Mechanism Investigation of the Synergistically Enhanced Performance of Carbon-Based Perovskite Solar Cells Utilizing Coal-Derived Multilayer Graphene with NiOx DOI

Ke Zhao,

Qixu Hu,

Zhenwu Zhong

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2025, Номер unknown

Опубликована: Июнь 3, 2025

The efficiency of carbon-based perovskite solar cells (C-PSCs) still significantly lags behind that metal-based devices due to the substantial interfacial resistance and energy level mismatch between carbon electrodes (CE) material. Herein, we present construction a carrier highway utilizing coal-derived multilayered graphene (MG) embedded with NiOx as hole-transport layer (HTL). This approach aims optimize alignment enhance contact, thereby improving quality film. Due its unique multilayer structure abundant oxygen-containing functional groups, MG synergized HTL not only provides well-aligned band configurations facilitate charge separation extraction but also acts Lewis base form coordination bonds uncoordinated lead ions by sharing electron pairs, reducing surface defects minimizing recombination losses at perovskite/CE interface, ultimately alleviating fill factor (FF) loss. As result, power conversion (PCE) FTO/SnO2/MAPbI3/MG + NiOx/Carbon structured device achieved 18.10%, representing significant enhancement 19.3% compared 15.17% for pristine device. study presents novel strategy enhancing overall performance C-PSCs through utilization cost-effective environmentally sustainable materials derived from coal.

Язык: Английский

Integration of Perovskite/Low‐Dimensional Material Heterostructures for Optoelectronics and Artificial Visual Systems DOI Creative Commons
Yingge Du, Junjie Yang, Ziyu Lv

и другие.

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 14, 2025

Abstract Heterojunctions combining halide perovskites with low‐dimensional materials are revolutionizing optoelectronic device design by leveraging complementary properties. Halide perovskites, known for their tunable bandgaps, excellent light‐harvesting, and efficient charge carrier mobility, provide a robust foundation photodetectors (PDs) imaging sensors. Low‐dimensional contribute ultrafast enhanced light‐matter interactions, mechanical flexibility. When integrated into heterostructures, these enable precise control over dynamics, leading to significant improvements in efficiency, stability, response speed. This synergy addresses critical challenges optoelectronics, advancing flexible electronics, wearable sensors, high‐sensitivity systems. Ongoing advancements interface engineering material synthesis continually enhancing the reliability operational efficacy of devices across various environmental conditions. Additionally, heterostructures show substantial promise neuromorphic computing, where properties support energy‐efficient, event‐driven data processing. By mimicking adaptive hierarchical nature biological visual systems, they offer new possibilities real‐time image analysis intelligent decision‐making. review highlights latest developments perovskite‐based heterojunctions transformative role bridging gap between artificial vision, driving technologies such as robotics bio‐inspired

Язык: Английский

Процитировано

0

Data-Mining-Aided-Material Design of Doped LaMnO3 Perovskites with Higher Curie Temperature DOI Open Access

Lumin Tian,

Wentan Wang,

Xiaobo Ji

и другие.

Materials, Год журнала: 2025, Номер 18(11), С. 2437 - 2437

Опубликована: Май 23, 2025

The Curie temperature (Tc) of LaMnO3-based perovskites is one the most important properties associated with their magnetic and spintronic applications. search for new even higher Tc a challenging problem in material design. Through systematic optimization support vector regression (SVR) architecture, we establish predictive framework determining doped LaMnO3 perovskites, leveraging fundamental atomic descriptors. correlation coefficient (R) between predicted experimental temperatures demonstrated high values 0.9111 when evaluated through leave-one-out cross-validation (LOOCV) approach, while maintaining robust 0.8385 on independent test set. subsequent high-throughput screening perovskite compounds exhibiting was implemented via our online computation platform materials data mining (OCPMDM), enabling rapid identification candidate protocols. findings demonstrate that machine learning exhibits significant efficacy cost-effectiveness identifying lanthanum manganite elevated Tc, as validated comparative computational empirical analyses. Furthermore, web-based infrastructure global dissemination framework, open-access deployment model.

Язык: Английский

Процитировано

0

Intermediate‐Phase Homogenization Through Intermolecular Interactions Toward Reproducible Fabrication of Perovskite Solar Cells DOI

Yan Zhu,

Xinyi Liu, Xinyuan Sui

и другие.

Advanced Energy Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 21, 2025

Abstract Perovskite solar cells, known for high efficiency, low‐cost production, and excellent optoelectronics, have drawn significant interest in the photovoltaic research community. However, fabrication of these devices faces challenges environmental sensitivity variability during manufacturing processes, leading to unsatisfied product yield. Herein, an intermediate‐phase homogenization approach is presented regulate multi‐phase evolution film formation by using tris(2‐benzimidazolylmethyl)amine (TR‐2‐BA) additive. It shown that intermolecular interaction TR‐2‐BA solvent molecules effectively inhibits diverse solvated intermediates, like PbI 2 ·Dimethyl sulfoxide (PbI ·DMSO) δ phase, thereby results homogenizing (Formamidinium) ·Pb 3 I 8 ·2DMSO ((FA) ·2DMSO) intermediate which enhances consistency nucleation growth behaviors. The controlled dynamics improve uniformity crystallinity, along with a notable reduction defect density. Consequently, fabricated achieve fill factor (FF) up 84.73% power conversion efficiency (PCE) 25.24%. Statistical from 120 prepared across different batches seasons present strategy decreases standard deviation device 0.74% 0.38%. This work provides novel reproducible high‐quality perovskite cells under varying conditions.

Язык: Английский

Процитировано

0

Transforming Near-Infrared Photodetectors with Perovskites: Materials, Strategies, and Future Outlook DOI

Ruizhi Xu,

Xin Yu Chin,

Luke R. W. White

и другие.

Energy & Fuels, Год журнала: 2025, Номер unknown

Опубликована: Июнь 2, 2025

Язык: Английский

Процитировано

0

Mechanism Investigation of the Synergistically Enhanced Performance of Carbon-Based Perovskite Solar Cells Utilizing Coal-Derived Multilayer Graphene with NiOx DOI

Ke Zhao,

Qixu Hu,

Zhenwu Zhong

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2025, Номер unknown

Опубликована: Июнь 3, 2025

The efficiency of carbon-based perovskite solar cells (C-PSCs) still significantly lags behind that metal-based devices due to the substantial interfacial resistance and energy level mismatch between carbon electrodes (CE) material. Herein, we present construction a carrier highway utilizing coal-derived multilayered graphene (MG) embedded with NiOx as hole-transport layer (HTL). This approach aims optimize alignment enhance contact, thereby improving quality film. Due its unique multilayer structure abundant oxygen-containing functional groups, MG synergized HTL not only provides well-aligned band configurations facilitate charge separation extraction but also acts Lewis base form coordination bonds uncoordinated lead ions by sharing electron pairs, reducing surface defects minimizing recombination losses at perovskite/CE interface, ultimately alleviating fill factor (FF) loss. As result, power conversion (PCE) FTO/SnO2/MAPbI3/MG + NiOx/Carbon structured device achieved 18.10%, representing significant enhancement 19.3% compared 15.17% for pristine device. study presents novel strategy enhancing overall performance C-PSCs through utilization cost-effective environmentally sustainable materials derived from coal.

Язык: Английский

Процитировано

0