Targeting with structural analogs of natural products the purine salvage pathway inLeishmania (Leishmania) infantumby computer-aided drug design approaches DOI Creative Commons
Haruna Luz Barazorda-Ccahuana, Eymi Gladys Cárcamo-Rodriguez, Angela Emperatriz Centeno-Lopez

и другие.

bioRxiv (Cold Spring Harbor Laboratory), Год журнала: 2023, Номер unknown

Опубликована: Ноя. 29, 2023

Abstract Visceral Leishmaniasis (VL) has a high death rate with 500,000 new cases and 50,000 deaths occurring annually. Despite the development of novel strategies technologies, there is no adequate treatment for disease. Therefore, purpose this study to find structural analogs natural products as potential drugs treat VL. To choose from that have demonstrated anti-leishmanial anti-adenine phosphoribosyltransferase (APRT) properties, might bind several targets purine salvage pathway, we used computer-aided drug design (CADD) techniques. Computational techniques were pathway Leishmania infantum , molecular dynamic simulations gather information on interactions between ligands proteins. An analog alkaloid Skimmianine, N,N-diethyl-4-methoxy-1-benzofuran-6-carboxamide, good binding affinity two L. targets, expected toxicity, oral route administration. This indicates compounds may activity, which granted in vitro vivo experiments settle finding future.

Язык: Английский

Navigating the Chemical Space and Chemical Multiverse of a Unified Latin American Natural Product Database: LANaPDB DOI Creative Commons
Alejandro Gómez‐García, Daniel A. Acuña Jiménez, William J. Zamora

и другие.

Pharmaceuticals, Год журнала: 2023, Номер 16(10), С. 1388 - 1388

Опубликована: Сен. 30, 2023

The number of databases natural products (NPs) has increased substantially. Latin America is extraordinarily rich in biodiversity, enabling the identification novel NPs, which encouraged both development and implementation those that are being created or under development. In a collective effort from several American countries, herein we introduce first version Natural Products Database (LANaPDB), public compound collection gathers chemical information NPs contained diverse this geographical region. current LANaPDB unifies six countries contains 12,959 structures. structural classification showed most abundant compounds terpenoids (63.2%), phenylpropanoids (18%) alkaloids (11.8%). From analysis distribution properties pharmaceutical interest, it was observed many satisfy some drug-like rules thumb for physicochemical properties. concept multiverse employed to generate multiple spaces two different fingerprints dimensionality reduction techniques. Comparing with FDA-approved drugs major open-access repository COCONUT, concluded space covered by completely overlaps COCONUT and, regions, drugs. will be updated, adding more each database, plus addition other countries.

Язык: Английский

Процитировано

16

Computer-aided drug design approaches applied to screen natural product’s structural analogs targeting arginase in Leishmania spp DOI Creative Commons
Haruna Luz Barazorda-Ccahuana, Luis Daniel Goyzueta-Mamani, Mayron Antonio Candia-Puma

и другие.

F1000Research, Год журнала: 2023, Номер 12, С. 93 - 93

Опубликована: Май 24, 2023

Introduction: Leishmaniasis is a disease with high mortality rates and approximately 1.5 million new cases each year. Despite the approaches advances to fight disease, there are no effective therapies. Methods: Hence, this study aims screen for natural products' structural analogs as drug candidates against leishmaniasis. We applied Computer-aided design (CADD) approaches, such virtual screening, molecular docking, dynamics simulation, mechanics-generalized Born surface area (MM-GBSA) binding free estimation, energy perturbation (FEP) aiming select from products that have shown anti-leishmanial anti-arginase activities could bind selectively Leishmania arginase enzyme. Results: The compounds 2H-1-benzopyran, 3,4-dihydro-2-(2-methylphenyl)-(9CI), echioidinin, malvidin showed good results targets three parasite species negative potential toxicities. echioidinin ligands generated interactions in active center at pH 2.0 conditions by MM-GBSA FEP methods. Conclusions: This work suggests activity of thus can be further vitro vivo experimentally validated.

Язык: Английский

Процитировано

10

Targeting with Structural Analogs of Natural Products the Purine Salvage Pathway in Leishmania (Leishmania) infantum by Computer-Aided Drug-Design Approaches DOI Creative Commons
Haruna Luz Barazorda-Ccahuana, Eymi Gladys Cárcamo-Rodriguez, Angela Emperatriz Centeno-Lopez

и другие.

Tropical Medicine and Infectious Disease, Год журнала: 2024, Номер 9(2), С. 41 - 41

Опубликована: Фев. 3, 2024

Visceral Leishmaniasis (VL) has a high death rate, with 500,000 new cases and 50,000 deaths occurring annually. Despite the development of novel strategies technologies, there is no adequate treatment for disease. Therefore, purpose this study to find structural analogs natural products as potential drugs treat VL. We selected from that have shown antileishmanial activities, may impede purine salvage pathway using computer-aided drug-design (CADD) approaches. For these, we started vastly studied target in pathway, adenine phosphoribosyl transferase (APRT) protein, which alone non-essential survival parasite. Keeping mind, search substance can bind multiple targets throughout pathway. Computational techniques were used Leishmania infantum, molecular dynamic simulations gather information on interactions between ligands proteins. Because its low homology human proteins essential role network interaction, findings further highlight significance adenylosuccinate lyase protein (ADL) therapeutic target. An analog alkaloid Skimmianine, N,N-diethyl-4-methoxy-1-benzofuran-6-carboxamide, demonstrated good binding affinity APRT ADL targets, expected toxicity, oral route administration. This indicates compound activity, was granted vitro vivo experiments settle finding future.

Язык: Английский

Процитировано

3

Exploring the Potential of Malvidin and Echiodinin as Probable Antileishmanial Agents Through In Silico Analysis and In Vitro Efficacy DOI Creative Commons
Luis Daniel Goyzueta-Mamani, Daniela P. Lage, Haruna Luz Barazorda-Ccahuana

и другие.

Molecules, Год журнала: 2025, Номер 30(1), С. 173 - 173

Опубликована: Янв. 4, 2025

Leishmaniasis, a neglected tropical disease caused by Leishmania species, presents serious public health challenges due to limited treatment options, toxicity, high costs, and drug resistance. In this study, the in vitro potential of malvidin echioidinin is examined as antileishmanial agents against L. amazonensis, braziliensis, infantum, comparing their effects amphotericin B (AmpB), standard drug. Malvidin demonstrated greater potency than across all parasite stages species. Against malvidin’s IC50 values were 197.71 ± 17.20 µM (stationary amastigotes) 258.07 17 (axenic amastigotes), compared echioidinin’s 272.99 29.90 μM 335.96 19.35 μM. AmpB was more potent, with 0.06 0.01 0.10 0.03 µM. exhibited lower cytotoxicity (CC50: 2920.31 80.29 µM) (1.06 0.12 favorable selectivity index. It reduced infection rates 35.75% amazonensis-infected macrophages. The silico analysis revealed strong binding between arginase, residues HIS139 PRO258 playing key roles. Gene expression indicated modulation oxidative stress DNA repair pathways, involving genes like GLO1 APEX1. These findings suggest safe, natural compound, warranting further vivo studies confirm its therapeutic efficacy pharmacokinetics animal models.

Язык: Английский

Процитировано

0

The latest progress in assay development in leishmaniasis drug discovery: a review of the available papers on PubMed from the past year DOI
G. Santos, Adriano C. Coelho, Juliana Quero Reimão

и другие.

Expert Opinion on Drug Discovery, Год журнала: 2025, Номер unknown

Опубликована: Янв. 6, 2025

Leishmaniasis is a significant neglected tropical disease with limited treatment options that urgently requires ongoing efforts in drug discovery. Recent advances have focused on the development of new assays and methods to identify effective therapeutic candidates.

Язык: Английский

Процитировано

0

Evaluation of the Antileishmanial Activity of Some Benzimidazole Derivatives Using In Vitro and In Silico Techniques DOI Creative Commons
Mustafa Eser, İbrahim Çavuş, Aybüke Züleyha Kaya

и другие.

Veterinary Sciences, Год журнала: 2025, Номер 12(6), С. 550 - 550

Опубликована: Июнь 5, 2025

Benzimidazole derivatives are well known for their anthelmintic activity. Investigating the potential efficacy of new this class against various parasites is essential to identify novel drug candidates. For purpose, an in-house molecular database was screened, and four benzimidazole-based molecules were chosen evaluate antiprotozoal The compounds (K1–K4) had been previously synthesized through a four-step procedure. in vitro cytotoxic properties assessed Leishmania (L.) major strain L929 mouse fibroblast cells. tests indicated that K1 (3-Cl phenyl) demonstrated antileishmanial effect (IC50 = 0.6787 µg/mL) cytotoxicity at elevated concentrations (CC50 250 healthy These findings comparable those AmpB. activity values determined as follows: K2; 8.89 µg/mL, K3; 45.11 K4; 69.19 µg/mL. CC50 K2, 63 µg/mL; 0.56 K4, 292 Molecular docking dynamic simulations conducted elucidate mechanisms action test substances. In silico investigations interactions between active site pteridine reductase 1 (PTR1), which biosynthetic enzyme parasite proliferation. N-alkyl exhibit inhibitory L. promastigotes. Therefore, these suggest vivo evaluation warranted, structural modifications may lead identification more effective agents.

Язык: Английский

Процитировано

0

Targeting Leishmania infantum Mannosyl-oligosaccharide glucosidase with natural products: potential pH-dependent inhibition explored through computer-aided drug design DOI Creative Commons
Luis Daniel Goyzueta-Mamani, Haruna Luz Barazorda-Ccahuana, Mayron Antonio Candia-Puma

и другие.

Frontiers in Pharmacology, Год журнала: 2024, Номер 15

Опубликована: Май 30, 2024

Visceral Leishmaniasis (VL) is a serious public health issue, documented in more than ninety countries, where an estimated 500,000 new cases emerge each year. Regardless of novel methodologies, advancements, and experimental interventions, therapeutic limitations, drug resistance are still challenging. For this reason, based on previous research, we screened natural products (NP) from Nuclei Bioassays, Ecophysiology, Biosynthesis Natural Products Database (NuBBE DB) , Mexican Compound (BIOFACQUIM), Peruvian (PeruNPDB) databases, addition to structural analogs Miglitol Acarbose, which have been suggested as treatments for VL shown encouraging action against parasite’s N-glycan biosynthesis. Using computer-aided design (CADD) approaches, the potential inhibitory effect these NP candidates was evaluated by inhibiting Mannosyl-oligosaccharide Glucosidase Protein (MOGS) Leishmania infantum enzyme essential protein glycosylation process, at various pH mimic changing environment. Also, computational analysis used evaluate Absorption, Distribution, Metabolism, Excretion, Toxicity (ADMET) profile, while molecular dynamic simulations were gather information interactions between ligands target. Our findings indicated that Ocotillone Subsessiline antileishmanial effects 5 7, respectively, due their high binding affinity MOGS active center. Furthermore, compounds non-toxic had be administered orally. This research indicates promising anti-leishmanial activity Subsessiline, suggesting further validation through vitro vivo experiments.

Язык: Английский

Процитировано

2

Exploring the Potential of Malvidin and Echiodinin as Probable Antileishmanial Agents Through In Silico Analysis And In Vitro Efficacy DOI Creative Commons
Luis Daniel Goyzueta-Mamani, Daniela P. Lage, Haruna Luz Barazorda-Ccahuana

и другие.

bioRxiv (Cold Spring Harbor Laboratory), Год журнала: 2024, Номер unknown

Опубликована: Окт. 4, 2024

Abstract Leishmaniasis is a neglected tropical disease, caused by distinct Leishmania species, which have significant public health challenges due to treatment limitations such as toxicity, high cost, and drug resistance. This study explores the in vitro potential of Malvidin Echioidinin probable antileishmanial agents against amazonensis , L. braziliensis infantum comparing their efficacy Amphotericin B (AmpB), standard drug. was more potent than across all parasite stages species. For Malvidin’s inhibitory concentration (IC 50 ) values were 197.71±17.20 µM 258.07±17 (stationary axenic amastigotes, respectively); whereas revealed IC 272.99±29.90 μM 335.96±19.35 respectively). AmpB showed 0.06±0.01 0.10±0.03 µM, respectively. demonstrated lower cytotoxicity activity mammalian cells with cytotoxic (CC value 2,920.31±80.29 while AmpB’s 1.06±0.12 µM. also exhibited favorable selectivity index (SI) values. reduced infection rates up 35.75% -infected macrophages. In silico analysis uncovered strong binding interactions between enzyme arginase three key residues HIS139 PRO258 playing crucial role. Tissue-specific markers expression highlighted modulation genes involved oxidative stress DNA repair, including glyoxalase 1 (GLO1) apurinic/apyrimidinic endodeoxyribonuclease (APEX1). The data corroborate hypothesis that safe can control parasites new natural compound for treatment. To further assess its therapeutic potential, vivo studies are required evaluate efficacy, safety, pharmacokinetics animal models, will be essential validating role candidate leishmaniasis

Язык: Английский

Процитировано

0

TargetingLeishmania infantumMannosyl-oligosaccharide glucosidase with natural products: pH-dependent inhibition explored through computer-aided drug design DOI Creative Commons
Luis Daniel Goyzueta-Mamani, Haruna Luz Barazorda-Ccahuana, Mayron Antonio Candia-Puma

и другие.

bioRxiv (Cold Spring Harbor Laboratory), Год журнала: 2024, Номер unknown

Опубликована: Март 16, 2024

Abstract Visceral Leishmaniasis (VL) is a serious public health issue, documented in more than ninety countries, where an estimated 500,000 new cases emerge each year. Regardless of novel methodologies, advancements, and experimental interventions, therapeutic limitations, drug resistance are still challenging. For this reason, based on previous research, we screened natural products (NP) from Nuclei Bioassays, Ecophysiology, Biosynthesis Natural Products Database (NuBBEDB), Mexican Compound (BIOFACQUIM), Peruvian (PeruNPDB) databases, addition to structural analogs Miglitol Acarbose, which have been suggested as treatments for VL shown encouraging action against parasite’s N-glycan biosynthesis. Using computer-aided design (CADD) approaches, the inhibitory effect these NP candidates was evaluated by inhibiting Mannosyl-oligosaccharide Glucosidase Protein (MOGS) Leishmania infantum , enzyme essential protein glycosylation process, at various pH mimic changing environment. Also, computational analysis used evaluate Absorption, Distribution, Metabolism, Excretion, Toxicity (ADMET) profile, while molecular dynamic simulations were gather information interactions between ligands target. Our findings indicated that Ocotillone Subsessiline potential antileishmanial effects 5 7, respectively, due their high binding affinity MOGS active center. Furthermore, compounds non-toxic had be administered orally. This research indicates promising anti-leishmanial activity Subsessiline, suggesting further validation through vitro vivo experiments.

Язык: Английский

Процитировано

0

Targeting with structural analogs of natural products the purine salvage pathway inLeishmania (Leishmania) infantumby computer-aided drug design approaches DOI Creative Commons
Haruna Luz Barazorda-Ccahuana, Eymi Gladys Cárcamo-Rodriguez, Angela Emperatriz Centeno-Lopez

и другие.

bioRxiv (Cold Spring Harbor Laboratory), Год журнала: 2023, Номер unknown

Опубликована: Ноя. 29, 2023

Abstract Visceral Leishmaniasis (VL) has a high death rate with 500,000 new cases and 50,000 deaths occurring annually. Despite the development of novel strategies technologies, there is no adequate treatment for disease. Therefore, purpose this study to find structural analogs natural products as potential drugs treat VL. To choose from that have demonstrated anti-leishmanial anti-adenine phosphoribosyltransferase (APRT) properties, might bind several targets purine salvage pathway, we used computer-aided drug design (CADD) techniques. Computational techniques were pathway Leishmania infantum , molecular dynamic simulations gather information on interactions between ligands proteins. An analog alkaloid Skimmianine, N,N-diethyl-4-methoxy-1-benzofuran-6-carboxamide, good binding affinity two L. targets, expected toxicity, oral route administration. This indicates compounds may activity, which granted in vitro vivo experiments settle finding future.

Язык: Английский

Процитировано

0