Selective Alkylarylation Difunctionalization of 1,3-Butadienes via Nickel/Photoredox Dual Catalysis DOI
Aidana Gimnkhan, Rajesh Kancherla, Krishnamoorthy Muralirajan

и другие.

Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Май 19, 2025

Photocatalytic multicomponent reactions are at the forefront of organic synthesis. In recent years, dicarbofunctionalization olefins has received significant attention, with nickel serving as a key transition metal catalyst under photochemical conditions. However, achieving regioselective 1,4-alkylarylation dienes alkyl and aryl bromides remains challenging. this work, we present Ni/photoredox dual catalysis approach for alkylarylation dienes, offering mild reaction that eliminates need stochiometric reductants. Broad substrate scope mechanistic investigations presented support proposed mechanism.

Язык: Английский

Selective Alkylarylation Difunctionalization of 1,3-Butadienes via Nickel/Photoredox Dual Catalysis DOI
Aidana Gimnkhan, Rajesh Kancherla, Krishnamoorthy Muralirajan

и другие.

Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Май 19, 2025

Photocatalytic multicomponent reactions are at the forefront of organic synthesis. In recent years, dicarbofunctionalization olefins has received significant attention, with nickel serving as a key transition metal catalyst under photochemical conditions. However, achieving regioselective 1,4-alkylarylation dienes alkyl and aryl bromides remains challenging. this work, we present Ni/photoredox dual catalysis approach for alkylarylation dienes, offering mild reaction that eliminates need stochiometric reductants. Broad substrate scope mechanistic investigations presented support proposed mechanism.

Язык: Английский

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