA can derive a stable SEI rich LiF electrochemical cycling, improving stability and suppressing dendritic growth. Therefore, full battery with LiFePO4 as cathode achieve capacity retention rate 83.9% after 400 cycles at 5.0 C. At -20 °C, Li∥LiFePO4 provide 137 mAh g-1. The solvent-induced strategy provides promising new avenue for designing solid electrolyte temperature resistance.

Язык: Английский

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A Novel Orientation Aliphatic Ketone‐Based Liquid Crystal Polymer Electrolyte for High‐Voltage Solid‐State Lithium Metal Batteries

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Март 20, 2025

Abstract Low room temperature ionic conductivity and interfacial incompatibility severely hinder the further application of polymer electrolytes in lithium metal batteries. Here, a novel shear‐oriented (SO) aliphatic ketone‐carbonyl‐based liquid crystal composite solid electrolyte (FL 7 M 3 @CSPE SO ) is prepared by situ thermal‐polymerization monomer (FPZ‐LC, FL) N, N' ‐Methylenebisacrylamide (MBA, M) on cellulose nanofiber (CNF) presence triethylene‐glycol‐dimethyl‐ether (G salt (lithium bis(trifluoromethanesulphonyl)imide, LiTFSI). The high polarity keto‐carbonyl groups improves dissociation ability salt. highly oriented crystals provide rapid ion transport channels. Thus, FL achieves 10 −4 S cm −1 lithium‐ion transference number (t Li+ 0.52 at 30 °C. Besides, formed stable interface layer effectively inhibits growth dendrites. assembled Li/FL /Li cells operate stably over 5500 h 0.05 mA −2 (30 °C). Impressively, /NCM811 exhibits long‐term cycle 1200 with capacity retention 92% under C 4.4 V (−5 This work not only highlights advantages improving capacity, but also provides design strategy for advanced suitable lower high‐voltage solid‐state

Язык: Английский

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Application of Polymer Electrolytes Prepared by Ultraviolet Polymerization in Various Lithium Metal Battery Systems

ACS Applied Energy Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 30, 2025

Язык: Английский

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Janus Solid Electrolyte with Ionic and Electronic Dual Conductive Face Guiding Lithium Deposition Oriental To Connect with Lithium Metal Anode

ACS Energy Letters, Год журнала: 2025, Номер unknown, С. 2679 - 2688

Опубликована: Май 9, 2025

Язык: Английский

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Contriving molecular configuration to realize a bidirectionally stable quasi-solid polymer electrolyte for high-voltage Li metal batteries

Chemical Engineering Journal, Год журнала: 2025, Номер 516, С. 163968 - 163968

Опубликована: Май 19, 2025

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Hydrogen‐Bonded Organic Frameworks (HOFs) Composite Polymer Electrolyte Enables the Stable Long‐Term Cycling of Lithium Metal Batteries with High‐Voltage Cathode

Small, Год журнала: 2025, Номер unknown

Опубликована: Май 19, 2025

Abstract Solid‐state lithium batteries have attracted significant interest due to their potential enhance the safety and energy density of modern storage systems. However, challenges such as low ionic conductivity poor interfacial compatibility hindered widespread adoption. In this study, a novel hydrogen‐bonded organic framework (HOF) composite polymer electrolyte (HCPG@SPE) is developed by integrating trimesic acid melamine‐based HOFs with natural matrix composed gelatin chitosan. The hydrogen‐bonding interactions between HOF in HCPG@SPE impart remarkable mechanical strength thermal stability. Additionally, weak lithium‐ions, its anion adsorption capacity, effectively generates more free facilitating migration while inhibiting movement. Electrochemical tests revealed that exhibited high (5.74 × 10⁻ 3 S cm⁻¹ at 30 °C), favorable lithium‐ion transference number (0.71), an extended electrochemical stability window (5.4 V). metal utilizing achieved outstanding performance, LFP| HCPG@SPE| Li cells retaining 98% capacity after 1000 cycles 5 C, NCM811| demonstrating stable cycling for 700 1 C. results suggest HOF‐based holds promise next‐generation high‐performance solid‐state batteries.

Язык: Английский

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Nanofiber connected metal organic frameworks adsorption membrane to enhance Li+ conduction and alleviate interfacial side reaction for solid electrolyte

Chemical Engineering Journal, Год журнала: 2024, Номер unknown, С. 157701 - 157701

Опубликована: Ноя. 1, 2024

Язык: Английский

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