Natural pentafuranosylnucleos(t)ides and their analogs: structure, functions, synthesis, and perspective of medical application DOI Creative Commons

Dmitrii Platov,

А. Н. Козлова, Cyril S. Alexeev

и другие.

Опубликована: Май 29, 2025

Pentafuranosylnucleos(t)ides represent a class of natural compounds regulating diverse cell functions being preferably components biopolymers and also participating as cyclic regulatory low-molecular ligands. Disaccharide nucleosides related analogs are considered therapeutically potent for the treatment cancer, viral diseases, variety metabolic disorders by mimicking structure biochemically occurring molecules in nicotinamide adenine dinucleotide (NAD+) transformation. Several approaches have been developed on way to chemical synthesis poly(adenosine diphosphate ribose) (PAR), unique biopolymer taking part DNA repair associated functions, that would allow extensive studies molecular mechanisms diseases. The present review consists following main parts, first one including structural characterization, biochemical roles, disaccharide from different sources their basis, second describing therapeutic applications analogs. General conclusion perspectives summarized last part.

Язык: Английский

TIR domains produce histidine-ADPR as an immune signal in bacteria DOI

Dziugas Sabonis,

Carmel Avraham, Renee B. Chang

и другие.

Nature, Год журнала: 2025, Номер unknown

Опубликована: Апрель 30, 2025

Язык: Английский

Процитировано

1

Self-sacrificing cell death to thwart phage infection DOI

Andrea Du Toit

Nature Reviews Microbiology, Год журнала: 2025, Номер unknown

Опубликована: Фев. 13, 2025

Язык: Английский

Процитировано

0

Chemical inhibition of a bacterial immune system DOI Creative Commons
Zhiyu Zang,

Olivia K. Duncan,

Dziugas Sabonis

и другие.

Опубликована: Фев. 21, 2025

Abstract The rise of antibiotic resistance motivates a revived interest in phage therapy. However, bacteria possess dozens anti-bacteriophage immune systems that confer to therapeutic phages. Chemical inhibitors these anti-phage could be employed as adjuvants overcome phage-based therapies. Here, we report can selectively inhibited by small molecules, thereby sensitizing phage-resistant We discovered class chemical inhibit the type II Thoeris system. These block biosynthesis histidine-ADPR intracellular ‘alarm’ signal ThsB and prevent ThsA from arresting replication. promiscuously diverse bacteria—including antibiotic-resistant pathogens. inhibition defense improved efficacy model therapy against strain P. aeruginosa mouse infection, suggesting potential. Furthermore, may tools dissect importance system for natural microbial communities.

Язык: Английский

Процитировано

0

Proteome-wide discovery of phage anti-defense proteins by Alphafold2 DOI
Zhifu Han, Yu Cao, Jijie Chai

и другие.

Molecular Cell, Год журнала: 2025, Номер 85(6), С. 1052 - 1053

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0

Cat1 forms filament networks to degrade NAD + during the type III CRISPR-Cas antiviral response DOI
Christian F. Baca, Puja Majumder, James H. Hickling

и другие.

Science, Год журнала: 2025, Номер unknown

Опубликована: Апрель 10, 2025

Type III CRISPR-Cas systems defend against viral infection in prokaryotes using an RNA-guided complex that recognizes foreign transcripts and synthesizes cyclic oligo-adenylate (cOA) messengers to activate CARF immune effectors. Here we investigated a protein containing domain fused Toll/interleukin-1 receptor (TIR) domain, Cat1. We found Cat1 provides immunity by cleaving depleting NAD + molecules from the infected host, inducing growth arrest prevents propagation. forms dimers stack upon each other generate long filaments are maintained bound cOA ligands, with stacked TIR domains forming cleavage catalytic sites. Further, assemble into unique trigonal pentagonal networks enhance degradation. presents unprecedented chemistry higher-order assembly for response.

Язык: Английский

Процитировано

0

Recognition-Dependent Activation of the Rrs1/Rps4 Immune Receptor Complex DOI
Heekyung Ahn, Guanghao Guo, Jan Sklenář

и другие.

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0

Natural pentafuranosylnucleos(t)ides and their analogs: structure, functions, synthesis, and perspective of medical application DOI Creative Commons

Dmitrii Platov,

А. Н. Козлова, Cyril S. Alexeev

и другие.

Опубликована: Май 29, 2025

Pentafuranosylnucleos(t)ides represent a class of natural compounds regulating diverse cell functions being preferably components biopolymers and also participating as cyclic regulatory low-molecular ligands. Disaccharide nucleosides related analogs are considered therapeutically potent for the treatment cancer, viral diseases, variety metabolic disorders by mimicking structure biochemically occurring molecules in nicotinamide adenine dinucleotide (NAD+) transformation. Several approaches have been developed on way to chemical synthesis poly(adenosine diphosphate ribose) (PAR), unique biopolymer taking part DNA repair associated functions, that would allow extensive studies molecular mechanisms diseases. The present review consists following main parts, first one including structural characterization, biochemical roles, disaccharide from different sources their basis, second describing therapeutic applications analogs. General conclusion perspectives summarized last part.

Язык: Английский

Процитировано

0