National Science Review, Год журнала: 2024, Номер 12(1)
Опубликована: Дек. 6, 2024
Язык: Английский
Advanced Functional Materials, Год журнала: 2025, Номер unknown
Опубликована: Март 10, 2025
Abstract Cascade electrochemical‐chemical coupling (CECC) involves sequential electrochemical and chemical reactions, using intermediates from processes as reactants for subsequent transformations to enhance the efficiency selectivity sustainable syntheses of complex chemicals. Despite its economic environmental benefits, CECC still faces multiple challenges, including a low utilization intermediate reactants, competitive side difficulties in design scale‐up catalysts, leading yield. To ensure economically viable CECC, it is imperative rationally develop cost‐efficient high‐performance such carbon‐based metal‐free electrocatalysts (C‐MFECs) certain carbon‐supported transition metal with high activity atomic precision desirable products. In this review, an overview recent advancements doping C‐MFECs provided enhancing their catalytic toward CECC. Three major systems based on are discussed; they hydrogen peroxide coupling, carbon dioxide upgrading, redox‐mediated systems. Current challenges future perspectives emerging field also addressed.
Язык: Английский
Процитировано
1
Chemical Society Reviews, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
This review highlights organo-mediators that enable electrochemical reactions via outer-sphere electron transfer (ET), offering advantages such as availability, tunability, and simplified post-processing compared to direct electrolysis.
Язык: Английский
Процитировано
1
Chinese Journal of Organic Chemistry, Год журнала: 2025, Номер 45(3), С. 1040 - 1040
Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
1
Molecular Catalysis, Год журнала: 2025, Номер 574, С. 114887 - 114887
Опубликована: Янв. 30, 2025
Язык: Английский
Процитировано
0
Green Carbon, Год журнала: 2025, Номер unknown
Опубликована: Фев. 1, 2025
Язык: Английский
Процитировано
0
National Science Review, Год журнала: 2025, Номер 12(5)
Опубликована: Март 27, 2025
Язык: Английский
Процитировано
0
Angewandte Chemie, Год журнала: 2025, Номер unknown
Опубликована: Апрель 7, 2025
Abstract Despite being widely available, the broad utilization of CO 2 for chemical production remains in its infancy. The difficulty using as an important resource industry lies high stability molecule and associated inertia. In this work, we demonstrate how to overcome these limitations by utilizing a solid oxide electrolysis cell (SOEC) with optimized cathode produce dry through high‐temperature . We further integrate process synthesis setup continuous‐flow coil reactor boost reactivity various carbonylation processes, including amino‐, alkoxy‐, phenoxycarbonylation, carbonylative Sonogashira couplings, or redox‐active esters. Ultimately, our approach offers platform strategy rapid, scalable, continuous carbonyl compounds directly from while eliminating requirement storing large quantities.
Язык: Английский
Процитировано
0
Angewandte Chemie International Edition, Год журнала: 2025, Номер unknown
Опубликована: Апрель 7, 2025
Abstract Despite being widely available, the broad utilization of CO 2 for chemical production remains in its infancy. The difficulty using as an important resource industry lies high stability molecule and associated inertia. In this work, we demonstrate how to overcome these limitations by utilizing a solid oxide electrolysis cell (SOEC) with optimized cathode produce dry through high‐temperature . We further integrate process synthesis setup continuous‐flow coil reactor boost reactivity various carbonylation processes, including amino‐, alkoxy‐, phenoxycarbonylation, carbonylative Sonogashira couplings, or redox‐active esters. Ultimately, our approach offers platform strategy rapid, scalable, continuous carbonyl compounds directly from while eliminating requirement storing large quantities.
Язык: Английский
Процитировано
0
Chem, Год журнала: 2025, Номер unknown, С. 102503 - 102503
Опубликована: Апрель 1, 2025
Язык: Английский
Процитировано
0
Journal of the American Chemical Society, Год журнала: 2025, Номер unknown
Опубликована: Апрель 22, 2025
Palladium-catalyzed bond-forming reactions such as carbonylations offer an efficient and versatile avenue to access products from often feedstock reagents. However, the use of catalysts also comes with a cost, their need be regenerated after each product-forming cycle requires balancing thermal operations. The latter can lead high barriers even well restrict application many products. We introduce herein alternative approach palladium catalyst design, where instead electrochemical potential drive catalysis by continual two-electron cycling metal oxidation state. power behind these redox steps offers route carry out carbonylation reactions, including catalytic synthesis high-energy aroyl halide electrophiles, at unprecedentedly mild ambient temperature pressure. More generally, analysis suggests this functions distinct multi-electron exchange pathway, reduction enables oxidative addition drives product elimination. combination creates unique platform both reverse operations are favored in same system energy only added source.
Язык: Английский
Процитировано
0