Transformation of Lignin Under Protection Strategies: Catalytic Oxidation and Depolymerization by Polyoxometalates Catalysts DOI Open Access

Xinyue Ma,

Wenbiao Xu

Polymers, Год журнала: 2024, Номер 16(24), С. 3480 - 3480

Опубликована: Дек. 13, 2024

The efficient utilization of lignin, a pivotal component lignocellulosic biomass, is crucial for advancing sustainable biorefinery processes. However, optimizing lignin valorization remains challenging due to its intricate structure and susceptibility undesirable reactions during processing. In this study, we delve into the impact various pretreatment agents on birch aiming enhance catalytic oxidation depolymerization under polyoxometalates (POMs) catalysis. Our results reveal that with formaldehyde effectively safeguards aryl ether linkages in leading notable increase aromatic compound yields POMs Furthermore, gel permeation chromatography (GPC) analysis underscores inhibition linkage hydrolysis upon addition. Gas chromatography–mass spectrometry (GC–MS) demonstrates boosts monomer yield by 2 3 times compared untreated underscoring effectiveness tailored strategies. This research significance adopting rational methods advance pathways catalyzed POMs, thereby contributing evolution biomass conversion technologies.

Язык: Английский

The role of lignin in adhesives for lignin-based formaldehyde-based resins: a review DOI

D Zhao,

Zhiyu Li,

Yuchun Zhang

и другие.

Biomass Conversion and Biorefinery, Год журнала: 2025, Номер unknown

Опубликована: Янв. 6, 2025

Язык: Английский

Процитировано

1

Environmental Impact of Textile Materials: Challenges in Fiber–Dye Chemistry and Implication of Microbial Biodegradation DOI Open Access
Arvind Negi

Polymers, Год журнала: 2025, Номер 17(7), С. 871 - 871

Опубликована: Март 24, 2025

Synthetic and natural fibers are widely used in the textile industry. Natural include cellulose-based materials like cotton, regenerated viscose as well protein-based such silk wool. fibers, on other hand, PET polyamides (like nylon). Due to significant differences their chemistry, distinct dyeing processes required, each generating specific waste. For example, cellulose exhibit chemical inertness toward dyes, necessitating auxiliaries that contribute wastewater contamination, whereas synthetic a major source of non-biodegradable microplastic emissions. Addressing environmental impact fiber processing requires deep molecular-level understanding enable informed decision-making. This manuscript emphasizes potential solutions, particularly through biodegradation related waste, aligning with United Nations Sustainable Development Goal 6, which promotes clean water sanitation. instance, cost-effective methods using enzymes or microbes can aid associated solutions while also addressing wastewater, contains high concentrations unreacted salts, highly water-soluble pollutants. paper covers different aspects dyeing, degradation mechanisms, waste produced by industry, highlighting microbial-based strategies for mitigation. The integration not only offers solution managing large volumes but paves way sustainable technologies.

Язык: Английский

Процитировано

0

Mechanistic insights and optimization of lignin depolymerization into aromatic monomers using vanadium-modified Dawson-type polyoxometalates DOI
Tingting Zhou, Hailin Zhang, Junyou Shi

и другие.

International Journal of Biological Macromolecules, Год журнала: 2025, Номер unknown, С. 139644 - 139644

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0

Prospecting artificial microbial consortia toward lignin valorization DOI
Jingjing Hu, Bin Gao, Zhihua Liu

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 162375 - 162375

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0

Microwave-Assisted Oxidative Degradation of Lignin Catalyzed by Hydrogen Peroxide–Alkaline Ionic Liquid System DOI Open Access
Yuxin Qin, Dan Li,

S. Mahmood

и другие.

Catalysts, Год журнала: 2025, Номер 15(4), С. 367 - 367

Опубликована: Апрель 9, 2025

In recent years, various green solvents have played more and important roles in catalysis biomass studies. this work, three imidazolium anion-based alkaline ionic liquids (ILs, including [BMIM]Im, [Ch]Im, [N4222]Im) were selected to catalyze the oxidative degradation of lignin by a microwave-assisted hydrogen peroxide–alkaline liquid system for first time, which aimed promote depolymerization high-value conversion increase number alcohol hydroxyl groups reactivity lignin. The changes before after taken as primary indices. As main conditions, influence microwave exposure power, concentration, peroxide concentration on efficacy was subsequently examined that exhibited most effective performance. addition, extracted reaction solution analyzed combination with gas chromatography–mass spectrometry (GC–MS), degraded solids characterized scanning electron microscopy (SEM), ultraviolet visible (UV–Vis) spectroscopy, Fourier-transform infrared spectroscopy (FT–IR), thermogravimetric derivative (TG–DTG) methods, determined composition products, mechanism, intuitive structural lignin, thereby providing insights into extent solvents.

Язык: Английский

Процитировано

0

Photodegradation of lignin biowaste catalyzed by biosynthesized zinc oxide nanoparticles using the leaf extract of Aristotelia chilensis DOI Creative Commons
Joelis Vera, W. A. T. Herrera, Edward Hermosilla

и другие.

Results in Engineering, Год журнала: 2024, Номер unknown, С. 103866 - 103866

Опубликована: Дек. 1, 2024

Язык: Английский

Процитировано

1

我国生物质基化工产品的关键技术现状与展望 DOI
Yin Liang, Zhenyu Zhang,

Haoan Fan

и другие.

Scientia Sinica Chimica, Год журнала: 2024, Номер unknown

Опубликована: Дек. 1, 2024

Процитировано

0

Transformation of Lignin Under Protection Strategies: Catalytic Oxidation and Depolymerization by Polyoxometalates Catalysts DOI Open Access

Xinyue Ma,

Wenbiao Xu

Polymers, Год журнала: 2024, Номер 16(24), С. 3480 - 3480

Опубликована: Дек. 13, 2024

The efficient utilization of lignin, a pivotal component lignocellulosic biomass, is crucial for advancing sustainable biorefinery processes. However, optimizing lignin valorization remains challenging due to its intricate structure and susceptibility undesirable reactions during processing. In this study, we delve into the impact various pretreatment agents on birch aiming enhance catalytic oxidation depolymerization under polyoxometalates (POMs) catalysis. Our results reveal that with formaldehyde effectively safeguards aryl ether linkages in leading notable increase aromatic compound yields POMs Furthermore, gel permeation chromatography (GPC) analysis underscores inhibition linkage hydrolysis upon addition. Gas chromatography–mass spectrometry (GC–MS) demonstrates boosts monomer yield by 2 3 times compared untreated underscoring effectiveness tailored strategies. This research significance adopting rational methods advance pathways catalyzed POMs, thereby contributing evolution biomass conversion technologies.

Язык: Английский

Процитировано

0