New Journal of Chemistry,
Год журнала:
2023,
Номер
47(24), С. 11425 - 11443
Опубликована: Янв. 1, 2023
Phase
pure
and
mesoporous
Co
3
O
4
crystals
are
designed
via
a
simple,
cost-effective
single-step
co-precipitation
method
having
higher
adsorption
uptake
capacity
intended
for
elimination
of
toxic
Cr(
vi
)
ions
from
the
aquatic
environment.
RSC Advances,
Год журнала:
2023,
Номер
13(29), С. 20150 - 20163
Опубликована: Янв. 1, 2023
A
facile
chemical
procedure
was
utilized
to
produce
an
effective
peroxy-monosulfate
(PMS)
activator,
namely
ZnCo2O4/alginate.
To
enhance
the
degradation
efficiency
of
Rhodamine
B
(RhB),
a
novel
response
surface
methodology
(RSM)
based
on
Box-Behnken
Design
(BBD)
method
employed.
Physical
and
properties
each
catalyst
(ZnCo2O4
ZnCo2O4/alginate)
were
characterized
using
several
techniques,
such
as
FTIR,
TGA,
XRD,
SEM,
TEM.
By
employing
BBD-RSM
with
quadratic
statistical
model
ANOVA
analysis,
optimal
conditions
for
RhB
decomposition
mathematically
determined,
four
parameters
including
dose,
PMS
concentration,
reaction
time.
The
achieved
at
dose
1
g
l-1,
dye
concentration
25
mg
time
40
min,
efficacy
98%.
ZnCo2O4/alginate
displayed
remarkable
stability
reusability,
demonstrated
by
recycling
tests.
Additionally,
quenching
tests
confirmed
that
SO4˙-/OH˙
radicals
played
crucial
role
in
process.
Abstract
This
study
presents
the
preparation
of
SiO
2
/g-C
3
N
5
@NiFe
O
4
nanophotocatalyst
for
removal
betamethasone
from
aqueous
solutions.
The
was
synthesized
using
solvothermal
method,
and
its
structure
optical
properties
were
characterized
confirmed
through
XRD,
FESEM,
EDX,
DRS,
BET,
VSM
PL
analysis.
Photocatalytic
optimized
a
central
composite
design.
band
gap
pure
g-C
,
NiFe
obtained
2.4
eV,
2.7
1.4
respectively
Tauc
plot.
F
-value
909.88
Lack
Fit
0.41
confirm
model
is
significant.
Also,
value
R
=
0.9988
along
with
adja
09977
demonstrates
excellent
performance.
Maximum
efficiency
approximately
87.15%
under
following
optimal
conditions:
dosage
0.005
g/50
mL,
concentration
20
mg/L,
an
irradiation
time
40
min
visible
light.
performance
closely
aligns
actual
80.65%.
In
conclusion,
photocatalytic
ability
Green Processing and Synthesis,
Год журнала:
2023,
Номер
12(1)
Опубликована: Янв. 1, 2023
Abstract
Zr-metal-organic
frameworks
(Zr-MOFs)
were
prepared
by
a
solvothermal
method
and
characterized
X-ray
diffraction,
scanning
electron
microscopy,
thermogravimetry.
Zr-MOFs
used
to
remove
doxycycline
hydrochloride
(DOC)
from
wastewater.
According
the
experimental
results,
maximum
adsorption
capacity
of
DOC
within
5
h
was
148.7
mg·g
−1
.
From
pseudo-second-order
kinetics
model,
all
R
2
values
greater
than
0.99,
which
proved
that
consistent
with
practice.
Freundlich
isotherm
proceeded
via
multilayer
adsorption.
The
aforementioned
results
show
have
good
application
prospects
for
removing