Sulfite Pretreatment Enhances Tobacco Stalk Deconstruction for Cellulose Saccharification and Lignin Pyrolysis DOI Open Access
Dong Li, Rui Wu, Sheng Zhang

и другие.

Catalysts, Год журнала: 2024, Номер 14(12), С. 889 - 889

Опубликована: Дек. 4, 2024

Sulfite-catalyzed acid pretreatment to overcome the inherent recalcitrance of biomass offers a significant advantage in terms obtaining high glucose conversion. However, residual lignin after enzymatic hydrolysis has not been fully exploited. Herein, this study introduced joint approach using sulfite-catalyzed (SPROL) and pyrolysis upgrade tobacco stalk produce fermentable sugar, resulting is used bio-oil bio-char. The results suggest that SPROL pretreated yields cellulose-based selectivity 75.9% with 15 FPU/g substrate enzyme dosage at 50 °C 72 h enzymolysis. Lignin characterization reveals sulfonation occurred during pretreatment, as sulfonating agent increased, thermal stability residue decreased. After sample 600 for 30 min, approximately 22%, 33%, 45% undergoes conversion into bio-oil, bio-char, gas products, respectively. analysis demonstrated acetic most abundant identified GC-MS component around 69.91% optimal condition, which implied it could be value when utilized pyroligneous acid. This research provides synthetic SPORL technique process commercial utilization agricultural waste value-added products.

Язык: Английский

Optimized steam explosion treatment of tobacco stems for enhanced extraction of solanesol and nicotine DOI Creative Commons
Zixin Wang,

Jimin Li,

Hui Yang

и другие.

Industrial Crops and Products, Год журнала: 2025, Номер 225, С. 120470 - 120470

Опубликована: Янв. 10, 2025

Язык: Английский

Процитировано

0

Efficient removal of lignin in tobacco stems with choline chloride-based deep eutectic solvents DOI Creative Commons

Sai‐Bo Yu,

Bo Qiu,

Yong Ju Jin

и другие.

Industrial Crops and Products, Год журнала: 2025, Номер 226, С. 120634 - 120634

Опубликована: Фев. 5, 2025

Язык: Английский

Процитировано

0

Comparison of the Effects of NaOH and Deep Eutectic Solvent Catalyzed Tobacco Stock Lignin Isolation: Chemical Structure and Thermal Characteristics DOI Open Access
Zhichang Liu, Ziwei Wang, Yichen Li

и другие.

Catalysts, Год журнала: 2024, Номер 14(11), С. 744 - 744

Опубликована: Окт. 23, 2024

Uncovering the structure of lignin from biorefinery has an important effect on catalytic depolymerization and production bioenergy. In this study, two lignins were isolated tobacco stalks via alkaline deep eutectic solvent (DES) catalyzed delignification processes, heterogeneity structural characteristics elucidated by gel permeation chromatography, 2D-HSQC, FT-IR, etc., to understand relationship between thermal lignin. It was found that presented various components, in which predominant interunit linkages black liquor are β-O-4 β-β linkages, disappeared DES treatment. exhibited lower molecular weights yields than Thermogravimetric analysis fixed-bed pyrolysis also performed investigate behavior. The results show approach can improve bio-oil highlight potential as a promising feedstock process. This work provides valuable example conversion into products.

Язык: Английский

Процитировано

1

Sulfite Pretreatment Enhances Tobacco Stalk Deconstruction for Cellulose Saccharification and Lignin Pyrolysis DOI Open Access
Dong Li, Rui Wu, Sheng Zhang

и другие.

Catalysts, Год журнала: 2024, Номер 14(12), С. 889 - 889

Опубликована: Дек. 4, 2024

Sulfite-catalyzed acid pretreatment to overcome the inherent recalcitrance of biomass offers a significant advantage in terms obtaining high glucose conversion. However, residual lignin after enzymatic hydrolysis has not been fully exploited. Herein, this study introduced joint approach using sulfite-catalyzed (SPROL) and pyrolysis upgrade tobacco stalk produce fermentable sugar, resulting is used bio-oil bio-char. The results suggest that SPROL pretreated yields cellulose-based selectivity 75.9% with 15 FPU/g substrate enzyme dosage at 50 °C 72 h enzymolysis. Lignin characterization reveals sulfonation occurred during pretreatment, as sulfonating agent increased, thermal stability residue decreased. After sample 600 for 30 min, approximately 22%, 33%, 45% undergoes conversion into bio-oil, bio-char, gas products, respectively. analysis demonstrated acetic most abundant identified GC-MS component around 69.91% optimal condition, which implied it could be value when utilized pyroligneous acid. This research provides synthetic SPORL technique process commercial utilization agricultural waste value-added products.

Язык: Английский

Процитировано

0