Transition-metal-free phosphorylation of polyfluoroarenes with P(O)H compounds

Organic & Biomolecular Chemistry, Год журнала: 2025, Номер 23(10), С. 2358 - 2361

Опубликована: Янв. 1, 2025

Herein, a base-promoted C-P(O) bond formation method has been developed for the phosphorylation of polyfluoroarenes through selective C-F cleavage. The high selectivity and mild, transition-metal-free conditions this underscore its potential sustainable synthesis applications. This expands scope polyfluoroarene functionalization, providing valuable tool incorporating phosphorus motifs in complex aromatic frameworks.

Язык: Английский

Investigation of the reaction of hexafluoro-1,4-naphthoquinone with substituted phenols

Journal of Fluorine Chemistry, Год журнала: 2025, Номер 282, С. 110402 - 110402

Опубликована: Фев. 1, 2025

Язык: Английский