Опубликована: Дек. 6, 2023

Dimers and oligomers of alkenes represent a category compounds that are in great demand for diverse industrial sectors. Among the developing synthetic methods, catalysis alkene dimerization oligomerization using transition metal salts complexes is undoubted interest practical application. This approach demonstrates substantial potential, offering not only elevated reaction rates but also precise control over chemo-, regio-, stereoselectivity reactions. In this review, we discuss data on catalytic systems oligomerization. Our focus lies analysis how activity chemoselectivity these influenced by various factors, such as nature metal, ligand environment, activator, substrate structure. Notably, review particularly discusses mechanisms, encompassing complex activation, structural dynamic features, reactivity hydride intermediates, which serve potential catalytically active centers

Язык: Английский