Anthraquinone Substituents Regulate the Ion-Transport Sites in iHOFs for Efficient Transport of Alkali-Metal Ions DOI

Xuyong Chen,

Li‐Hui Cao,

Xiang‐Tian Bai

и другие.

Inorganic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Май 5, 2025

The designability of crystalline framework materials holds promise for the development stable solid-state electrolytes with high ionic conductivity. In this study, we present three anthraquinone-based hydrogen-bonded organic frameworks (iHOF-21-23), which possess 2D sandwich-shaped hydrogen-bonding networks. By modulating anthraquinone substituents, iHOFs exhibit distinct ion-transport sites. Specifically, both carbonyls in structure iHOF-22 are sites, whereas only one carbonyl each iHOF-21 and iHOF-23 is, thus exhibits higher conductivities. conductivities Li+, Na+, K+ at 30 °C 1.37 × 10-4, 1.14 9.76 10-5 S cm-1, respectively, 16-47% than those iHOF-23. design multidimensional ion transport provides valuable insights various batteries.

Язык: Английский

Recent Advances in Porous Organic Cages for Energy Applications DOI Creative Commons
Chao Liu, Zhixuan Wang, Hailong Wang

и другие.

Chemical Science, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

Recent advances and outlook of porous organic cage-based materials (pristine POCs, POC composites derivatives) in the field energy applications, including photocatalysis, electrocatalysis, separation, batteries proton conductivity.

Язык: Английский

Процитировано

4
Tailoring functionalities: pore engineering strategies in porous organic cages for diverse applications DOI

Mingming Hua,

Yang Ding, Chunxiao Lv

и другие.

Journal of Materials Chemistry A, Год журнала: 2024, Номер unknown

Опубликована: Дек. 10, 2024

This review focuses on pore engineering (intrinsic size, extrinsic porosity, and environment) in porous organic cages summarizes the roles of various fields.

Язык: Английский

Процитировано

3
Anthraquinone Substituents Regulate the Ion-Transport Sites in iHOFs for Efficient Transport of Alkali-Metal Ions DOI

Xuyong Chen,

Li‐Hui Cao,

Xiang‐Tian Bai

и другие.

Inorganic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Май 5, 2025

The designability of crystalline framework materials holds promise for the development stable solid-state electrolytes with high ionic conductivity. In this study, we present three anthraquinone-based hydrogen-bonded organic frameworks (iHOF-21-23), which possess 2D sandwich-shaped hydrogen-bonding networks. By modulating anthraquinone substituents, iHOFs exhibit distinct ion-transport sites. Specifically, both carbonyls in structure iHOF-22 are sites, whereas only one carbonyl each iHOF-21 and iHOF-23 is, thus exhibits higher conductivities. conductivities Li+, Na+, K+ at 30 °C 1.37 × 10-4, 1.14 9.76 10-5 S cm-1, respectively, 16-47% than those iHOF-23. design multidimensional ion transport provides valuable insights various batteries.

Язык: Английский

Процитировано

0