Ag‐BN hybrid filler prepared by a rapid microwave‐heating method and its effective use for PVDF‐based composite DOI Creative Commons

Jian‐Wu Xiao,

Bo Lin,

Guo‐Cui Bao

и другие.

Polymer Composites, Год журнала: 2025, Номер unknown

Опубликована: Март 26, 2025

Abstract In this work, a silver nanoparticle‐boron nitride nanoplate (Ag‐BN) hybrid filler was prepared using an effective microwave‐heating method in only 2 min and utilized as functional for polyvinylidene fluoride (PVDF)‐based composite. The successful deposition of Ag nanoparticles on BN nanoplates, forming the Ag‐BN filler, confirmed through series microstructural characterizations FTIR, WAXD, UV–Vis, SEM, TEM, EDS mapping. Furthermore, it found that incorporation into PVDF effectively enhanced crystallization behaviors, dielectric properties, thermal conductivities resultant Ag‐BN/PVDF composites. For example, nonisothermal‐crystallization‐peak temperatures, degrees, contents polar β ‐ γ ‐form crystallines PVDF, constants, loss tangents, pure Ag‐BN1(10 wt.%)/PVDF composite are 136.2 143.7°C, 41.37% 53.41%, 26.0% 72.6%, 8.2 15.0, 0.023 0.024, 0.12 0.31 W/m·K, respectively. Highlights obtained from rapid method. Novel composites were solution‐blending can induce crystalline PVDF. have property compared to conductivity

Язык: Английский

Retainable large magnetoelectric coupling in BiFeO3@CoFe2O4 core-shell nanoparticle embedded P(VDF-TrFE) matrix DOI

Chenyang Wang,

Xu Ling-Fang,

Xiang Lv

и другие.

Applied Physics Letters, Год журнала: 2025, Номер 126(8)

Опубликована: Фев. 24, 2025

Flexible magnetoelectric composite devices have exceptional features and potential in peculiar scenes. However, maintaining the response under extreme bending conditions remains a challenge. Polyvinylidene fluoride-based polymers, possessing favorable piezoelectric properties high flexibility, provide viable solution for composites. This work constructed multiferroic core-shell nanoparticle-embedded flexible membranes achieved retainable (ME) coupling coefficient curved materials. A maximum ME of 74 mV cm−1 Oe−1 was obtained, far higher than 0–3 nanocomposites reported thus far. The can be maintained above 40 when angle is less 90° expresses sensitivity within Hdc range 100–2400 Oe. Based on crystal structure analysis phase-field simulation, synergy effects accounting nanoparticles, copolymer matrix, magnetic cores contribute to promoted provides feasible pathway next-generation wearable portable fields.

Язык: Английский

Процитировано

0

Ag‐BN hybrid filler prepared by a rapid microwave‐heating method and its effective use for PVDF‐based composite DOI Creative Commons

Jian‐Wu Xiao,

Bo Lin,

Guo‐Cui Bao

и другие.

Polymer Composites, Год журнала: 2025, Номер unknown

Опубликована: Март 26, 2025

Abstract In this work, a silver nanoparticle‐boron nitride nanoplate (Ag‐BN) hybrid filler was prepared using an effective microwave‐heating method in only 2 min and utilized as functional for polyvinylidene fluoride (PVDF)‐based composite. The successful deposition of Ag nanoparticles on BN nanoplates, forming the Ag‐BN filler, confirmed through series microstructural characterizations FTIR, WAXD, UV–Vis, SEM, TEM, EDS mapping. Furthermore, it found that incorporation into PVDF effectively enhanced crystallization behaviors, dielectric properties, thermal conductivities resultant Ag‐BN/PVDF composites. For example, nonisothermal‐crystallization‐peak temperatures, degrees, contents polar β ‐ γ ‐form crystallines PVDF, constants, loss tangents, pure Ag‐BN1(10 wt.%)/PVDF composite are 136.2 143.7°C, 41.37% 53.41%, 26.0% 72.6%, 8.2 15.0, 0.023 0.024, 0.12 0.31 W/m·K, respectively. Highlights obtained from rapid method. Novel composites were solution‐blending can induce crystalline PVDF. have property compared to conductivity

Язык: Английский

Процитировано

0