New spiro-heterocyclic coumarin derivatives as antibacterial agents: design, synthesis and molecular docking DOI Creative Commons
Abdallah F. Al-burgus, Omar T. Ali, Omar Y. Al-Abbasy

и другие.

Chimica Techno Acta, Год журнала: 2024, Номер 11(3)

Опубликована: Авг. 8, 2024

Coumarin derivatives were synthesized herein from 3-acetyl coumarin and 4-(pyrimidin-2-yldiazenyl) antipyrine, leading to the azo chalcone intermediate compound. The final spiro-heterocyclic coumarins produced through cyclization of azo-chalcone with thiourea, guanidine hydrochloride, benzene-1,2-diamine, 2-aminophenol, hydroxylamine respectively. obtained target compounds purified by column chromatography characterized FT-IR, 1H NMR, 13C-NMR elemental analysis. antibacterial activity was evaluated in vitro against Gram-negative Gram-positive bacteria. One showed significant activity. Furthermore, docking study this compound DNA gyrase for E. coli S. aureus bacterial strains investigated, which revealed vital interactions binding.

Язык: Английский

Hemisynthesis of monoterpene-containing pyridin-2-one, pyrano[2,3-c]pyrazole and dicarbamate derivatives: in vitro and in silico anti-inflammatory activity DOI
Maamar Haffas,

Naïma Benkiki,

Farid Chebrouk

и другие.

Journal of Molecular Structure, Год журнала: 2025, Номер unknown, С. 141565 - 141565

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

1

Discovery of Pyrano[2,3-c]pyrazole Derivatives as Novel Potential Human Coronavirus Inhibitors: Design, Synthesis, In Silico, In Vitro, and ADME Studies DOI Creative Commons
Abdou K. Allayeh,

Aliaa H. El-boghdady,

Mohamed A. Said

и другие.

Pharmaceuticals, Год журнала: 2024, Номер 17(2), С. 198 - 198

Опубликована: Фев. 2, 2024

The SARS-CoV-2 pandemic at the end of 2019 had major worldwide health and economic consequences. Until effective vaccination approaches were created, healthcare sectors endured a shortage operative treatments that might prevent infection’s spread. As result, academia pharmaceutical industry prioritized development SARS-CoV2 antiviral medication. Pyranopyrazoles have been shown to play prominent function in chemistry drug sighting because their significant bioactive properties. We provide herein novel sequence pyranopyrazoles annulated systems whose efficacy cytotoxicity explored versus human coronavirus 229E (HCoV-229E) Vero-E6 cell lines as model for Coronaviridae family. Fifteen synthetic congeners pointed out miscellaneous efficacies against HCoV-229E with variable inhibition degrees. Compound 18 showed high selectivity index (SI = 12.6) established spectacular inhibitory capacity 229E. Compounds 6, 7, 14 exposed moderate efficacies. 14, exhibited substantial action through replication phase reduction percentages extending from 53.6%, 60.7%, 55% 82.2%, correspondingly. Likewise, when assessed positive control tipranavir (88.6%), efficiency compounds Mpro provided 80.4%, 73.1%, 81.4% up 84.5%, respectively. In silico studies performed investigate further biological activity target compounds’ physical chemical features, including molecular dynamic (MD) simulations, protein–ligand docking, ADME studies, density functional theory (DFT) calculations. These inquiries demonstrated this series metabolically stable are inhibitors inhibit viral protein may emerged COVID-19 curative option.

Язык: Английский

Процитировано

6

Synthesis of new pyrimidine derivatives and study their antibacterial activity: Computational and in vitro assessment DOI Creative Commons

Huda Hadi Nima,

Ahmed Hassen Shntaif

Journal of Umm Al-Qura University for Applied Sciences, Год журнала: 2025, Номер unknown

Опубликована: Апрель 10, 2025

Abstract To identify novel antimicrobial candidates, a class of derivatives pyrimidine and chalcone were synthesized their biological activities determined by in vitro silico analyses. Chalcone wet lab using various chemical reactions. Chalcones prepared reacting 4-hydroxy-3-nitro acetophenone with substituted benzaldehydes basic medium. Pyrimidine was the presence ethanol chalcones thiourea urea The Structures compounds confirmed (FTIR, 1 HNMR, 13 CNMR Mass spectroscopy). In assessments conducted to verify antibacterial activity analyzing inhibition zones molecular docking interactions against DNA gyrase S. aureus Escherichia coli . Upon results analysis, it observed that II , b c d e III f IV inhibited growth both bacteria, indicating these might be potent bacterial activity. further confirm inhibitory effect derived compounds, performed proteins Staphylococcus species explore probable binding conformations. As result, high affinity as indicated results, suggests majority have demonstrated gram-positive gram-negative bacteria. summary, compound may serve potentially strong dual gyrase.

Язык: Английский

Процитировано

0

Role of DNA Double-Strand Break Formation in Gyrase Inhibitor-Mediated Killing of Nonreplicating Persistent Mycobacterium tuberculosis in Caseum DOI Creative Commons

Priyanka Ashwath,

Paulina Osiecki,

Danielle M. Weiner

и другие.

ACS Infectious Diseases, Год журнала: 2024, Номер unknown

Опубликована: Сен. 24, 2024

Tuberculosis is the leading cause of mortality by infectious agents worldwide. The necrotic debris, known as caseum, which accumulates in center pulmonary lesions and cavities home to nonreplicating drug-tolerant

Язык: Английский

Процитировано

2

Exploration of crystal structure, supramolecular organization, and computational studies of a novel pyrazole derivative: A structural and theoretical perspectives DOI

D. Rekharani,

Vinay Kumar,

Chethan BS

и другие.

Journal of Molecular Structure, Год журнала: 2024, Номер unknown, С. 140265 - 140265

Опубликована: Окт. 1, 2024

Язык: Английский

Процитировано

1

Prominent Antidiabetic and Anticancer Investigation of Scrophularia deserti Extract: Integration of Experimental and Computational Approaches DOI
Arafa Musa, Shaimaa R. Ahmed, Shaimaa Hussein

и другие.

Journal of Molecular Structure, Год журнала: 2024, Номер 1315, С. 138769 - 138769

Опубликована: Июнь 5, 2024

Язык: Английский

Процитировано

0

New spiro-heterocyclic coumarin derivatives as antibacterial agents: design, synthesis and molecular docking DOI Creative Commons
Abdallah F. Al-burgus, Omar T. Ali, Omar Y. Al-Abbasy

и другие.

Chimica Techno Acta, Год журнала: 2024, Номер 11(3)

Опубликована: Авг. 8, 2024

Coumarin derivatives were synthesized herein from 3-acetyl coumarin and 4-(pyrimidin-2-yldiazenyl) antipyrine, leading to the azo chalcone intermediate compound. The final spiro-heterocyclic coumarins produced through cyclization of azo-chalcone with thiourea, guanidine hydrochloride, benzene-1,2-diamine, 2-aminophenol, hydroxylamine respectively. obtained target compounds purified by column chromatography characterized FT-IR, 1H NMR, 13C-NMR elemental analysis. antibacterial activity was evaluated in vitro against Gram-negative Gram-positive bacteria. One showed significant activity. Furthermore, docking study this compound DNA gyrase for E. coli S. aureus bacterial strains investigated, which revealed vital interactions binding.

Язык: Английский

Процитировано

0