Опубликована: Янв. 25, 2024

A enantioselective tandem transformation concerning asymmetric allylic decarboxylative addition and cyclization of N-nosylimines with vinylethylene carbonates (VECs) in the presence [Rh(C2H4)2Cl]2, chiral sulfoxide-N-olefin tridentate ligand has been developed. The reaction VECs various substituted proceeded smoothly under mild conditions, giving highly functionalized oxazolidine frameworks good to high yields excellent enantioselectivity.

Язык: Английский