Theoretical and practical aspects of indirect spin–spin couplings DOI
Jarosław Jaźwiński

Royal Society of Chemistry eBooks, Год журнала: 2024, Номер unknown, С. 24 - 52

Опубликована: Ноя. 15, 2024

The review gathers the most important works on SSCC, considering their practical and theoretical aspects. These chapters deal with improvement of calculation methods, benchmark calculations using large sets compounds, measurements coupling constants in individual application to exploration conformations as well couplings through unusual chemical bonds. Finally, examples natural compounds were provided which J(H,H) J(C,H) helpful determining structure. This covers period from May 2023 April 2024.

Язык: Английский

Marine natural products DOI Creative Commons
Anthony R. Carroll, Brent R. Copp, Tanja Grkovic

и другие.

Natural Product Reports, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

A comprehensive review of 1220 new MNPs including a novel sex inducing pheromone from the diatom Seminavis robusta .

Язык: Английский

Процитировано

4

Novel Bioactive Natural Products from Marine-Derived Penicillium Fungi: A Review (2021–2023) DOI Creative Commons

Fang Lv,

Yan‐Bo Zeng

Marine Drugs, Год журнала: 2024, Номер 22(5), С. 191 - 191

Опубликована: Апрель 23, 2024

Marine-derived

Язык: Английский

Процитировано

15

Genome Mining of a Deep-Sea-Derived Penicillium allii-sativi Revealed Polyketide-Terpenoid Hybrids with Antiosteoporosis Activity DOI
Chun‐Lan Xie, Taizong Wu, Yuan Wang

и другие.

Organic Letters, Год журнала: 2024, Номер 26(18), С. 3889 - 3895

Опубликована: Апрель 26, 2024

Two novel meroterpenoids, alliisativins A and B (1, 2) were discovered through a genome-based exploration of the biosynthetic gene clusters deep-sea-derived fungus Penicillium allii-sativi MCCC entry 3A00580. Extensive spectroscopic analysis, quantum calculations, chemical derivatization, biogenetic considerations utilized to establish their structures. Alliisativins possess unique carbon skeleton featuring drimane sesquiterpene with highly oxidized polyketide. Noteworthily, alliisativin (1) showed dual activity in promoting osteogenesis inhibiting osteoclast, indicating an antiosteoporosis potential.

Язык: Английский

Процитировано

12

Viridicatol from the Deep‐Sea‐Derived Fungus Alleviates Bone Loss by Targeting the Wnt/SHN3 Pathway DOI Creative Commons
Chun‐Lan Xie,

S Ye,

Yu‐Ting Yue

и другие.

Advanced Science, Год журнала: 2025, Номер unknown

Опубликована: Апрель 7, 2025

Abstract As an enticing bone anabolic target, short‐term inhibition of Schnurri‐3 (SHN3) resulted in high‐bone mass due to augmented osteoblast activity. However, no studies are conducted identify natural products targeting SHN3 inhibition. Herein, a screening strategy for the discovery marine compounds that facilitate differentiation by silencing is presented. One leading quinolinone alkaloid, viridicatol (VDC), isolated from deep‐sea‐derived fungus, vigorously promotes osteogenic via Wnt/SHN3 signaling pathway osteoblasts, thereby preventing osteoporosis while enhancing bone‐fracture healing mouse model. Subsequently, SDSSD (Ser, Asp, Ser, Asp) further employed engineer bone‐targeting nanovesicles (BT‐NVs) optimal delivery VDC which mitigates loss observed severe osteogenesis imperfecta Hence, these results initially uncover promising product, VDC, treatment and highlighting its translational potential clinical applications.

Язык: Английский

Процитировано

1

Chemical Constituents of the Deep‐Sea‐Derived Penicillium citrinum W22 and Their Ferroptosis Inhibitory Activity DOI Open Access

Zheng‐Biao Zou,

Yan‐Lin Ma,

Yan Li

и другие.

Chemistry & Biodiversity, Год журнала: 2025, Номер unknown

Опубликована: Янв. 17, 2025

ABSTRACT One new monomeric citrinin analog ( 1 ) and 42 known compounds 2–43 were isolated from Penicillium citrinum W22. The structure of was determined by detailed analysis the 1D 2D nuclear magnetic resonance (NMR), HRESIMS, time‐dependent density functional theory (TD‐DFT)‐based electronic circular dichroism (ECD) calculation. Penicitrinol A 2 methyl 2‐(2‐acetyl‐3,5‐dihydroxy‐4,6‐dimethylphenyl) acetate 11 significantly inhibited renin‐angiotensin system‐selective lethal 3 (RSL3)‐induced ferroptosis with half maximal effective concentration (EC 50 values 1.6 34.0 µM, respectively.

Язык: Английский

Процитировано

0

Exploring the bioactive potential of deep-sea microorganisms: A review of recent discoveries DOI

Salman Khan,

Tingting Wang, Muhammad Zain Ul Arifeen

и другие.

Bioorganic Chemistry, Год журнала: 2025, Номер 161, С. 108521 - 108521

Опубликована: Апрель 26, 2025

Язык: Английский

Процитировано

0

In Vitro Insights into the Role of 7,8-Epoxy-11-Sinulariolide Acetate Isolated from Soft Coral Sinularia siaesensis in the Potential Attenuation of Inflammation and Osteoclastogenesis DOI Creative Commons

Lin-Mao Ke,

Dan-Dan Yu,

Ming‐Zhi Su

и другие.

Marine Drugs, Год журнала: 2024, Номер 22(2), С. 95 - 95

Опубликована: Фев. 19, 2024

The balance between bone-resorbing osteoclasts and bone-forming osteoblasts is essential for the process of bone remodeling. Excessive osteoclast differentiation plays a pivotal role in pathogenesis diseases such as rheumatoid arthritis osteoporosis. In present study, we examined whether 7,8-epoxy-11-sinulariolide acetate (Esa), marine natural product soft coral Sinularia siaesensis, attenuates inflammation osteoclastogenesis vitro. results indicated that Esa significantly inhibited lipopolysaccharide (LPS)-induced model RAW264.7 cells suppressed receptor activator nuclear factor-κB ligand (RANKL)-triggered osteoclastogenesis. down-regulated protein expression iNOS, COX-2, TNF-α by inhibiting NF-κB/MAPK/PI3K pathways reducing release reactive oxygen species (ROS) macrophages. Besides, treatment osteoclast-specific markers NFATC1, MMP-9, CTSK proteins. These findings suggest may be potential agent maintenance homeostasis associated with inflammation.

Язык: Английский

Процитировано

1

Chemical Constituents from the deep‐sea‐derived Fungus Aureobasidium melanogenum LUO5 DOI
Haoyu Dong,

Yuan Wang,

Xiaoyu Zhang

и другие.

Chemistry & Biodiversity, Год журнала: 2024, Номер 21(6)

Опубликована: Апрель 12, 2024

Abstract Three new C 10 and 12 aliphatic δ ‐lactones ( 1 – 3 ), three fatty acid methyl esters 4 6 eight known compounds 7 14 ) were isolated from the marine Aureobasidium sp. LUO5. Their structures established by detailed analyses of NMR, HRESIMS, optical rotation, ECD data. All isolates tested for their inhibitory effects on nitric oxide production in LPS‐induced BV‐2 cells. Notably, compound displayed strongest effect with IC 50 value 120.3 nM.

Язык: Английский

Процитировано

0

Theoretical and practical aspects of indirect spin–spin couplings DOI
Jarosław Jaźwiński

Royal Society of Chemistry eBooks, Год журнала: 2024, Номер unknown, С. 24 - 52

Опубликована: Ноя. 15, 2024

The review gathers the most important works on SSCC, considering their practical and theoretical aspects. These chapters deal with improvement of calculation methods, benchmark calculations using large sets compounds, measurements coupling constants in individual application to exploration conformations as well couplings through unusual chemical bonds. Finally, examples natural compounds were provided which J(H,H) J(C,H) helpful determining structure. This covers period from May 2023 April 2024.

Язык: Английский

Процитировано

0