Ceramics International, Год журнала: 2024, Номер unknown
Опубликована: Дек. 1, 2024
Язык: Английский
Ceramics International, Год журнала: 2024, Номер unknown
Опубликована: Дек. 1, 2024
Язык: Английский
International Journal of Biological Macromolecules, Год журнала: 2024, Номер 273, С. 133078 - 133078
Опубликована: Июнь 28, 2024
Язык: Английский
Процитировано
17Chemosphere, Год журнала: 2024, Номер 359, С. 142273 - 142273
Опубликована: Май 13, 2024
Язык: Английский
Процитировано
13Colloids and Surfaces A Physicochemical and Engineering Aspects, Год журнала: 2024, Номер 697, С. 134314 - 134314
Опубликована: Май 25, 2024
Язык: Английский
Процитировано
8Journal of environmental chemical engineering, Год журнала: 2024, Номер 12(5), С. 113505 - 113505
Опубликована: Июль 4, 2024
Язык: Английский
Процитировано
8Journal of Alloys and Compounds, Год журнала: 2025, Номер 1017, С. 179064 - 179064
Опубликована: Фев. 1, 2025
Язык: Английский
Процитировано
1Journal of Photochemistry and Photobiology A Chemistry, Год журнала: 2024, Номер 453, С. 115662 - 115662
Опубликована: Апрель 8, 2024
Язык: Английский
Процитировано
6Journal of Hazardous Materials Advances, Год журнала: 2025, Номер 17, С. 100624 - 100624
Опубликована: Янв. 31, 2025
Язык: Английский
Процитировано
0Transition Metal Chemistry, Год журнала: 2025, Номер unknown
Опубликована: Фев. 24, 2025
Язык: Английский
Процитировано
0Inorganic Chemistry, Год журнала: 2025, Номер unknown
Опубликована: Апрель 24, 2025
The development of eco-friendly hydrogen peroxide (H2O2) synthesis through the photocatalytic oxygen reduction reaction holds significant potential for sustainable chemical engineering; however, it remains hindered by necessity sacrificial agents. Herein, we construct a two-dimensional (2D) S-scheme heterojunction interfacial coupling S-vacancy-rich ZnIn2S4 (SV-ZIS) with Bi2WO6 (BWO) nanosheets via an in situ growth method. Band alignment engineering establishes giant built-in electric field at Bi2WO6/SV-ZIS interface, which drives directional charge transfer, leaving photogenerated electrons and holes highest redox potentials accumulated on BWO SV-ZIS, respectively, O2 H2O oxidation. This spatial separation mechanism enhances both electron-hole pair dissociation efficiency (validated transient photocurrent analysis) preserves strong (reflected free-radical capturing experiments). 2D/2D architecture further amplifies migration atomic-level contact, leading to efficient H2O2 production rate 822 μmol L-1 h-1 pure water. work provides strategy designing high-performance photocatalysts toward under environmentally benign conditions.
Язык: Английский
Процитировано
0Results in Chemistry, Год журнала: 2024, Номер 7, С. 101497 - 101497
Опубликована: Янв. 1, 2024
Solar energy-utilizing photocatalysts for water purification remain essential environmental sustainability. This report presents new concepts in bismuth oxychloride/oxide/carbon nanotubes. (BiOCl/Bi2O3/CNT) composites, synthesized through a chemical deposition method involving BiOCl carbon nanotube bath, followed by surface reduction/oxidation steps. The impact of ratio and calcination temperature were explored. Characterization involved ultraviolet–visible diffuse reflectance spectroscopy (UV–vis DRS), X-ray photoelectron (XPS), fourier transform infrared (FTIR), diffraction (XRD), scanning electron microscopy (SEM), energy dispersive (EDX), elemental mapping, N2 adsorption/desorption analysis, electrochemical impedance (EIS). XRD analysis revealed in-situ formation α β-Bi2O3 phases, rendering the composite more responsive to visible light at 200 °C. Carbon nanotubes reduced band gap ternary yielding lower energies range compared Bi2O3. XPS identified metallic Bi0 particles, enhancing mobility charge separation. synergy BiOCl/Bi2O3/CNT-200 material significantly improved diclofenac degradation under solar simulator irradiation. Total organic (TOC) demonstrated 81 % mineralization with material. Active species trapping crucial roles HO• radicals h+ holes pollutant degradation. presence normally metastable phase °C enhanced simulation efficiency, while acted as reservoirs, aided particles. present study sets out an efficient synthesis approach photomineralization complex pharmaceutical compounds.
Язык: Английский
Процитировано
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