Ultrafast Room‐Temperature Synthesis of Yb3+/Er3+ Codoped K3ZrF7 Nanocrystals for Thermal Enhancement of Upconversion DOI

Huhui Fu,

Wenfeng Xie,

Yuanqi Qian

и другие.

Laser & Photonics Review, Год журнала: 2024, Номер unknown

Опубликована: Дек. 4, 2024

Abstract Lanthanide (Ln 3+ )‐doped upconversion nanocrystals (NCs) have attracted great attention due to their outstanding luminescent performance and wide applications in various fields. However, the preparation of most Ln ‐doped NCs requires rigorous conditions such as high reaction temperature, long time, strict anhydrous oxygen‐free environment, tedious post‐treatment process. Herein, sub‐100 nm Yb /Er codoped K 3 ZrF 7 octahedral are prepared by an extremely simple coprecipitation method (10 s only at room temperature). The resulting show excellent luminescence (UCL), significantly superior both conventional high‐temperature‐synthesized counterparts room‐temperature‐synthesized NaBiF 4 :Yb/Er controls. More importantly, abnormal thermally enhanced UCL over a temperature range from 473 is found these NCs, making them promising candidates for ratiometric thermometry applications. By employing intensity ratio between two non‐thermally coupled energy levels Er , namely F 9/2 2 H 11/2 display extraordinarily absolute sensitivity 443.2% −1 comparatively large relative 1.55% temperature. These results reveal that can not be facilely via ultrafast room‐temperature synthesis, but also hold potential areas optical sensing biological

Язык: Английский

Time-resolved optical fiber measurements: a review of scintillator materials and applications DOI Creative Commons
F. Moradi, D.A. Bradley,

Zubair Hassan Tarif

и другие.

Radiation Detection Technology and Methods, Год журнала: 2025, Номер unknown

Опубликована: Янв. 5, 2025

Abstract Background Optical fiber radioluminescence measurement (OFRLM) is a cutting-edge technique poised to play major role in radiation detection and dosimetry. Time-resolved involves capturing the temporal dynamics of light emission from scintillators, providing detailed information about pulses. Objective This review aims evaluate various scintillator materials used time-resolved OFRLM systems their critical importance ionizing Content The article discusses properties materials, including organic, inorganic, composite compositions, highlights unique suitability for measurements with systems. Performance characteristics, advantages, limitations different are thoroughly reviewed. Conclusion provides insights into optimal selection systems, offering criteria improving performance facilitating advancements

Язык: Английский

Процитировано

2

Unleashing the Potential of Defect Engineered Persistent Pr3+‐Activated Phosphors for Multi‐Dimensional Anti‐Counterfeiting and X‐Ray Imaging Applications DOI Creative Commons
Annu Balhara, Santosh K. Gupta, P. S. Ghosh

и другие.

Small, Год журнала: 2025, Номер unknown

Опубликована: Апрель 24, 2025

Abstract Persistent luminescence (PersL) in inorganic phosphors offers great potential for anti‐counterfeiting and optical storage, with optimization of PersL, multicolor tuning, defect engineering. This study presents a Ca 3 Ga 2 Ge O 12: Pr 3+ (CGGO:Pr) phosphor long‐lasting PersL emissions. Aliovalent codoping Er Yb ions optimizes deep/shallow trap redistribution, controlling depths from 0.98 to optimal 0.73 eV through the creation new shallow electron traps (Yb • , ) alongside existing V levels. The smart /Er /Yb :CGGO exhibits three‐dimensional visible emissions under 275 380 nm excitation, as well upconversion 980 laser irradiation. Hybrid density functional calculations, thermoluminescence, positron annihilation lifetime spectroscopy revealed nature different PersL. Together, single system featuring has been developed, exhibiting improved regulated (≈0.73 eV) suitable robust multimodal documents, pharmaceuticals, industrial products. Furthermore, composite PMMA‐CGGO:Pr films have shown remarkable capability X‐ray imaging, achieving resolution 4 lp/mm, which exceeds that commercial Gd S:Tb screens. These findings highlight this work advanced imaging applications, offering enhanced controlled depths.

Язык: Английский

Процитировано

0

Single activator doped fluoride nanoparticles for X-ray excited high-resolution and delayed flexible nonplanar imaging DOI

Weixin Xu,

Min Zhou, Renren Deng

и другие.

Chemical Engineering Journal, Год журнала: 2024, Номер unknown, С. 156406 - 156406

Опубликована: Окт. 1, 2024

Язык: Английский

Процитировано

2

Investigating the Mechanism of Rare-Earth Ion Incorporation into Glass–Ceramic Crystal Phases through Er3+ Ion Probe Characteristics DOI Creative Commons
Zhuo Chen, Wenzhe Cui,

Sijun Ren

и другие.

Nanomaterials, Год журнала: 2024, Номер 14(18), С. 1479 - 1479

Опубликована: Сен. 11, 2024

Exploring the intrinsic mechanisms of rare-earth ions entering crystal phase has great significance for finely tuning luminescent properties glass-ceramics. Using Er

Язык: Английский

Процитировано

0

Fluorescence of europium activated by molecular-like silver clusters for the detection of alkaline phosphatase activity DOI
Chenxi Zhao, Xiaoxia Li, Yang Shu

и другие.

Talanta, Год журнала: 2024, Номер 281, С. 126892 - 126892

Опубликована: Сен. 17, 2024

Язык: Английский

Процитировано

0

Ultrafast Room‐Temperature Synthesis of Yb3+/Er3+ Codoped K3ZrF7 Nanocrystals for Thermal Enhancement of Upconversion DOI

Huhui Fu,

Wenfeng Xie,

Yuanqi Qian

и другие.

Laser & Photonics Review, Год журнала: 2024, Номер unknown

Опубликована: Дек. 4, 2024

Abstract Lanthanide (Ln 3+ )‐doped upconversion nanocrystals (NCs) have attracted great attention due to their outstanding luminescent performance and wide applications in various fields. However, the preparation of most Ln ‐doped NCs requires rigorous conditions such as high reaction temperature, long time, strict anhydrous oxygen‐free environment, tedious post‐treatment process. Herein, sub‐100 nm Yb /Er codoped K 3 ZrF 7 octahedral are prepared by an extremely simple coprecipitation method (10 s only at room temperature). The resulting show excellent luminescence (UCL), significantly superior both conventional high‐temperature‐synthesized counterparts room‐temperature‐synthesized NaBiF 4 :Yb/Er controls. More importantly, abnormal thermally enhanced UCL over a temperature range from 473 is found these NCs, making them promising candidates for ratiometric thermometry applications. By employing intensity ratio between two non‐thermally coupled energy levels Er , namely F 9/2 2 H 11/2 display extraordinarily absolute sensitivity 443.2% −1 comparatively large relative 1.55% temperature. These results reveal that can not be facilely via ultrafast room‐temperature synthesis, but also hold potential areas optical sensing biological

Язык: Английский

Процитировано

0