Iron-Photocatalyzed Decarboxylative Alkylation of Carboxylic Acids with Morita–Baylis–Hillman Acetates DOI
Yanli Yin, Fang Chen, Dong Chen

и другие.

Organic Letters, Год журнала: 2024, Номер unknown

Опубликована: Дек. 27, 2024

We present an iron-photocatalyzed decarboxylative alkylation strategy involving carboxylic acids and Morita–Baylis–Hillman (MBH) acetates to synthesize E-type tri- tetrasubstituted alkenes with moderate excellent stereoselectivity (E/Z ratio up >19:1). This method is applicable a broad range of structurally diverse primary, secondary, tertiary alkyl acids, as well complex pharmaceutical natural achieving efficient various MBH under mild conditions (>60 examples, yields 96%). approach offers powerful for streamlined alkylation.

Язык: Английский

Harnessing Nitroarenes: Photo-Driven Synergistic Construction of Phosphinic Amides via Hydrogen Transfer and Oxygen Migration DOI
Bin Sun,

Zhaokang Zhang,

Xiaohui Zhuang

и другие.

Chemical Communications, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

A method for synthesizing phosphinic amides via hydrogen transfer and oxygen migration through an EDA complex-based cascade reaction is presented.

Язык: Английский

Процитировано

0
Iron-Photocatalyzed Decarboxylative Alkylation of Carboxylic Acids with Morita–Baylis–Hillman Acetates DOI
Yanli Yin, Fang Chen, Dong Chen

и другие.

Organic Letters, Год журнала: 2024, Номер unknown

Опубликована: Дек. 27, 2024

We present an iron-photocatalyzed decarboxylative alkylation strategy involving carboxylic acids and Morita–Baylis–Hillman (MBH) acetates to synthesize E-type tri- tetrasubstituted alkenes with moderate excellent stereoselectivity (E/Z ratio up >19:1). This method is applicable a broad range of structurally diverse primary, secondary, tertiary alkyl acids, as well complex pharmaceutical natural achieving efficient various MBH under mild conditions (>60 examples, yields 96%). approach offers powerful for streamlined alkylation.

Язык: Английский

Процитировано

0