Photoinduced Vicinal Sulfamoyloximation of Alkenes: Harnessing Bifunctional Nitrosamines via a Rapid Radical Trapping Strategy
Wei Li,
Chenchen Diao,
Yilian Lu
и другие.
Organic Letters,
Год журнала:
2024,
Номер
26(29), С. 6253 - 6258
Опубликована: Июль 17, 2024
We
developed
a
photoinduced
method
for
vicinal
sulfamoyloximation
of
alkenes
using
Язык: Английский
Visible-light-induced photocatalyst- and metal-free radical phosphinoyloximation of alkenes with tert-butyl nitrite as bifunctional reagent
Chinese Chemical Letters,
Год журнала:
2024,
Номер
unknown, С. 110425 - 110425
Опубликована: Окт. 1, 2024
Язык: Английский
C(sp3)—H Bond Oximinylation
Acta Chimica Sinica,
Год журнала:
2025,
Номер
83(4), С. 390 - 390
Опубликована: Янв. 1, 2025
Язык: Английский
Photosensitized Imino-Sulfamoylation of Alkenes with Oxime Carbamates
Ai-Lian Wang,
Huan-Huan Zhao,
Haowen Jiang
и другие.
Organic Letters,
Год журнала:
2025,
Номер
unknown
Опубликована: Май 1, 2025
In
this
study,
we
have
devised
a
strategy
that
employs
oxime
carbamate
as
bifunctional
diamination
reagent
in
combination
with
SO2
to
realize
imino-sulfamoylation
of
alkenes.
This
protocol
is
characterized
by
its
mild
conditions,
operational
simplicity,
and
metal-free
nature,
while
demonstrating
broad
functional
group
tolerance
for
Furthermore,
the
application
method
provides
an
accessible
route
diverse
range
β-amino
sulfonamide
derivatives.
Язык: Английский
Direct vicinal sulfonyloximation of alkenes: an efficient and straightforward approach towards the synthesis of α-sulfonyl ketoximes
RSC Advances,
Год журнала:
2025,
Номер
15(22), С. 17174 - 17185
Опубликована: Янв. 1, 2025
Direct
vicinal
sulfonylative
difunctionalization
of
simple
alkenes
represents
a
powerful
strategy
for
the
rapid
assembly
β-functionalized
sulfones
from
starting
materials.
Язык: Английский
Reactivity Tuning for Selective Aldimino-Sulfonylation of Styrenes by Photocatalytic Activation of Sulfonyl Aldimines
The Journal of Organic Chemistry,
Год журнала:
2025,
Номер
unknown
Опубликована: Май 31, 2025
Imino-sulfonylation
of
styrene
represents
a
powerful
method
for
constructing
highly
functionalized
molecules,
while
only
diphenyl
imines
were
able
to
be
employed
in
previous
reports.
By
modulating
the
electron
property
styrene,
visible-light-mediated
radical/radical
cross-coupling
aldiminyl
radical
and
carbon-centered
was
achieved
synthesize
diverse
aldimine-embedded
sulfones
by
using
sulfonyl
aldimines
α-trifluoromethylstyrenes.
One-pot
oxidation
delivered
Ritter-type
amidation
products
without
need
excessive
nitriles
as
solvent.
Furthermore,
this
protocol
took
advantage
simple
reaction
conditions,
good
substituent
diversity,
high
atom
economy
broaden
research
radicals
amination
alkenes.
Язык: Английский
DABCO‐Mediated Photoelectrochemical Three‐Component Sulfonocyclization of 3‐Aza‐1,5‐dienes
Lu-Cai Ding,
Gui-Hong Yang,
Li Luo
и другие.
Chinese Journal of Chemistry,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 2, 2024
Comprehensive
Summary
Herein,
we
report
a
rare
example
of
three‐component
net‐oxidative
sulfonylation
SO
2
surrogate
with
an
oxidatively
activated
radical
precursor
under
mild
and
metal‐
external‐oxidant‐free
conditions.
The
mildness
sustainability
the
reaction
are
enabled
by
photoelectrocatalysis,
3‐aza‐1,5‐dienes,
organotrifluoroborates
1,4‐diazabicyclo[2.2.2]octane
bis(sulfur
dioxide)
adduct
(DABSO)
undergo
sulfonylative
cyclization
to
afford
sulfono
4‐pyrrolin‐2‐ones
in
atom‐economical
manner
broad
substrate
scope
good
functional‐group
tolerance.
protocol
is
amenable
late‐stage
diversification
complex
molecular
architectures
as
well
gram‐scale
synthesis.
Sunlight
could
be
used
light
source,
conducted
all‐solar
mode
using
commercially
available
photovoltaic
panel
generate
electricity
situ
.
Mechanistic
studies
reveal
that
generated
(DABCO),
which
was
generally
innocent
previous
reactions,
functions
electron
shuttle
between
photocatalytic
cycle
reactants.
Язык: Английский
Visible Light-Driven Interrupted Barton Reaction: Intermolecular Radical-Relay Sulfonyloximation of Alkenes with DABSO and Alkyl Nitrites
Organic Letters,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 24, 2024
A
visible
light-driven,
intermolecular
interrupted
Barton
reaction
has
been
developed
for
radical-relay
sulfonyloximation
of
alkenes
with
alkyl
nitrites,
using
DABSO
as
a
trapping
reagent.
This
method
overcomes
the
challenges
competing
normal
reactions
and
polarity
mismatches
by
rapidly
irreversibly
capturing
radicals,
preventing
unwanted
side
reactions.
The
resulting
polarity-reversed
sulfonyl
radicals
undergo
highly
selective
addition
to
alkenes,
yielding
α-alkylsulfonyl
ketoximes
tethered
hydroxyl
or
ketone
groups.
Conducted
under
mild
light
conditions,
this
approach
eliminates
need
harsh
mercury
lamps,
offering
scalable,
chemoselective
synthesizing
valuable
sulfonylated
oxime
derivatives.
Язык: Английский