Atomistic Insight on Effect of Silica Fume on Intermolecular Interactions between Poly(carboxylate) Superplasticizer and Calcium Ions in Concrete DOI Creative Commons

Berik Rakhimbayev,

Б.Н. Мукашев,

P. Kusherova

и другие.

Nanomaterials, Год журнала: 2024, Номер 14(13), С. 1084 - 1084

Опубликована: Июнь 25, 2024

Understanding how poly(carboxylate)s of chemical admixtures interact with calcium ions in cement pore solutions the presence silica fume is fundamental to developing better for concrete production. In this work, intermolecular interactions a poly(carboxylate) superplasticizer type admixture was investigated via classical all-atom molecular dynamics (MD) simulations and Density Functional Theory (DFT) calculation methods fume. The MD simulation DFT results indicate that are interacting oxygen atoms carboxylate group PCE. interaction energy could mean an improved adsorption PCE segment ions. regard, it can be noted ester-based have onto comparison ether-based segment. Moreover, silicon dioxide improve

Язык: Английский

Life cycle assessment of electricity generation by tire pyrolysis oil DOI
Michail Tsangas, Iliana Papamichael,

Pantelitsa Loizia

и другие.

Process Safety and Environmental Protection, Год журнала: 2024, Номер 186, С. 376 - 387

Опубликована: Апрель 8, 2024

Язык: Английский

Процитировано

14

Production of Sustainable Mortar with Sodium Hydroxide Treated Rubber Crumb DOI Creative Commons
Abiodun Kilani, Bolanle Deborah Ikotun, Rasheed Abdulwahab

и другие.

Iranian Journal of Science and Technology Transactions of Civil Engineering, Год журнала: 2025, Номер unknown

Опубликована: Март 10, 2025

Язык: Английский

Процитировано

0

Electrochemical Differences in the Passivity State of Reinforced Concrete for Two Mix Design Methods DOI Creative Commons
Jorge Alberto Briceño-Mena, M. Balancán-Zapata,

Eduardo de Jesus Pérez-García

и другие.

Buildings, Год журнала: 2025, Номер 15(8), С. 1293 - 1293

Опубликована: Апрель 15, 2025

Durable reinforced concrete is a fundamental requirement in marine environment, but at the same time it must be sustainable, meaning its production emits least amount of greenhouse gases. Hence, importance achieving optimal proportioning methods. This paper presents and discusses electrochemical differences passivity state specimens designed using two methods: M1 prioritizes ultimate strength element, M2 focuses on sustainability through optimized aggregate arrangement reduced cement content. Small beams (150 mm × 150 300 mm) with varying cover thickness (15 mm, 20 30 mm), water/cement ratios (0.45 0.65), all utilizing Portland composite (PCC 30R), were exposed tropical environment 50 m from seashore north Yucatan Peninsula for 700 days (passive state). Corrosion rate, corrosion potential, resistivity, internal conditions (relative humidity temperature) periodically measured. A key finding revealed that M2, despite sustainable advantage, tends to depassivation before M1, during years exposure while passive state.

Язык: Английский

Процитировано

0

Development of sustainable HPC using rubber powder and waste wire: carbon footprint analysis, mechanical and microstructural properties DOI Creative Commons
Hasan Mostafaei, Massih Kelishadi, Hadi Bahmani

и другие.

European Journal of Environmental and Civil engineering, Год журнала: 2024, Номер 29(2), С. 399 - 420

Опубликована: Сен. 10, 2024

Язык: Английский

Процитировано

3

Atomistic Insight on Effect of Silica Fume on Intermolecular Interactions between Poly(carboxylate) Superplasticizer and Calcium Ions in Concrete DOI Creative Commons

Berik Rakhimbayev,

Б.Н. Мукашев,

P. Kusherova

и другие.

Nanomaterials, Год журнала: 2024, Номер 14(13), С. 1084 - 1084

Опубликована: Июнь 25, 2024

Understanding how poly(carboxylate)s of chemical admixtures interact with calcium ions in cement pore solutions the presence silica fume is fundamental to developing better for concrete production. In this work, intermolecular interactions a poly(carboxylate) superplasticizer type admixture was investigated via classical all-atom molecular dynamics (MD) simulations and Density Functional Theory (DFT) calculation methods fume. The MD simulation DFT results indicate that are interacting oxygen atoms carboxylate group PCE. interaction energy could mean an improved adsorption PCE segment ions. regard, it can be noted ester-based have onto comparison ether-based segment. Moreover, silicon dioxide improve

Язык: Английский

Процитировано

0