Selective C(sp2)–P Cross-Coupling of Alkenylsulfonium Salts with P(O)H Compounds: Divergent Synthesis of Alkenylphosphorus Compounds DOI
Jing Xiao,

Dequan Xie,

L.‐F. WANG

и другие.

Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Март 13, 2025

Herein, we report a both regioselective and stereoselective method for the formation of C(sp2)–P bonds using alkenylsulfonium salts >P(O)–H compounds. By employing palladium catalyst or K2CO3, variety (E)-alkenylphosphorus compounds terminal alkenylphosphorus were successfully synthesized with high selectivity. Notably, trisubstituted (Z)-alkenylphosphorus first time under metal-free conditions. This protocol has wide substrate scope good functional group compatibility, providing direct highly selective approach preparation various

Язык: Английский

Selective C(sp2)–P Cross-Coupling of Alkenylsulfonium Salts with P(O)H Compounds: Divergent Synthesis of Alkenylphosphorus Compounds DOI
Jing Xiao,

Dequan Xie,

L.‐F. WANG

и другие.

Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Март 13, 2025

Herein, we report a both regioselective and stereoselective method for the formation of C(sp2)–P bonds using alkenylsulfonium salts >P(O)–H compounds. By employing palladium catalyst or K2CO3, variety (E)-alkenylphosphorus compounds terminal alkenylphosphorus were successfully synthesized with high selectivity. Notably, trisubstituted (Z)-alkenylphosphorus first time under metal-free conditions. This protocol has wide substrate scope good functional group compatibility, providing direct highly selective approach preparation various

Язык: Английский

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