Aqueous Micellar Environment Impacts the Co-Catalyzed Phototransformation: A Case Study DOI Creative Commons
Aleksandra Wincenciuk, Piotr Cmoch, Maciej Giedyk

и другие.

Опубликована: Фев. 20, 2024

In recent years, methodologies that rely on water as the reaction medium have gained considerable attention. The unique properties of micellar solutions were shown to improve regio-, stereo-, and chemoselectivity different transformations. Herein, we demonstrate aqueous environment is a suitable for visible light driven cobalt-catalyzed involving radical species. this system, reduced vitamin B12 reacts with alkyl halides, gen-erating radicals are trapped by lipophilic olefin present in Stern layer. A series NMR measurements theoretical studies revealed location components system.

Язык: Английский

Aqueous Micellar Environment Impacts the Co-Catalyzed Phototransformation: A Case Study DOI Creative Commons
Aleksandra Wincenciuk, Piotr Cmoch, Maciej Giedyk

и другие.

Опубликована: Фев. 20, 2024

In recent years, methodologies that rely on water as the reaction medium have gained considerable attention. The unique properties of micellar solutions were shown to improve regio-, stereo-, and chemoselectivity different transformations. Herein, we demonstrate aqueous environment is a suitable for visible light driven cobalt-catalyzed involving radical species. this system, reduced vitamin B12 reacts with alkyl halides, gen-erating radicals are trapped by lipophilic olefin present in Stern layer. A series NMR measurements theoretical studies revealed location components system.

Язык: Английский

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