Chemical Reviews,
Год журнала:
2025,
Номер
unknown
Опубликована: Фев. 18, 2025
The
electrocatalytic
technique,
as
an
efficient
energy
storage
and
conversion
technology,
has
attracted
significant
attention
to
address
exhaustion
environmental
pollution.
Usually,
the
activity
selectivity
of
reactions
are
largely
dominated
by
dynamic
process
occurring
on
electrocatalysts.
Therefore,
high-performance
electrocatalysts,
which
can
dominate
pathway
barrier
reactions,
great
significance
for
advancement
technique.
Metal-organic
frameworks
(MOFs),
emerging
crystalline
porous
materials,
present
structural
component
advantages
including
well-defined
structure,
high
surface
area,
large
porosity,
diverse
components,
easy
tailorability,
demonstrating
fantastic
potential
precise
fabrication
In
this
Review,
strategies
in
electrocatalysts
based
MOF-related
materials
specifically
introduced
from
aspects
catalytic
site
design
microenvironment
modulation
around
sites.
Furthermore,
representative
progress
achieved
various
applications
employing
MOF-based
is
systematically
summarized,
with
special
emphasis
MOFs
performance
optimization.
Finally,
remaining
challenges
future
perspectives
further
highlighted.
Advanced Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Окт. 22, 2024
Abstract
Reconstruction
of
catalysts
is
now
well
recognized
as
a
common
phenomenon
in
electrocatalysis.
As
the
reconstructed
structure
may
promote
or
hamper
electrochemical
performance,
how
to
achieve
designed
active
surface
for
highly
enhanced
catalytic
activity
through
reconstruction
needs
be
carefully
investigated.
In
this
review,
genesis
and
effects
various
processes,
such
hydrogen
evolution
reaction
(HER),
oxygen
(OER),
carbon
dioxide
reduction
(CO
2
RR),
nitrate
(NO
3
RR)
are
first
described.
Then,
strategies
optimizing
reconstruction,
valence
states
control,
phase
retention,
engineering,
poisoning
prevention
comprehensively
discussed.
Finally,
general
rules
optimization
summarized
give
perspectives
future
study.
It
believed
that
review
shall
provide
deep
insights
into
electrocatalytic
mechanisms
guide
design
pre‐catalysts
with
improved
activity.
Journal of Materials Chemistry A,
Год журнала:
2024,
Номер
12(32), С. 20578 - 20605
Опубликована: Янв. 1, 2024
Molecular
engineering
of
MOF-based
electrocatalysts
for
the
CO
2
RR,
computational
simulations,
and
advanced
characterization
studies
are
discussed
summarized
to
illustrate
correlation
between
their
structure
performance.
Chemical Communications,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
Incorporating
crown
ether
into
Cu-based
MOFs
tailors
the
microenvironment
at
electrolyte–catalyst
interface,
enhancing
Faradaic
efficiency
of
electrochemical
CO
2
reduction
reaction
to
ethylene
(C
H
4
).
Chemical Science,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
This
review
systematically
summarizes
the
latest
advances
in
bimetallic
effects
for
reduction
of
CO
2
to
multi-carbon
products,
discussing
structure–activity
relationships
typical
catalysts
reaction.
In
this
perspective
we
analyze
copper
and
copper-based
electrocatalysts
with
high
ethylene
selectivities
from
the
literature
to
identify
global
catalyst
formulation
trends
that
allow
for
making
catalysts
improved
performance.
