Thermodynamics of the cyanation reaction of octyl alcohol with ammonia DOI

Tohirjon Anvarov,

Kadir Murodov,

Dilafruz Muradova

и другие.

AIP conference proceedings, Год журнала: 2024, Номер 3244, С. 050009 - 050009

Опубликована: Янв. 1, 2024

Язык: Английский

Cathodic tandem alkylation/dearomatization of heterocycles enabled by Al-facilitated carbonyl deoxygenation DOI Creative Commons
Jinhui Hu,

Weijie Deng,

Jianfeng Zhou

и другие.

Nature Communications, Год журнала: 2025, Номер 16(1)

Опубликована: Янв. 25, 2025

Язык: Английский

Процитировано

0
Dearomatization of Aromatic Compounds: A Decade Review DOI
Jianmin Chen, Wenhao Zhang, Dayun Huang

и другие.

Asian Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Май 28, 2025

Abstract Dearomatization offers an efficient strategy for directly converting arenes into cyclic molecules. In this review, we discuss representative examples of dearomatization reactions through five modes: (1) radical dearomatization, (2) halofunctionalization‐dearomatization, in which three‐membered intermediates were frequently involved, (3) nucleophilic mainly about electron‐rich arenes, (4) oxidative and (5) reductive dearomatization. Compared to heteroarenes, simple benzene are more challenging participate reactions. recent years, fewer reports have focused on benzene. Heteroarenes, inherently or easily activated, tend undergo readily. This review highlights a decade progress including indoles, benzofurans, benzothiophenes, thiophenes, furans, naphthols, naphthalenes, quinolines, pyridines, nitrobenzenes, benzenes. It also analyzes their mechanisms strategies. We hope will aid future research field.

Язык: Английский

Процитировано

0
Advances in Electrochemical Reactions Involving Acetonitrile DOI

Yongqun Mei,

Pei Liao,

Yunfei Zhang

и другие.

Organic & Biomolecular Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

Acetonitrile serves dual roles as both a versatile organic solvent and an active reactant in electrochemical synthesis, functioning carbon or nitrogen source to access amides, nitrogen-containing heterocycles, other high-value derivatives. This review systematically classifies acetonitrile transformations by bond-forming patterns (C-C, C-N, C-S, cyclizations) mechanistic pathways, while highlighting the pivotal role of redox mediators-including organocatalysts, metal catalysts, photoelectrocatalysts-in enabling these processes. Future advances will necessitate innovative electrocatalytic systems advance application functionalization inert alkanes, enantioselective green production pharmaceutical intermediates, particularly addressing challenges regioselectivity over-oxidation. Resolving gaps foster interdisciplinary sustainable chemistry drug discovery.

Язык: Английский

Процитировано

0
Identification of Ni3Fe Alloy as a Candidate Catalyst for Quinoline Selective Hydrogenation with Computations DOI
Zhaochun He, Y.H. Liu, Tao Wang

и другие.

Catalysis Science & Technology, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

We computationally identified Ni 3 Fe as a promising catalyst for the quinoline (QL) selective hydrogenation to 1,2,3,4-tetrahydroquinoline (py-THQL) using density functional theory calculations and microkinetic modeling.

Язык: Английский

Процитировано

0
To cyclize or not? Synthesis of heterocycles through electro-oxidation of N,N-$$\hbox {dimethylaniline}^\dag$$ DOI

Marimuthu Lakshmipriya,

Bommireddy Naveen,

Subramaniyan Prasanna Kumari

и другие.

Chemical Papers, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 21, 2024

Язык: Английский

Процитировано

0
Thermodynamics of the cyanation reaction of octyl alcohol with ammonia DOI

Tohirjon Anvarov,

Kadir Murodov,

Dilafruz Muradova

и другие.

AIP conference proceedings, Год журнала: 2024, Номер 3244, С. 050009 - 050009

Опубликована: Янв. 1, 2024

Язык: Английский

Процитировано

0