Chemical Science,
Год журнала:
2024,
Номер
15(45), С. 18715 - 18750
Опубликована: Янв. 1, 2024
The
construction
of
functional
structures
within
a
single
plane
still
has
lot
challenges.
This
review
article
will
help
us
find
new
groundbreaking
directions
in
lateral
nanoarchitectonics
toward
advanced
material
organization.
Chemical Science,
Год журнала:
2024,
Номер
15(36), С. 14585 - 14607
Опубликована: Янв. 1, 2024
The
development
of
high-efficiency
atomic-level
catalysts
for
energy-conversion
and
-storage
technologies
is
crucial
to
address
energy
shortages.
spin
states
diatomic
(DACs)
are
closely
tied
their
catalytic
activity.
Adjusting
the
DACs'
active
centers
can
directly
modify
occupancy
d-orbitals,
thereby
influencing
bonding
strength
between
metal
sites
intermediates
as
well
transfer
during
electro
reactions.
Herein,
we
discuss
various
techniques
characterizing
atomic
strategies
modulating
center
states.
Next,
outline
recent
progress
in
study
effects
DACs
oxygen
reduction
reaction
(ORR),
evolution
(OER),
hydrogen
(HER),
electrocatalytic
nitrogen/nitrate
(eNRR/NO
Advanced Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Сен. 30, 2024
Abstract
Oxygen
electrocatalysis,
as
the
pivotal
circle
of
many
green
energy
technologies,
sets
off
a
worldwide
research
boom
in
full
swing,
while
its
large
kinetic
obstacles
require
remarkable
catalysts
to
break
through.
Here,
based
on
summarizing
reaction
mechanisms
and
situ
characterizations,
structure–activity
relationships
oxygen
electrocatalysts
are
emphatically
overviewed,
including
influence
geometric
morphology
chemical
structures
electrocatalytic
performances.
Subsequently,
experimental/theoretical
is
combined
with
device
applications
comprehensively
summarize
cutting‐edge
according
various
material
categories.
Finally,
future
challenges
forecasted
from
perspective
catalyst
development
applications,
favoring
researchers
promote
industrialization
electrocatalysis
at
an
early
date.
Advanced Functional Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Март 3, 2025
Abstract
Oxygen
electrocatalysis
is
a
core
reaction
in
renewable
energy
devices,
greatly
promoting
the
transformation
and
upgrading
of
structure.
Nonetheless,
performance
conversion
devices
hindered
by
large
overpotential
slow
kinetics
oxygen
electrocatalytic
reactions.
Recently,
single‐atom
catalysts
(SACs)
have
emerged
as
promising
contenders
field
because
their
exceptional
metal
atom
utilization,
distinctive
coordination
environment,
adjustable
electronic
properties.
This
review
presents
latest
advancements
design
Co‐based
SACs
for
electrocatalysis.
First,
OER
ORR
mechanisms
are
introduced.
Subsequently,
strategies
regulating
structure
summarized
three
aspects,
including
centers,
support
carriers.
A
particular
emphasis
given
to
relationship
between
properties
catalysts.
Afterward,
applications
explored.
Ultimately,
challenges
prospects
prospected.
Developing
efficient
and
sustainable
electrocatalysts
for
the
oxygen
evolution
reaction
(OER)
is
crucial
advancing
energy
conversion
storage
technologies.
3d
transition-metal
(oxy)hydroxides
spinel-type
oxides
have
emerged
as
promising
candidates
due
to
their
structural
flexibility,
redox
activity,
abundance
in
earth's
crust.
However,
OER
performance
can
be
changed
dynamically
during
surface
reconstruction
transformation.
Essentially,
multiple
elementary
processes
occur
simultaneously,
whereby
electrocatalyst
surfaces
undergo
substantial
changes
OER.
A
better
understanding
of
these
how
they
affect
electrocatalytic
essential
design.
This
review
aims
critically
assess
processes,
including
oxidation,
amorphization,
transformation,
cation
dissolution,
redeposition,
facet
electrolyte
effects
on
performance.
The
begins
with
an
overview
electrocatalysts'
structure,
couples,
common
issues
associated
electrochemical
measurements
spinels,
followed
by
recent
advancements
involved
challenges
new
perspectives
are
presented
at
last,
potentially
shedding
light
rational
design
next-generation
applications.