Catalysis Science & Technology,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 10, 2024
This
study
reports
the
conversion
of
CO
2
and
H
to
O
at
low
temperature
pressure
(up
203
°C,
p
=
3.5
bar)
using
plasmonic
Au/CeO
2−
x
photocatalysts,
with
mildly
concentrated
sunlight
as
sole
energy
source
9
kW
m
−2
).
Abstract
Pure
CeO
2
and
Ce
1‐x
Mn
x
O
,
where
=
0,
2,
4
6%
w/w,
were
synthesized
by
sol‐gel
method
using
Acacia
Concinna
fruit
extract
as
a
surfactant
stabilizing
agent.
The
particles
subjected
to
various
characterization
techniques,
including
XRD,
HRTEM,
FESEM,
FTIR,
Raman
UV‐Visible
spectroscopy.
XRD
pattern
of
the
samples
demonstrated
single
phase
with
cubic
fluorite
type
structure
crystallite
size
6–7
nm.
morphology
nanoparticles
(NPs)
was
analyzed
FESEM
HRTEM
which
illustrated
an
aggregate
irregular
spherical
average
particle
is
around
18
spectroscopy
validated
purity
indicated
about
structural
defects
caused
dopants.
bandgap
energy
NPs
calculated
be
3.00
eV
from
Tauc
plot
spectroscopy,
gradually
decreased
2.43
increase
in
manganese
doping.
Cytotoxicity
studies
signified
role
Mn‐doped
potential
nanotherapeutic
agent
for
cancer
treatment.
cell
viability
assay
showed
that
200
µg/mL
exhibited
remarkable
cytotoxic
effect
inhibiting
50%
cells
both
breast
colon
lines
without
affecting
healthy
lines.
Catalysis Science & Technology,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 10, 2024
This
study
reports
the
conversion
of
CO
2
and
H
to
O
at
low
temperature
pressure
(up
203
°C,
p
=
3.5
bar)
using
plasmonic
Au/CeO
2−
x
photocatalysts,
with
mildly
concentrated
sunlight
as
sole
energy
source
9
kW
m
−2
).