Adsorptive Behavior of Corn-Cob- and Straw-Derived Biochar for Polycyclic Aromatic Hydrocarbon Removal from Aqueous Systems DOI Open Access
Jelena Beljin, Marijana Kragulj Isakovski, Jasmina Agbaba

и другие.

Processes, Год журнала: 2025, Номер 13(5), С. 1521 - 1521

Опубликована: Май 15, 2025

This study investigates the potential of biochar derived from agricultural residues—corn cob and wheat straw—for removing polycyclic aromatic hydrocarbons (PAHs) aqueous systems. Biochars were produced via pyrolysis at 700 °C characterized using BET, SEM, EDS, FTIR, pXRD to evaluate physicochemical properties. Adsorption experiments with naphthalene, fluorene, fluoranthene, pyrene revealed high adsorption affinities (Log Kd = 4.35–5.69 L/kg), Freundlich isotherm modeling indicating nonlinear behavior (n 0.732–0.923), suggesting a combination pore filling chemical interactions such as π-π stacking hydrogen bonding. Corn-cob biochar, rich in lignin, exhibited higher surface area (111 m2/g) greater affinity for while wheat-straw oxygen content more functional groups, performed better naphthalene pyrene. FTIR confirmed graphitic structures facilitating PAH interactions. These results underscore importance feedstock selection conditions tailoring properties specific pollutants. While both biochars compare favorably conventional adsorbents like activated carbon, further research on long-term stability complex matrices is needed. Overall, findings support development cost-effective, scalable, eco-friendly biochar-based technologies water remediation.

Язык: Английский

Selection Path for Energy-Efficient Food Waste Management in Urban Areas: Scenario Analysis and Insights from Poland DOI Creative Commons
Anna Rolewicz-Kalińska, Krystyna Lelicińska-Serafin, Piotr Manczarski

и другие.

Energies, Год журнала: 2025, Номер 18(2), С. 385 - 385

Опубликована: Янв. 17, 2025

The problem of food being wasted in households has become an essential challenge recent years. Food waste can be valorized accordance with the principles sustainable development, including as a source energy. This study analyses potential anaerobic fermentation, pyrolysis, ethanol incineration, and composting to treat waste, focusing on its energy yield. research considered two scenarios for generating Poland both near term (2030) long (2050). Scenarios were proposed regions different levels urbanization demographic trends. criteria selection technologies energy-efficient processing from identified, taking into account current state these technologies, their prospective changes, nature regions, trajectory generation, spatial generation rate, potential. Technologies like methane fermentation thermochemical methods should developed densely populated areas high rate. Among processes, fast pyrolysis will provide most significant benefits, followed by moderate biocarbonization—at similar levels. Incineration is placed between carbonization gasification. In less lower rates, combining substrates co-processing green considered. Biocarbonization systems integrated rural regions.

Язык: Английский

Процитировано

0

Review of Treatment Techniques for Dredged Sediments in the Context of Valorization as Secondary Raw Materials DOI Creative Commons

Ayodele Afolayan,

Robert Černý, Jan Fořt

и другие.

Buildings, Год журнала: 2025, Номер 15(10), С. 1639 - 1639

Опубликована: Май 13, 2025

The valorization of dredged sediments (DS) presents a sustainable solution for managing waste while addressing resource scarcity and environmental concerns. This review explores treatment techniques reuse options DS, focusing on applications in the construction industry. However, disposal poses challenges due to potential contamination with heavy metals organic pollutants. study categorizes approaches into physical, chemical, biological, thermal processes. Physical methods, such as separation dewatering, offer volume reduction but have limited capacities against chemically bound contaminants. Chemical treatments, including oxidation immobilization, target specific pollutants often entail high costs risks. Biological approaches, bioremediation phytoremediation, provide sustainable, low-cost alternatives require longer timescales. Thermal processes like pyrolysis vitrification efficiently destroy or stabilize contaminants involve energy demands. Pyrolysis emerges particularly promising technology, combining effective decontamination recovery biochar production. Despite advances area, identifies key barriers large-scale DS reuse: variability, lack standardized guidelines, long-term performance data. Future research should focus integrated strategies, other industrial by-products, optimization processing, aiming attain cost-effective, reuse. Overall, treated supports circular-economy principles offers significant economic benefits.

Язык: Английский

Процитировано

0

Adsorptive Behavior of Corn-Cob- and Straw-Derived Biochar for Polycyclic Aromatic Hydrocarbon Removal from Aqueous Systems DOI Open Access
Jelena Beljin, Marijana Kragulj Isakovski, Jasmina Agbaba

и другие.

Processes, Год журнала: 2025, Номер 13(5), С. 1521 - 1521

Опубликована: Май 15, 2025

This study investigates the potential of biochar derived from agricultural residues—corn cob and wheat straw—for removing polycyclic aromatic hydrocarbons (PAHs) aqueous systems. Biochars were produced via pyrolysis at 700 °C characterized using BET, SEM, EDS, FTIR, pXRD to evaluate physicochemical properties. Adsorption experiments with naphthalene, fluorene, fluoranthene, pyrene revealed high adsorption affinities (Log Kd = 4.35–5.69 L/kg), Freundlich isotherm modeling indicating nonlinear behavior (n 0.732–0.923), suggesting a combination pore filling chemical interactions such as π-π stacking hydrogen bonding. Corn-cob biochar, rich in lignin, exhibited higher surface area (111 m2/g) greater affinity for while wheat-straw oxygen content more functional groups, performed better naphthalene pyrene. FTIR confirmed graphitic structures facilitating PAH interactions. These results underscore importance feedstock selection conditions tailoring properties specific pollutants. While both biochars compare favorably conventional adsorbents like activated carbon, further research on long-term stability complex matrices is needed. Overall, findings support development cost-effective, scalable, eco-friendly biochar-based technologies water remediation.

Язык: Английский

Процитировано

0