Nanocomposite design for solid-state lithium metal batteries: Progress, challenge, and prospects DOI Creative Commons
Yong Chen,

Xu Lv,

Yang Xu

и другие.

Advanced Nanocomposites, Год журнала: 2024, Номер 1(1), С. 120 - 143

Опубликована: Янв. 1, 2024

Lithium metal batteries have gained significant attention due to their high energy density, making them a promising candidate for various applications, including electric vehicles and grid-scale storage. Nevertheless, the practical development of lithium faces challenges related dendrite formation, low cycling efficiency, poor safety use liquid electrolytes. Solid-state electrolytes (SSEs) are most attractive alternatives next-generation safe high-energy density storage systems. However, conventional SSEs fail meet simultaneous demands ionic conductivity mechanical properties, intrinsic solid-state chemical properties. Among numerous modifying strategies SSE chemistry, composite polymer (CPEs) with advanced nanocomposite design display suitable processability, wettability, flexibility, cost production. This review comprehensively outlines merits functions designs in CPEs. provides valuable insights into recent progress electrolytes, offering guidance future research efforts this field.

Язык: Английский

Lignin Derived Ultrathin All‐Solid Polymer Electrolytes with 3D Single‐Ion Nanofiber Ionic Bridge Framework for High Performance Lithium Batteries DOI
Yuhan Liu,

Pinhui Wang,

Zhenyue Yang

и другие.

Advanced Materials, Год журнала: 2024, Номер 36(27)

Опубликована: Апрель 16, 2024

Abstract The lignin derived ultrathin all‐solid composite polymer electrolyte (CPE) with a thickness of only 13.2 µm, which possess 3D nanofiber ionic bridge networks composed single‐ion lignin‐based lithium salt (L‐Li) and poly(vinylidene fluoride‐ co ‐hexafluoropropylene) (PVDF‐HFP) as the framework, poly(ethylene oxide)/lithium bis(trifluoromethanesulfonyl)imide (PEO/LiTFSI) filler, is obtained through electrospinning/spraying hot‐pressing. t. Li‐symmetric cell assembled CPE can stably cycle more than 6000 h under 0.5 mA cm −2 little Li dendrites growth. Moreover, Li||CPE||LiFePO 4 cells over 700 cycles at 0.2 C super high initial discharge capacity 158.5 mAh g −1 room temperature, favorable 123 −20 °C for 250 cycles. excellent electrochemical performance mainly attributed to reason that network afford uniformly dispersed L‐Li electrospinning, synergizes LiTFSI well in PEO form abundant efficient + transfer channels. induces uniform deposition interface, effectively inhibit dendrites. This work provides promising strategy achieve biobased electrolytes solid‐state ion batteries.

Язык: Английский

Процитировано

35
Zwitterionic Cellulose‐Based Polymer Electrolyte Enabled by Aqueous Solution Casting for High‐Performance Solid‐State Batteries DOI
Yong Cheng, Zhichao Cai, Jinglei Xu

и другие.

Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(30)

Опубликована: Май 7, 2024

Polyethylene oxide (PEO)-based solid-state batteries hold great promise as the next-generation with high energy density and safety. However, PEO-based electrolytes encounter certain limitations, including inferior ionic conductivity, low Li

Язык: Английский

Процитировано

27
Super‐Ionic Conductor Soft Filler Promotes Li+ Transport in Integrated Cathode–Electrolyte for Solid‐State Battery at Room Temperature DOI

Binbin Yang,

Chenglong Deng, Nan Chen

и другие.

Advanced Materials, Год журнала: 2024, Номер 36(27)

Опубликована: Апрель 7, 2024

Abstract Composite polymer solid electrolytes (CPEs), possessing good rigid flexible, are expected to be used in solid‐state lithium‐metal batteries. The integration of fillers into matrices emerges as a dominant strategy improve Li + transport and form ‐conducting electrode–electrolyte interface. However, challenges arise traditional fillers: 1) inorganic fillers, characterized by high interfacial energy, induce agglomeration; 2) organic with elevated crystallinity, impede intrinsic ionic conductivity, both severely hindering migration. Here, concept super‐ionic conductor soft filler, utilizing conductivity nanocellulose (Li‐NC) model, is introduced which exhibits conductivity. Li‐NC anchors anions, enhances speed, assists the cathode–electrolyte electrodes for room temperature tough dual‐channel electrolyte (TDCT) polyvinylidene fluoride (PVDF) demonstrates transfer number (0.79) due synergistic coordination mechanism transport. Integrated electrodes’ design enables stable performance LiNi 0.5 Co 0.2 Mn 0.3 O 2 |Li cells, 720 cycles at C, 88.8% capacity retention. Furthermore, lifespan Li|TDCT|Li cells over 4000 h Li‐rich 1.2 Ni 0.13 0.54 excellent performance, proving practical application potential filler energy density batteries temperature.

Язык: Английский

Процитировано

18
Revealing the Influence of Electron Migration Inside Polymer Electrolyte on Li+ Transport and Interphase Reconfiguration for Li Metal Batteries DOI
Yingmin Jin, Ruifan Lin, Yumeng Li

и другие.

Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(24)

Опубликована: Апрель 13, 2024

The development of highly producible and interfacial compatible in situ polymerized electrolytes for solid-state lithium metal batteries (SSLMBs) have been plagued by insufficient transport kinetics uncontrollable dendrite propagation. Herein, we seek to explore a rationally designed nanofiber architecture balance all the criteria SSLMBs, which La

Язык: Английский

Процитировано

17
A dual-network structured poly (m-phenylene isophthalamide) nanofiber separator with Li6.4La3Zr1.4Ta0.6O12 for dendrite-free and high-safety lithium-metal batteries DOI
Huijuan Zhao, Guodong Zhao, Fengquan Liu

и другие.

Chemical Engineering Journal, Год журнала: 2024, Номер 490, С. 151559 - 151559

Опубликована: Апрель 22, 2024

Язык: Английский

Процитировано

17
Understanding multi-scale ion-transport in solid-state lithium batteries DOI Creative Commons
Wen Yu, Nanping Deng, Feng Yang

и другие.

eScience, Год журнала: 2024, Номер unknown, С. 100278 - 100278

Опубликована: Май 1, 2024

Solid-state lithium battery (SSLB) is considered as one of the promising candidates for next-generation power batteries due to high safety, unprecedented energy density and favorable adaptability pression temperature. However, system solid electrolyte (SE), most important components in SSLB, usually plagued by clumsy ionic transport, leading poor rate performance SSLBs. Herein, a unique perspective proposed re-examine ion-transport behavior conductors tracing Li+ at multi-scale, including microscopic, mesoscopic macroscopic scales. The multi-scale mechanisms corresponding characterization techniques are analyzed depth. Furthermore, some strategies structure design improve kinetics scales elaborated systematically, involving modulation microscopic homogeneous structure, heterogeneous structures, etc. generalized rules SEs expected construct close link from mechanism−structure−characterization performances

Язык: Английский

Процитировано

15
Interface‐Targeting Carrier‐Catalytic Integrated Design Contributing to Lithium Dihalide‐Rich SEI toward High Interface Stability for Long‐Life Solid‐State Lithium‐Metal Batteries DOI

Xuanyi Zhou,

Fenfen Huang,

Xuedong Zhang

и другие.

Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(21)

Опубликована: Март 28, 2024

Abstract The generation of solid electrolyte interphase (SEI) largely determines the comprehensive performance all‐solid‐state batteries. Herein, a novel “carrier‐catalytic” integrated design is strategically exploited to in situ construct stable LiF‐LiBr rich SEI by improving electron transfer kinetics accelerate bond‐breaking dynamics. Specifically, high transport capacity Br‐TPOM skeleton increases polarity C−Br, thus promoting LiBr. Then, enhancement further promotes fracture C−F from TFSI − form LiF. Finally, and homogeneous artificial‐SEI with enriched lithium dihalide constructed through co‐growth mechanism LiF LiBr, which facilitatse Li‐ion regulates deposition behavior. Impressively, PEO‐Br‐TPOM paired LiFePO 4 delivers ultra‐long cycling stability over 1000 cycles 81 % retention at 1 C while pouch cells possess 88 superior after 550 initial discharge 145 mAh g −1 0.2 absence external pressure. Even under stringent conditions, practical electric quantities plateau 30 demonstrates its application potential energy storage field.

Язык: Английский

Процитировано

14
Interface‐Targeting Carrier‐Catalytic Integrated Design Contributing to Lithium Dihalide‐Rich SEI toward High Interface Stability for Long‐Life Solid‐State Lithium‐Metal Batteries DOI

Xuanyi Zhou,

Fenfen Huang,

Xuedong Zhang

и другие.

Angewandte Chemie, Год журнала: 2024, Номер 136(21)

Опубликована: Март 28, 2024

Abstract The generation of solid electrolyte interphase (SEI) largely determines the comprehensive performance all‐solid‐state batteries. Herein, a novel “carrier‐catalytic” integrated design is strategically exploited to in situ construct stable LiF‐LiBr rich SEI by improving electron transfer kinetics accelerate bond‐breaking dynamics. Specifically, high transport capacity Br‐TPOM skeleton increases polarity C−Br, thus promoting LiBr. Then, enhancement further promotes fracture C−F from TFSI − form LiF. Finally, and homogeneous artificial‐SEI with enriched lithium dihalide constructed through co‐growth mechanism LiF LiBr, which facilitatse Li‐ion regulates deposition behavior. Impressively, PEO‐Br‐TPOM paired LiFePO 4 delivers ultra‐long cycling stability over 1000 cycles 81 % retention at 1 C while pouch cells possess 88 superior after 550 initial discharge 145 mAh g −1 0.2 absence external pressure. Even under stringent conditions, practical electric quantities plateau 30 demonstrates its application potential energy storage field.

Язык: Английский

Процитировано

12
Deciphering and Integrating Functionalized Side Chains for High Ion‐Conductive Elastic Ternary Copolymer Solid‐State Electrolytes for Safe Lithium Metal Batteries DOI Creative Commons
Hongfei Xu, Jinlin Yang, Yuxiang Niu

и другие.

Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(36)

Опубликована: Июнь 17, 2024

A critical challenge in solid polymer lithium batteries is developing a matrix that can harmonize ionic transportation, electrochemical stability, and mechanical durability. We introduce novel design by deciphering the structure-function relationships of side chains. Leveraging molecular orbital-polarity-spatial freedom strategy, high ion-conductive hyperelastic ternary copolymer electrolyte (CPE) synthesized, incorporating three functionalized chains poly-2,2,2-Trifluoroethyl acrylate (PTFEA), poly(vinylene carbonate) (PVC), polyethylene glycol monomethyl ether (PEGMEA). It revealed fluorine-rich chain (PTFEA) contributes to improved stability interfacial compatibility; highly polar (PVC) facilitates efficient dissociation migration ions; flexible (PEGMEA) with spatial promotes segmental motion interchain ion exchanges. The resulting CPE demonstrates an conductivity 2.19×10

Язык: Английский

Процитировано

10
Janus nanofibers with multiple Li+ transport channels and outstanding thermal stability for all-solid-state composite polymer electrolytes DOI

Hengying Xiang,

Nanping Deng, Lu Gao

и другие.

Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(26), С. 16022 - 16033

Опубликована: Янв. 1, 2024

Herein, PEO-based composite polymer electrolytes enhanced by Janus nanofibers with multiple Li + transport channels and outstanding thermal stability were prepared, which exhibit ultra-long cycle in all-solid-state lithium metal batteries.

Язык: Английский

Процитировано

9