Regioselective C–F Bond Transformations of Silyl Difluoroenolates DOI
Ryohei Doi,

Koki Kajiwara,

Taiki Negoro

и другие.

Organic Letters, Год журнала: 2023, Номер 25(29), С. 5542 - 5547

Опубликована: Июль 19, 2023

Herein, we report the development of a nickel-catalyzed cross-coupling reaction silyl difluoroenolates with aryl zinc reagents via C–F bond cleavage. Treatment stoichiometric amount Ni(0)/N-heterocyclic carbene (NHC) in presence lithium salt resulted cleavage to selectively afford corresponding (Z)-alkenyl Ni complexes. On basis observations, developed catalytic that delivers single geometric isomer fluoroenolate.

Язык: Английский

Regioselective C–F Bond Transformations of Silyl Difluoroenolates DOI
Ryohei Doi,

Koki Kajiwara,

Taiki Negoro

и другие.

Organic Letters, Год журнала: 2023, Номер 25(29), С. 5542 - 5547

Опубликована: Июль 19, 2023

Herein, we report the development of a nickel-catalyzed cross-coupling reaction silyl difluoroenolates with aryl zinc reagents via C–F bond cleavage. Treatment stoichiometric amount Ni(0)/N-heterocyclic carbene (NHC) in presence lithium salt resulted cleavage to selectively afford corresponding (Z)-alkenyl Ni complexes. On basis observations, developed catalytic that delivers single geometric isomer fluoroenolate.

Язык: Английский

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