Organic Letters, Год журнала: 2025, Номер unknown
Опубликована: Март 11, 2025
The SF5O group has been less explored as a highly fluorinated substituent on an organic framework. In fact, only few SF5O-containing compounds have reported, and the preparation of relied hazardous reagents special apparatuses. Herein we describe safe efficient access to various pentafluoro(aryloxy)-λ6-sulfanes (ArOSF5) through reaction hypervalent λ3-chlor(brom)anes with [Et3MeN]+[OSF5]−. synthetic application potentials ArOSF5 moieties were demonstrated by inertness OSF5 in presence palladium catalysts, alkalis, nucleophiles.
Язык: Английский