Sodiophilic Zn‐Diamane Ion Rectification Layer Modulated Polypropylene Separators Enable Dendrite‐Free Sodium Metal Batteries DOI Open Access

Nan Shen,

Shuge Dai,

Gaojie Zhou

и другие.

Advanced Functional Materials, Год журнала: 2024, Номер unknown

Опубликована: Дек. 26, 2024

Abstract Sodium (Na) metal is regarded as an ideal anode for sodium batteries (SMBs) due to its high theoretical specific capacity and low electrochemical potential. However, utilization still restricted by the notorious dendrites unstable solid electrolyte interface (SEI). Herein, a zinc nanoparticle decorated 2D diamond (diamane) modulated commercial polypropylene (Zn‐diamane/PP) separator dedicated mitigating these issues longevity of anodes. Interestingly, sodiophilic Zn‐diamane/PP significantly accelerates ion mobilization promotes uniform flux, thus effectively preventing dendrite growth enhancing stability SEI layer. A Na||Na symmetric cell with demonstrates prolonged lifespan exceeding 5000 h at 1 mA cm −2 mAh . Notably, it sustains >1000 ultra‐high current density 25 The dendrite‐free deposition morphology formation inorganic‐rich inner layer have been investigated through comprehensive characterizations calculations analysis. Furthermore, full comprising Na 3 V 2 (PO 4 ) @C cathode, separator, demonstrate reversible 90 g −1 over 500 cycles. These results potential long‐cycle SMBs.

Язык: Английский

A Modular Agrivoltaics Building Envelope Integrating Thin-Film Photovoltaics and Hydroponic Urban Farming Systems: A Circular Design Approach with the Multi-Objective Optimization of Energy, Light, Water and Structure DOI Open Access

Yihan Zhang,

Tianyi Chen, Eugenia Gasparri

и другие.

Sustainability, Год журнала: 2025, Номер 17(2), С. 666 - 666

Опубликована: Янв. 16, 2025

As cities confront multiple challenges such as climate change, urbanization, and food security, growing attention has been given to sustainable vertical farming renewable energy solutions. Building facades, typically underutilized in high-density urban environments, present an opportunity for multifunctional buildings composed of both photovoltaic (PV) systems modules. However, on surfaces, these two often compete space. This research focuses the development a agrivoltaics building envelope (ABE) system, combining building-integrated PV (BIPV) technology with hydroponic farming. ABE system adopts modular design approach, where each unit can be prefabricated independently assembled through interlocking connection bolted fastening ensure ease construction scalability. The process includes 2D cross-sectional technical design, assembly sequences, analysis key parameters 3D modeling. combined Research Design (RtD) (RfD) approach bridge prototyping, testing, performance optimization. highlights potential integrating agricultural production systems. By addressing space optimization multifunctionality, provides practical framework future applications sustainability.

Язык: Английский

Процитировано

2

Effects of high entropy combined with Cu/Ag doping on the thermoelectric properties of Bi2Sr2Co2Oy ceramics DOI
Yingying Xu, Mengyao Li, Yingjiu Zhang

и другие.

Ceramics International, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0

3D Printed Sodiophilic Reduced Graphene Oxide/Diamane Microlattice Aerogel for Enhanced Sodium Metal Battery Anodes DOI Creative Commons
Mengmeng Liu,

Dezhi Kong,

Ningning Chu

и другие.

Advanced Science, Год журнала: 2025, Номер unknown

Опубликована: Март 31, 2025

Abstract Sodium metal anode holds great potential for high energy density sodium batteries. However, its practical utilization is impeded by significant volume change and uncontrolled dendrite growth. To tackle these issues, a three‐dimensional (3D) hierarchical porous sodiophilic reduced graphene oxide/diamane (rGO/diamane) microlattice aerogel constructed direct ink writing (DIW) 3D printing (3DP) method. The molten Na diffused into the rGO/diamane host to form Na@rGO/diamane anode, which can deliver an ultra‐high capacity of 78.60 mAh cm −2 (1090.94 g −1 ). Benefiting from uniform ion distribution homogeneously distributed diamane enabled dendrite‐free deposition morphology, anodes exhibit long cycle‐life over 7200 h at 1 mA with . Furthermore, also enhances long‐term stability elevated operation temperature 60 °C, sustaining prolonged lifespan 400 Notably, when integrated 3 V 2 (PO 4 ) @carbon (NVP@C) cathode full cell delivers sustained longevity, maintaining 2000 cycles retention rate 95.72%. This work sheds new insights application development stable high‐performance

Язык: Английский

Процитировано

0

Synergistic integration of MnCo2O4/MoS2 with rGO as positive electrode for enhanced electrochemical performance in asymmetric supercapacitors DOI

K. Manimegala,

S. Stella Mary,

M. Saravanakumar

и другие.

Ionics, Год журнала: 2025, Номер unknown

Опубликована: Апрель 2, 2025

Язык: Английский

Процитировано

0

In Situ TEM Studies of Tunnel‐Structured Materials for Alkali Metal‐Ion Batteries DOI Creative Commons
Shuge Dai, C.P. Yang, Ye Wang

и другие.

Advanced Science, Год журнала: 2025, Номер unknown

Опубликована: Апрель 15, 2025

Abstract Tunnel‐structured materials have garnered significant attention as promising candidates for high‐performance rechargeable batteries, owing to their unique structural characteristics that facilitate efficient ionic transport. However, understanding the dynamic processes of transport within these tunnels is crucial further development and performance optimization. Analytical in situ transmission electron microscopy (TEM) has demonstrated its effectiveness a powerful tool visualizing complex real time. In this review, we summarize state‐of‐the‐art tracking tunnel‐structured alkali metal‐ion batteries (AMIBs) by TEM observation at atomic scale, elucidating fundamental issues pertaining phase transformations, evolution, interfacial reactions degradation mechanisms. This review covers wide range electrode electrolyte used AMIBs, highlighting versatility general applicability mechanisms underlying AMIBs. Furthermore, work critically discusses current challenges future research directions, offering perspectives on next‐generation battery through advanced characterization techniques.

Язык: Английский

Процитировано

0

Sodiophilic Zn‐Diamane Ion Rectification Layer Modulated Polypropylene Separators Enable Dendrite‐Free Sodium Metal Batteries DOI Open Access

Nan Shen,

Shuge Dai,

Gaojie Zhou

и другие.

Advanced Functional Materials, Год журнала: 2024, Номер unknown

Опубликована: Дек. 26, 2024

Abstract Sodium (Na) metal is regarded as an ideal anode for sodium batteries (SMBs) due to its high theoretical specific capacity and low electrochemical potential. However, utilization still restricted by the notorious dendrites unstable solid electrolyte interface (SEI). Herein, a zinc nanoparticle decorated 2D diamond (diamane) modulated commercial polypropylene (Zn‐diamane/PP) separator dedicated mitigating these issues longevity of anodes. Interestingly, sodiophilic Zn‐diamane/PP significantly accelerates ion mobilization promotes uniform flux, thus effectively preventing dendrite growth enhancing stability SEI layer. A Na||Na symmetric cell with demonstrates prolonged lifespan exceeding 5000 h at 1 mA cm −2 mAh . Notably, it sustains >1000 ultra‐high current density 25 The dendrite‐free deposition morphology formation inorganic‐rich inner layer have been investigated through comprehensive characterizations calculations analysis. Furthermore, full comprising Na 3 V 2 (PO 4 ) @C cathode, separator, demonstrate reversible 90 g −1 over 500 cycles. These results potential long‐cycle SMBs.

Язык: Английский

Процитировано

2