Pyrazine‐Based Chiral AIE Electronic Acceptors for Real‐Time Monitoring Hierarchical Self‐Assembly and Tuning Emissions through Intermolecular Charge‐Transfer Effects DOI
Xiang He,

Meizhu Xie,

Yingjuan Hong

и другие.

Advanced Optical Materials, Год журнала: 2024, Номер unknown

Опубликована: Окт. 3, 2024

Abstract Development of chiral aggregation‐induced emission (AIE) materials toward hierarchical self‐assembly is crucial to reveal the origin and evolution life. In this work, a pair AIE enantiomers fabricated by attaching typical units binaphthyl core via single bond linkage. The behavior inherited from introduced unit while can not only improve photo‐physical properties but also provide whole molecules with chirality. Moreover, as driven dipolar structure chirality AIEgens, different morphologies such spheres, ribbons or fibers, flowers, even bigger structures various sizes be dynamically monitored assembled time, which provided favorable evidence study structural molecular level higher‐level structure. On other hand, these AIEgens act strong electronic acceptors due unit. By complexing them donors, resulting intermolecular charge transfer induce remarkable red emissions tunable much their individuals. This enabled it facile, economic, flexible approach develop organic photoelectric materials.

Язык: Английский

Pyrazine‐Based Chiral AIE Electronic Acceptors for Real‐Time Monitoring Hierarchical Self‐Assembly and Tuning Emissions through Intermolecular Charge‐Transfer Effects DOI
Xiang He,

Meizhu Xie,

Yingjuan Hong

и другие.

Advanced Optical Materials, Год журнала: 2024, Номер unknown

Опубликована: Окт. 3, 2024

Abstract Development of chiral aggregation‐induced emission (AIE) materials toward hierarchical self‐assembly is crucial to reveal the origin and evolution life. In this work, a pair AIE enantiomers fabricated by attaching typical units binaphthyl core via single bond linkage. The behavior inherited from introduced unit while can not only improve photo‐physical properties but also provide whole molecules with chirality. Moreover, as driven dipolar structure chirality AIEgens, different morphologies such spheres, ribbons or fibers, flowers, even bigger structures various sizes be dynamically monitored assembled time, which provided favorable evidence study structural molecular level higher‐level structure. On other hand, these AIEgens act strong electronic acceptors due unit. By complexing them donors, resulting intermolecular charge transfer induce remarkable red emissions tunable much their individuals. This enabled it facile, economic, flexible approach develop organic photoelectric materials.

Язык: Английский

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