Journal of environmental chemical engineering, Год журнала: 2024, Номер unknown, С. 114413 - 114413
Опубликована: Окт. 1, 2024
Язык: Английский
Journal of environmental chemical engineering, Год журнала: 2024, Номер unknown, С. 114413 - 114413
Опубликована: Окт. 1, 2024
Язык: Английский
Clean Technologies, Год журнала: 2025, Номер 7(1), С. 15 - 15
Опубликована: Фев. 7, 2025
The Mediterranean region faces significant water scarcity, a challenge intensified by climate change, impacting both agricultural productivity and quality. High sodium levels in irrigation compromise soil structure, leading to reduced crop yields economic strain. This study investigates the use of sustainable adsorbents derived from residues (almond shell, eggshell, pumice) for removal water. These materials, widely available Mediterranean, support circular economy principles repurposing biowaste address challenges. Adsorption experiments were conducted using real water, capturing complexity its physicochemical properties evaluate effectiveness these biosorbents under practical conditions. A Central Composite Rotational Design (CCRD) was applied optimize adsorption parameters, focusing on adsorbent concentration, agitation, contact time. Kinetic studies indicated that adhered pseudo-second order model, suggesting chemically controlled process. Isotherm analysis, with strong fit Jovanovic confirmed predominantly monomolecular mechanism across all adsorbents, while Freundlich model highlighted site heterogeneity. Microscopy energy-dispersive X-ray spectroscopy (EDX) revealed structural modifications before after treatment. porous internal structure almond shell displayed retention, calcified eggshell surface showed high initial efficiency but rapid saturation. Pumice, noted extensive porosity, sustained capacity even deposits formed during research demonstrates potential biowaste-derived efficient complex aqueous systems, offering viable solution agriculture improved management regions.
Язык: Английский
Процитировано
0Journal of Water Process Engineering, Год журнала: 2025, Номер 71, С. 107349 - 107349
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
0Research Square (Research Square), Год журнала: 2025, Номер unknown
Опубликована: Апрель 1, 2025
Язык: Английский
Процитировано
0Molecules, Год журнала: 2024, Номер 29(11), С. 2545 - 2545
Опубликована: Май 28, 2024
Efficient boron removal from irrigation waters is crucial for sustainable agriculture, as elevated levels of can be toxic to many plants, limiting growth and crop productivity. In this context, the present study investigated sorption equilibrium using zeolites in two types aqueous matrices: a synthetic solution containing only natural waters. Through application various isothermal models (Langmuir, Freundlich, Sips, Toth, Jovanovic, Temkin, Dubinin–Radushkevich, Redlich–Peterson), efficacy zeolite under controlled real conditions was evaluated. The results indicated notable difference behavior between matrices, reflecting complexity heterogeneity interactions boron–zeolite system. solution, Freundlich model provided best fit (R2 = 0.9917), suggesting heterogeneous multilayer sorption, while Sips showed high describing both evidencing its capability capture complex nature interaction different environmental conditions. However, waters, Jovanovic demonstrated most accurate 0.999), highlighting importance physical sorption. These findings underscore significant influence water matrix on agent, emphasizing need consider specific composition design treatments. Additionally, stress selecting appropriate predict behavior, which developing effective treatment strategies. This provides basis optimizing agricultural industrial applications, contributing more efficient processes.
Язык: Английский
Процитировано
1Journal of environmental chemical engineering, Год журнала: 2024, Номер unknown, С. 114413 - 114413
Опубликована: Окт. 1, 2024
Язык: Английский
Процитировано
1