Bacterial Cellulose-Derived Sorbents for Cr (VI) Remediation: Adsorption, Elution, and Reuse DOI Open Access
Uriel Fernando Carreño Sayago, Vladimir Ballesteros Ballesteros,

A. Aguilar

и другие.

Polymers, Год журнала: 2024, Номер 16(18), С. 2605 - 2605

Опубликована: Сен. 14, 2024

The search for adsorbents that are non-toxic and low cost with a high adsorption capacity excellent recyclability is priority to determine the way reduce serious environmental impacts caused by discharge of effluents loaded heavy metals. Bacterial cellulose (BC) biomass has functional groups such as hydroxyl carbonyl play crucial role in making this so efficient at removing contaminants present water through cation exchange. This research aims develop an experimental process adsorption, elution, reuse bacterial treating contaminated Cr (VI). SEM images kinetics behavior were analyzed pseudo-first- pseudo-second-order models together isothermal analysis after each elution process. was agreement Langmuir model along its reuse; up 225 mg/g, adding all processes. study presents novel approach preparation capable retaining (VI) stability. method eliminates need chemical agents, which would otherwise be difficult implement due their costs. viability field industrial wastewater treatment demonstrated.

Язык: Английский

Carboxymethyl hemicellulose hydrogel as a fluorescent biosensor for bacterial and fungal detection with DFT and molecular docking studies DOI Creative Commons

Hebat‐Allah S. Tohamy

Scientific Reports, Год журнала: 2025, Номер 15(1)

Опубликована: Янв. 4, 2025

Abstract A new method was developed to quickly produce carboxymethyl hemicellulose (CM-Hemi) and fluorescent nitrogen-doped carbon dots (N–CDs) from sugarcane bagasse (SB). These materials were then combined with calcium chloride (CaCl₂) create hydrogel sensors antibacterial antifungal properties. The CM-Hemi@Ca-N–CDs effective against both Gram-negative ( Escherichia coli ) Gram-positive Staphylococcus aureus bacteria compared CM-Hemi@Ca which give no activity. Both hydrogels also exhibited properties Candida albicans . Molecular docking studies revealed that the had strong binding interactions protein (1.92 A°) compard (2.01 A°), aligned inhibition zone measurements test. fluorescence microscope differences in emitted light color when interacted different types of microorganisms, likely due variations their cell walls. Density functional theory (DFT) calculations indicate incorporation N–CDs into enhances its stability rigidity. This is evidenced by lower energy gap (E g ), higher electron affinity (μ), softness (S) hydrogel. Additionally, formation amide bonds between CM-Hemi contributes increased rigidity hydrogel.These findings supporting th effectiveness as an antibacterial/antifungal sensor.

Язык: Английский

Процитировано

3

Improving acrylonitrile rubber properties by recycled nano graphene oxide prepared from sugarcane bagasse DOI Creative Commons
D. E. El‐Nashar,

Hebat‐Allah S. Tohamy,

Adel A. Koriem

и другие.

Polymer Composites, Год журнала: 2025, Номер unknown

Опубликована: Фев. 6, 2025

Abstract Naturally occurring inexpensive substance is useful as a raw material like graphite. Graphene oxide (GO) made from sugarcane bagasse (SB) to create nano graphene (GO‐SB). Nitrile rubber (NBR) was used base matrix while (GO‐SB) filler combined at various loadings [2, 4, 6, 8, and 10 Part per hundred part of (phr)]. The impact the prepared loading on physicomechanical curing characteristics NBR nanocomposites examined evaluated. Transmission Electron Microscopy (TEM), x‐ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT‐IR) were estimate characterize investigated samples. Excellent dispersion (8 phr) in observed using scanning electron microscopy (SEM). agglomerations found be heterogeneous (10 phr). Curing characterizations showed that compounded with had larger maximum minimum torques, torque difference 8 phr, faster cure rate than unfilled compound. equilibrium swelling mechanical demonstrated reinforcing effect contained phr When content increased up Shore A hardness values increased. Highlights nanosized bagasse. verified nanoscale oxide. Nano ingredients are incorporated by mixer. Effect properties products have better physico properties.

Язык: Английский

Процитировано

2

Fluffy-like amphiphilic graphene oxide and its effects on improving the antibacterial activity and thermal outstanding of ethyl cellulose /polyvinyl alcohol hydrogel film DOI Creative Commons

Hebat‐Allah S. Tohamy,

Hossam M. El‐Masry

BMC Chemistry, Год журнала: 2024, Номер 18(1)

Опубликована: Июнь 26, 2024

Abstract The antibacterial characteristics of graphene oxide (GO-SB) nano-sheets generated by charring sugarcane bagasse (SB) are described in this study. capability GO-SB was improved when it grafted with ethyl cellulose (EC) and polyvinyl alcohol (PVA) to form GO-SB/EC/PVA hydrogels. Characterization nanosheets hydrogels accomplished using FTIR, SEM, XRD, thermal studies. antimicrobial activity carried out against Gram positive bacteria [ Micrococcus leutus & Staphylococcus aureus ], negative Escherichia coli , Pseudomonas aeruginosa ] pathogenic fungal yeast Candida albicans applying the disc diffusion method. method results showed that exhibited a reasonable level demonstrating improvement more effective increasing inhibition zone Gram-positive bacteria, from (13.0 16.0 mm). Graphical abstract

Язык: Английский

Процитировано

12

Fullerenes and tree-shaped/fingerprinted carbon quantum dots for chromium adsorption via microwave-assisted synthesis DOI Creative Commons

Hebat‐Allah S. Tohamy,

Mohamed El‐Sakhawy, Samir Kamel

и другие.

RSC Advances, Год журнала: 2024, Номер 14(35), С. 25785 - 25792

Опубликована: Янв. 1, 2024

: Employing citric acid/dimethyl formamide (CA/DMF), two distinct types of carbon quantum dots (CQDs), tree-shaped/fingerprinted (TF-CQDs) and fullerene-like (F) were synthesized from both cellulose carboxymethyl (CMC).

Язык: Английский

Процитировано

10

Novel microwave assisted carboxymethyl-graphene oxide and its hepatoprotective activity DOI Creative Commons

Hebat‐Allah S. Tohamy,

Fatma Mohamed,

Mohamed El‐Sakhawy

и другие.

BMC Pharmacology and Toxicology, Год журнала: 2024, Номер 25(1)

Опубликована: Авг. 13, 2024

Abstract This study reports a novel, eco-friendly; fast and cost-effective microwave method for synthesizing carboxymethylated graphene oxide (CMGO) from sugarcane residues. Fourier-transform infrared spectroscopy (FTIR) confirmed successful CMGO synthesis through the presence of characteristic peaks at 1567.93 1639.29 cm −1 (COONa vibrations) increased CH 2 intensity compared to unmodified (GO). Furthermore, derived residues demonstrated potential in mitigating side effects toxic materials like carbon tetrachloride (CCl 4 ). Treatment with partially reduced elevated levels liver enzymes (ALT AST) nitrogenous waste products (urea uric acid) CCl -induced damage models, suggesting an improvement function despite ongoing cellular damage.This work paves way sustainable economical approach produce functionalized promising biomedical applications alleviating toxin-induced injury. Graphical abstract

Язык: Английский

Процитировано

7

Development and characterization of fluorescent cellulose succinate hydrogels for efficient chromium adsorption DOI

Hebat‐Allah S. Tohamy,

Mohamed El‐Sakhawy, Beata Strachota

и другие.

Journal of Polymer Research, Год журнала: 2024, Номер 31(11)

Опубликована: Ноя. 1, 2024

Язык: Английский

Процитировано

5

Speedy synthesis of magnetite/carbon dots for efficient chromium removal and reduction: a combined experimental and DFT approach DOI Creative Commons

Hebat‐Allah S. Tohamy

Emergent Materials, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 28, 2024

Abstract Magnetic carbon dots (Fe 3 O 4 /N–CQDs) was prepared by and eco-friendly one-step microwave method using sugarcane bagasse (SB) as a starting material, applied to remove ad reduce Cr(VI) in wastewater. The magnetization process performed novel instead of the long time conventional co-precipitation method. Fe /N–CQDs showed high saturated (Ms ~ 38.047 emu/g). When neat N–CQDs were adsorb Cr(VI), R% slightly higher case (93.86%) compared (91.73%). Moreover, reduction rate than N–CQDs. study confirmed presence magnetic iron oxide (Fe-O) at 655 cm −1 FTIR spectroscopy. Interestingly, XRD analysis revealed peaks indicative elemental (Fe(0)) alongside oxide. Furthermore, TGA/DTG significantly weight residue (∑RW) for alone, suggesting enhanced thermal stability due component. This is further supported activation energy (∑A) pre-exponential factor (∑s) obtained fluorescence N–CQDs, which make them suitable chemosensor future work. In addition, DFT calculations Graphical

Язык: Английский

Процитировано

5

Novel, Speedy, and Eco-Friendly Carboxymethyl Cellulose-Nitrogen Doped Carbon Dots Biosensors with DFT Calculations, Molecular Docking, and Experimental Validation DOI Creative Commons

Hebat‐Allah S. Tohamy

Gels, Год журнала: 2024, Номер 10(11), С. 686 - 686

Опубликована: Окт. 24, 2024

Carboxymethyl cellulose (CMC) was prepared from sugarcane bagasse (SB) in minutes using a novel microwave method. Additionally, nitrogen-doped carbon dots (N-CDs) were synthesized SB the same technique. These materials crosslinked with CaCl

Язык: Английский

Процитировано

4

Antimicrobial Plectranthus amboinicus emulsions prepared with amphiphilic cellulose stearate DOI

Hebat‐Allah S. Tohamy,

Mohamed El‐Sakhawy, Sally A. Abdel-Halim

и другие.

Euro-Mediterranean Journal for Environmental Integration, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 5, 2024

Язык: Английский

Процитировано

4

Cellulosic schiff base hydrogel biosensor for bacterial detection with pH/thermo-responsitivity: DFT calculations and molecular docking DOI

Hebat‐Allah S. Tohamy

International Journal of Biological Macromolecules, Год журнала: 2024, Номер 283, С. 137389 - 137389

Опубликована: Ноя. 12, 2024

Язык: Английский

Процитировано

4