ACS Sustainable Chemistry & Engineering,
Год журнала:
2022,
Номер
10(43), С. 14212 - 14219
Опубликована: Окт. 17, 2022
A
series
of
zinc
indium
sulfide
(ZnIn2S4)
were
synthesized
by
solvothermal
methods
in
different
solvents.
After
characterizations,
the
ZnIn2S4
prepared
ethanol
(i.e.,
ZIS-1)
showed
highest
photocurrent
density.
With
ZIS-1
as
a
photocatalyst,
direct
C–H
azolation
N-heterocycles
including
quinoxalin-2(1H)-ones,
quinazoline,
and
2H-benzo[b][1,4]oxazin-2-ones
(32
examples)
was
realized
an
air
atmosphere
under
blue
light
(456
nm).
More
importantly,
microspherical
photocatalyst
is
stable
catalytic
process
can
be
used
at
least
five
times
while
reactivity
remains
unchanged.
In
addition,
this
practical
approach
also
applicable
to
some
other
complex
molecules
interest,
such
ibuprofen
isoxepac.
ACS Catalysis,
Год журнала:
2023,
Номер
13(17), С. 11851 - 11856
Опубликована: Авг. 23, 2023
The
synthesis
of
dialkyl-substituted
cyclopropanes
is
an
important
challenge
in
with
applications
drug
discovery
and
agrochemistry.
Herein,
we
report
on
the
gem-dialkyl
situ-generated
dialkyl
diazo
compounds
under
Bamford–Stevens
conditions.
A
simple
cobalt
catalyst
was
identified
to
be
optimal
achieve
high
yields.
Experimental
computational
studies
suggest
participation
a
metalloradical
reaction
mechanism
that
facilitates
carbene
transfer
reactions
provides
access
single
step.
Organic Letters,
Год журнала:
2022,
Номер
24(36), С. 6647 - 6652
Опубликована: Сен. 2, 2022
A
visible-light-promoted
three
component
reaction
of
diazo
compounds,
nitriles,
and
carboxylic
acids
is
reported.
The
utilizes
acceptor-only
compounds
as
carbene
precursors
nitriles
carbene-trapping
reagents
to
form
the
key
nitrile
ylides.
Under
optimal
conditions,
a
wide
range
imide
products
were
obtained
in
good
excellent
yields.
gram-scale
synthesis
synthetic
application
isoquinoline-1,3(2H,4H)-dione
derivatives
further
proved
value
this
method.
ACS Sustainable Chemistry & Engineering,
Год журнала:
2022,
Номер
10(43), С. 14212 - 14219
Опубликована: Окт. 17, 2022
A
series
of
zinc
indium
sulfide
(ZnIn2S4)
were
synthesized
by
solvothermal
methods
in
different
solvents.
After
characterizations,
the
ZnIn2S4
prepared
ethanol
(i.e.,
ZIS-1)
showed
highest
photocurrent
density.
With
ZIS-1
as
a
photocatalyst,
direct
C–H
azolation
N-heterocycles
including
quinoxalin-2(1H)-ones,
quinazoline,
and
2H-benzo[b][1,4]oxazin-2-ones
(32
examples)
was
realized
an
air
atmosphere
under
blue
light
(456
nm).
More
importantly,
microspherical
photocatalyst
is
stable
catalytic
process
can
be
used
at
least
five
times
while
reactivity
remains
unchanged.
In
addition,
this
practical
approach
also
applicable
to
some
other
complex
molecules
interest,
such
ibuprofen
isoxepac.
