Advanced Materials,
Год журнала:
2021,
Номер
33(50)
Опубликована: Июнь 12, 2021
Abstract
Transition
metal
sulfides
are
an
extraordinarily
vital
class
of
semiconductors
with
a
wide
range
applications
in
the
photocatalytic
field.
A
great
number
recent
advances
transformations
lignocellulosic
biomass,
largest
renewable
carbon
resource,
into
high‐quality
fuels
and
value‐added
chemicals
has
been
achieved
over
sulfide
semiconductors.
Herein,
progress
breakthroughs
metal‐sulfide‐based
systems
for
lignocellulose
valorization
emphasis
on
selective
depolymerization
lignin
oxidative
coupling
some
important
bioplatforms
highligted.
The
key
issues
that
control
reaction
pathways
mechanisms
carefully
examined.
functions
elementary
reactions,
including
CO‐bond
cleavage,
oxidations,
CC
coupling,
CH
activation,
discussed
to
offer
insights
guide
rational
design
active
photocatalysts
sustainable
chemistry.
prospects
biomass
also
analyzed
briefly
discussed.
The Science of The Total Environment,
Год журнала:
2021,
Номер
794, С. 148539 - 148539
Опубликована: Июнь 19, 2021
Digitalization
provides
access
to
an
integrated
network
of
unexploited
big
data
with
potential
benefits
for
society
and
the
environment.
The
development
smart
systems
connected
internet
things
can
generate
unique
opportunities
strategically
address
challenges
associated
United
Nations
Sustainable
Development
Goals
(SDGs)
ensure
equitable,
environmentally
sustainable,
healthy
society.
This
perspective
describes
that
digitalization
provide
towards
building
sustainable
future.
Smart
technologies
are
envisioned
as
game-changing
tools,
whereby
their
integration
will
benefit
three
essential
elements
food-water-energy
nexus:
(i)
food
production;
(ii)
clean
safe
potable
water;
(iii)
green
energy
generation
usage.
It
then
discusses
catalyze
transition
manufacturing
practices
enhance
citizens'
health
wellbeing
by
providing
digital
care,
particularly
underserved
communities.
Finally,
englobes
a
holistic
view
on
how
it
contribute
serious
endangered
planet
biodiversity
climate
change.
Angewandte Chemie International Edition,
Год журнала:
2021,
Номер
60(36), С. 19572 - 19590
Опубликована: Фев. 19, 2021
Abstract
Compared
to
modern
fossil‐fuel‐based
refineries,
the
emerging
electrocatalytic
refinery
(e‐refinery)
is
a
more
sustainable
and
environmentally
benign
strategy
convert
renewable
feedstocks
energy
sources
into
transportable
fuels
value‐added
chemicals.
A
crucial
step
in
conducting
e‐refinery
processes
development
of
appropriate
reactions
optimal
electrocatalysts
for
efficient
cleavage
formation
chemical
bonds.
However,
compared
well‐studied
primary
(e.g.,
O
2
reduction,
water
splitting),
mechanistic
aspects
materials
design
complex
are
yet
be
settled.
To
address
this
challenge,
herein,
we
first
present
fundamentals
heterogeneous
electrocatalysis
some
reactions,
then
implement
these
establish
framework
by
coupling
situ
generated
intermediates
(integrated
reactions)
or
products
(tandem
reactions).
We
also
set
principles
strategies
efficiently
manipulate
reaction
pathways.
Science,
Год журнала:
2021,
Номер
374(6563), С. 71 - 76
Опубликована: Сен. 30, 2021
Reducing
net
emission
The
great
majority
of
plastics
in
current
use
are
sourced
from
fossil
fuels,
with
additional
fuels
combusted
to
power
their
manufacture.
Substantial
research
is
focused
on
finding
more
sustainable
building
blocks
for
next-generation
polymers.
Meys
et
al
.
report
a
series
life
cycle
analyses
suggesting
that
even
the
varieties
commercial
monomers
could
potentially
be
manufactured
and
polymerized
no
greenhouse
gas
emissions.
relies
combining
recycling
plastic
waste
chemical
reduction
carbon
dioxide
captured
incineration
or
derived
biomass.
—JSY
Advanced Energy Materials,
Год журнала:
2021,
Номер
11(43)
Опубликована: Июнь 17, 2021
Abstract
Biomass
is
recognized
as
an
ideal
CO
2
neutral,
abundant,
and
renewable
resource
substitute
to
fossil
fuels.
The
rich
proton
content
in
most
biomass
derived
materials,
such
ethanol,
5‐hydroxymethylfurfural
(HMF)
glycerol
allows
it
be
effective
hydrogen
carrier.
oxidation
derivatives,
2,5‐difurandicarboxylic
acid
from
HMF,
glyceric
are
valuable
products
used
biodegradable
polymers
pharmaceuticals.
Therefore,
combining
biomass‐derived
compound
at
the
anode
evolution
reaction
cathode
a
electrolysis
or
photo‐reforming
reactor
would
present
promising
strategy
for
coproducing
high
value
chemicals
with
low
energy
consumption
emissions.
This
review
aims
combine
fundamental
knowledge
on
photo
electro‐assisted
catalysis
provide
comprehensive
understanding
of
general
mechanisms
different
molecule
oxidation.
At
same
time,
catalyst
requirements
recent
advances
various
feedstock
compounds
also
reviewed
detail.
Technoeconomic
assessment
life
cycle
analysis
performed
feedstocks
assess
relative
benefits
processes,
finally
critical
prospects
given
challenges
opportunities
technology
development
meet
sustainability
requirement
future
global
economy.
Angewandte Chemie International Edition,
Год журнала:
2021,
Номер
61(15)
Опубликована: Дек. 17, 2021
Green
carbon
science
is
defined
as
the
"study
and
optimization
of
transformation
carbon-containing
compounds
relevant
processes
involved
in
entire
cycle
from
resource
processing,
energy
utilization,
CO2
fixation,
recycling
to
utilize
resources
efficiently
minimize
net
emission."[1]
related
closely
neutrality,
fields
have
developed
quickly
last
decade.
In
this
Minireview,
we
propose
concept
index,
recent
progress
petroleum
refining,
production
liquid
fuels,
chemicals,
materials
using
coal,
methane,
,
biomass,
waste
plastics
highlighted
combination
with
green
science.
An
outlook
for
these
important
provided
final
section.
Annual Review of Environment and Resources,
Год журнала:
2020,
Номер
45(1), С. 331 - 386
Опубликована: Авг. 4, 2020
This
review
synthesizes
diverse
approaches
that
researchers
have
brought
to
bear
on
the
challenge
of
sustainable
development.
We
construct
an
integrated
framework
highlighting
union
set
elements
and
relationships
those
shown
be
useful
in
explaining
nature–society
interactions
multiple
contexts.
Compelling
evidence
has
accumulated
should
viewed
as
a
globally
interconnected,
complex
adaptive
system
which
heterogeneity,
nonlinearity,
innovation
play
formative
roles.
The
long-term
evolution
cannot
predicted
but
can
understood
partially
guided
through
dynamic
interventions.
Research
identified
six
capacities
necessary
support
such
interventions
guiding
development
pathways
toward
sustainability.
These
are
(
a)
measure
development,
b)
promote
equity,
c)
adapt
shocks
surprises,
d)
transform
into
more
pathways,
e)
link
knowledge
with
action,
f)
devise
governance
arrangements
allow
people
work
together
exercising
other
capacities.
Advanced Energy Materials,
Год журнала:
2020,
Номер
11(43)
Опубликована: Дек. 21, 2020
Abstract
The
commercial
breakthrough
of
Li‐ion
batteries
(LIBs)
in
the
1990s
irrevocably
shaped
today's
energy
storage
landscape,
but
disposed
represent
a
growing
hazard
to
environment.
One
may
initially
assume
that
recycling
processes
are
commendable
technologies
ensure
counterbalance
LIBs
manufacturing.
However,
question
remains
whether
current
state‐of‐the‐art
can
be
considered
as
green.
This
problem
is
due
application
toxic
chemicals
or
situ
generation
harmful
substances
during
process.
Besides
potential
toxicity,
solutions
accompanied
with
intense
consumption,
causing
carbon
dioxide
emissions,
disagreement
circular
economy
principles.
review
provides
critical
assessment
both
published
research
articles
and
patents
derive
broad
picture
on
sustainability
technologies.
Although
efficiency
industrially
applied
exhibit
high
overall
efficiency,
their
general
process
design
generally
based
waste
reduction
downcycling.
Contrariwise,
sustainable
should
rely
ensuring
upcycling
all
materials
toward
zero
minimized
utilization.
Current
expected
development
presented,
ranging
from
dismantling
over
components
separation
bioderived
materials.