Specific Photocatalytic C–C Coupling of Benzyl Alcohol to Deoxybenzoin or Benzoin by Precise Control of Cα–H Bond Activation or O–H Bond Activation by Adjusting the Adsorption Orientation of Hydrobenzoin Intermediates DOI Creative Commons
Z.F. Yue,

Guanchu Lu,

Wenjing Wei

и другие.

ACS Catalysis, Год журнала: 2024, Номер 14(20), С. 15306 - 15324

Опубликована: Окт. 2, 2024

Benzyl alcohol (BA) is a major biomass derivative and can be further converted into deoxybenzoin (DOB) benzoin (BZ) as high-value products for industrial applications through photocatalytic C-C coupling reaction. The process contains two reaction steps, which are (1) the of BA to hydrobenzoin (HB) intermediates (2) either dehydration HB DOB or dehydrogenation BZ. We found that generation BZ mainly determined by activation C

Язык: Английский

Specific Photocatalytic C–C Coupling of Benzyl Alcohol to Deoxybenzoin or Benzoin by Precise Control of Cα–H Bond Activation or O–H Bond Activation by Adjusting the Adsorption Orientation of Hydrobenzoin Intermediates DOI Creative Commons
Z.F. Yue,

Guanchu Lu,

Wenjing Wei

и другие.

ACS Catalysis, Год журнала: 2024, Номер 14(20), С. 15306 - 15324

Опубликована: Окт. 2, 2024

Benzyl alcohol (BA) is a major biomass derivative and can be further converted into deoxybenzoin (DOB) benzoin (BZ) as high-value products for industrial applications through photocatalytic C-C coupling reaction. The process contains two reaction steps, which are (1) the of BA to hydrobenzoin (HB) intermediates (2) either dehydration HB DOB or dehydrogenation BZ. We found that generation BZ mainly determined by activation C

Язык: Английский

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