Quinuclidine‐Catalyzed Electrochemical Minisci Acylation of N‐Heteroarenes with Acylhydrazines DOI
Haonan Zhang, Dehui Wang, Kun Xu

и другие.

ChemCatChem, Год журнала: 2024, Номер unknown

Опубликована: Дек. 3, 2024

Abstract The quinuclidine (Qu)‐catalyzed activation of acylhydrazines to afford the corresponding acyl radicals remains an unmet challenge. To address this challenge, we report a synergistic strategy by combining electro‐oxidation with Qu‐based HAT catalysis. Enabled strategy, electrochemical Minisci acylation N ‐heterocycles was realized for first time.

Язык: Английский

Acyl radicals generated from aldehydes with NHPI as electrocatalyst: aldehydes and alcohols as carbon-centered radical precursors DOI Creative Commons
Rodrigo G. Enríquez, Juan S. Dato-Santiago, Roberto del Río‐Rodríguez

и другие.

Organic Chemistry Frontiers, Год журнала: 2024, Номер 11(17), С. 4842 - 4848

Опубликована: Янв. 1, 2024

We describe how N -hydroxyphthalimide (NHPI) promotes hydrogen atom transfer from aldehydes under electrochemical conditions. NHPI plays a multifunctional role, enabling the consideration of or alcohols as sp 3 -carbon centered radicals.

Язык: Английский

Процитировано

3
Electrochemical Oxidation Decarboxylative Cyclization of α-Keto Acid with o-Aminobenzylamine DOI
Jiwei Wu, Jun He, Jingjing Wang

и другие.

Chinese Journal of Organic Chemistry, Год журнала: 2024, Номер 44(3), С. 972 - 972

Опубликована: Янв. 1, 2024

Язык: Английский

Процитировано

1
Electrochemical Organic Synthesis DOI
Hai‐Chao Xu

Synthesis, Год журнала: 2023, Номер 55(18), С. 2797 - 2798

Опубликована: Авг. 29, 2023

Received: 03 August 2023 Accepted after revision: Article published online:29

Язык: Английский

Процитировано

1
Visible‐Light‐Driven Synthesis of 6‐Aroyl Benzimidazo[1,2‐c]quinazolines from N‐Cyanobenzimidazoles and α‐Keto Acids by Radical Relay Cyclization DOI

Yang Hu,

Cheng‐Liang Liu,

Wen‐Tao He

и другие.

European Journal of Organic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Май 31, 2024

Abstract A diverse array of 6‐aroyl benzimidazo[1,2‐ c ]quinazolines was successfully synthesized using easily obtainable N ‐cyanobenzimidazoles and α‐keto acids, facilitated by photoredox catalysis. mechanistic investigation revealed that this methodology might involve both energy transfer catalytic cycles, generating acyl radicals subsequently promote radical relay cyclization.

Язык: Английский

Процитировано

0
Quinuclidine‐Catalyzed Electrochemical Minisci Acylation of N‐Heteroarenes with Acylhydrazines DOI
Haonan Zhang, Dehui Wang, Kun Xu

и другие.

ChemCatChem, Год журнала: 2024, Номер unknown

Опубликована: Дек. 3, 2024

Abstract The quinuclidine (Qu)‐catalyzed activation of acylhydrazines to afford the corresponding acyl radicals remains an unmet challenge. To address this challenge, we report a synergistic strategy by combining electro‐oxidation with Qu‐based HAT catalysis. Enabled strategy, electrochemical Minisci acylation N ‐heterocycles was realized for first time.

Язык: Английский

Процитировано

0