Harnessing Nitroarenes: Photo-Driven Synergistic Construction of Phosphinic Amides via Hydrogen Transfer and Oxygen Migration
Bin Sun,
Zhaokang Zhang,
Xiaohui Zhuang
и другие.
Chemical Communications,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
A
method
for
synthesizing
phosphinic
amides
via
hydrogen
transfer
and
oxygen
migration
through
an
EDA
complex-based
cascade
reaction
is
presented.
Язык: Английский
Photo-induced decarboxylative radical cascade cyclization of unactivated alkenes: access to CF- and CF2-substituted ring-fused imidazoles
RSC Advances,
Год журнала:
2025,
Номер
15(16), С. 12739 - 12745
Опубликована: Янв. 1, 2025
A
mild
and
effective
visible-light-induced
decarboxylative
radical
cascade
reaction
of
olefin-containing
imidazoles
α-fluorinated
carboxylic
acids,
has
been
developed
to
afford
monofluoromethylated
or
aryldifluoromethylated
polycyclic
imidazoles.
Язык: Английский
Iron-Photocatalyzed Decarboxylative Alkylation of Carboxylic Acids with Morita–Baylis–Hillman Acetates
Organic Letters,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 27, 2024
We
present
an
iron-photocatalyzed
decarboxylative
alkylation
strategy
involving
carboxylic
acids
and
Morita–Baylis–Hillman
(MBH)
acetates
to
synthesize
E-type
tri-
tetrasubstituted
alkenes
with
moderate
excellent
stereoselectivity
(E/Z
ratio
up
>19:1).
This
method
is
applicable
a
broad
range
of
structurally
diverse
primary,
secondary,
tertiary
alkyl
acids,
as
well
complex
pharmaceutical
natural
achieving
efficient
various
MBH
under
mild
conditions
(>60
examples,
yields
96%).
approach
offers
powerful
for
streamlined
alkylation.
Язык: Английский