Retainable large magnetoelectric coupling in BiFeO3@CoFe2O4 core-shell nanoparticle embedded P(VDF-TrFE) matrix
Chenyang Wang,
Xu Ling-Fang,
Xiang Lv
и другие.
Applied Physics Letters,
Год журнала:
2025,
Номер
126(8)
Опубликована: Фев. 24, 2025
Flexible
magnetoelectric
composite
devices
have
exceptional
features
and
potential
in
peculiar
scenes.
However,
maintaining
the
response
under
extreme
bending
conditions
remains
a
challenge.
Polyvinylidene
fluoride-based
polymers,
possessing
favorable
piezoelectric
properties
high
flexibility,
provide
viable
solution
for
composites.
This
work
constructed
multiferroic
core-shell
nanoparticle-embedded
flexible
membranes
achieved
retainable
(ME)
coupling
coefficient
curved
materials.
A
maximum
ME
of
74
mV
cm−1
Oe−1
was
obtained,
far
higher
than
0–3
nanocomposites
reported
thus
far.
The
can
be
maintained
above
40
when
angle
is
less
90°
expresses
sensitivity
within
Hdc
range
100–2400
Oe.
Based
on
crystal
structure
analysis
phase-field
simulation,
synergy
effects
accounting
nanoparticles,
copolymer
matrix,
magnetic
cores
contribute
to
promoted
provides
feasible
pathway
next-generation
wearable
portable
fields.
Язык: Английский
Ag‐BN hybrid filler prepared by a rapid microwave‐heating method and its effective use for PVDF‐based composite
Jian‐Wu Xiao,
Bo Lin,
Guo‐Cui Bao
и другие.
Polymer Composites,
Год журнала:
2025,
Номер
unknown
Опубликована: Март 26, 2025
Abstract
In
this
work,
a
silver
nanoparticle‐boron
nitride
nanoplate
(Ag‐BN)
hybrid
filler
was
prepared
using
an
effective
microwave‐heating
method
in
only
2
min
and
utilized
as
functional
for
polyvinylidene
fluoride
(PVDF)‐based
composite.
The
successful
deposition
of
Ag
nanoparticles
on
BN
nanoplates,
forming
the
Ag‐BN
filler,
confirmed
through
series
microstructural
characterizations
FTIR,
WAXD,
UV–Vis,
SEM,
TEM,
EDS
mapping.
Furthermore,
it
found
that
incorporation
into
PVDF
effectively
enhanced
crystallization
behaviors,
dielectric
properties,
thermal
conductivities
resultant
Ag‐BN/PVDF
composites.
For
example,
nonisothermal‐crystallization‐peak
temperatures,
degrees,
contents
polar
β
‐
γ
‐form
crystallines
PVDF,
constants,
loss
tangents,
pure
Ag‐BN1(10
wt.%)/PVDF
composite
are
136.2
143.7°C,
41.37%
53.41%,
26.0%
72.6%,
8.2
15.0,
0.023
0.024,
0.12
0.31
W/m·K,
respectively.
Highlights
obtained
from
rapid
method.
Novel
composites
were
solution‐blending
can
induce
crystalline
PVDF.
have
property
compared
to
conductivity
Язык: Английский