Energy Conversion and Management, Год журнала: 2024, Номер 321, С. 119069 - 119069
Опубликована: Сен. 24, 2024
Язык: Английский
Energy Conversion and Management, Год журнала: 2024, Номер 321, С. 119069 - 119069
Опубликована: Сен. 24, 2024
Язык: Английский
Journal of Applied Electrochemistry, Год журнала: 2025, Номер unknown
Опубликована: Март 18, 2025
Язык: Английский
Процитировано
0ChemElectroChem, Год журнала: 2025, Номер unknown
Опубликована: Март 30, 2025
In energy conversion technologies, the electron spin effect in catalysts plays a crucial role overcoming spin‐forbidden reactions, offering novel approach to overcome performance bottlenecks of catalysts. Recently, with breakthroughs magnetic field–enhanced catalysis and theoretical predictions, significant progress has been made design development this concept, several attractive inspiring catalyst strategies reported recently, particularly precise modulation states/spin interactions at catalytic sites through coordination modulation, spin‐pinning effect, chirality induction, radical adsorption, are outlined. The concept then explores advantages these enhancing activity/selectivity, investigating selectivity reaction pathways, expanding systems. Finally, proposes future directions for technologies.
Язык: Английский
Процитировано
0Journal of the American Chemical Society, Год журнала: 2025, Номер unknown
Опубликована: Апрель 12, 2025
Manipulating the spin ordering of oxygen evolution reaction (OER) catalysts through magnetization has recently emerged as a promising strategy to enhance performance. Despite numerous experiments elaborating on magnetic effect for improved OER, origin this phenomenon remains largely unexplored, primarily due difficulty in directly distinguishing states electrocatalysts during chemical reactions at atomic level. X-ray emission spectroscopy (XES), which provides information sensitive specific elements complex, may serve technique differentiate onset OER catalytic activities from influence states. In work, we employ situ XES technique, along with absorption (XAS), investigate interplay between atomic/electronic structures, states, and CoFe2O4 (CFO) catalyst under an external field. This enhancement is that facilitates spin-selective electron transfer adsorbed OH- reactants, strongly depends configurations tetrahedral-(Td) octahedral-(Oh) sites both Fe Co ions. Our result contributes comprehensive understanding field-assisted electrocatalysis level paves way designing highly efficient catalysts.
Язык: Английский
Процитировано
0ACS Applied Energy Materials, Год журнала: 2025, Номер unknown
Опубликована: Апрель 15, 2025
Язык: Английский
Процитировано
0Energy Conversion and Management, Год журнала: 2024, Номер 321, С. 119069 - 119069
Опубликована: Сен. 24, 2024
Язык: Английский
Процитировано
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