The
self-assembled
monolayer
(SAM)
technique,
known
for
its
customizable
molecular
segments
and
active
end
groups,
is
widely
recognized
as
a
powerful
tool
regulating
the
interfacial
properties
of
high-energy-density
lithium
metal
batteries.
However,
it
remains
unclear
how
degree
long-range
order
in
SAMs
affects
solid
electrolyte
interphase
(SEI).
In
this
study,
we
precisely
controlled
hydrolysis
silanes
to
construct
monolayers
with
varying
degrees
investigated
their
effects
on
SEI
nanostructure
anode
performance.
results
indicate
that
significantly
influences
decomposition
kinetics
carbon-fluorine
bond
bis(trifluoromethanesulfonyl)imide
(LiTFSI),
promoting
formation
LiF-rich
profoundly
affecting
long-term
stability
highly
sensitive
during
electrochemical
processes.
These
findings
provide
new
insights
directions
design
tailored
long-lasting
interfaces.
Abstract
The
miniaturization,
integration,
and
high
data
throughput
of
electronic
chips
present
challenging
demands
on
thermal
management,
especially
concerning
heat
dissipation
at
interfaces,
which
is
a
fundamental
scientific
question
as
well
an
engineering
problem—a
death
problem
called
in
semiconductor
industry.
A
comprehensive
examination
interfacial
resistance
has
been
given
from
physics
perspective
2022
Review
Modern
Physics
.
Here,
we
provide
detailed
overview
materials
perspective,
focusing
the
optimization
structure
compositions
interface
(TIMs)
interact/contact
with
source
sink.
First,
discuss
impact
conductivity,
bond
line
thickness,
contact
TIMs.
Second,
it
pointed
out
that
there
are
two
major
routes
to
improve
transfer
through
interface.
One
reduce
TIM's
(
R
TIM
)
TIMs
strategies
like
incorporating
conductive
fillers,
enhancing
treatment
techniques.
other
c
by
improving
effective
contact,
strengthening
bonding,
utilizing
mass
gradient
alleviate
vibrational
mismatch
between
source/sink.
Finally,
such
challenges
theories,
potential
developments
sustainable
TIMs,
application
AI
design
also
explored.
Advanced Engineering Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 29, 2025
Electrically
insulating
thermal
interface
materials
(TIMs)
are
desired
for
certain
applications
to
avoid
electrical
current
leakage.
However,
it
is
more
challenging
achieve
high
conductivity
(
κ
)
due
the
noncoalescing
nature
of
ceramic
particles.
Herein,
independent
control
and
TIMs
reported,
with
aid
low‐temperature
coalescing
silver
nanoparticles
(AgNPs),
enhancing
,
decreasing
total
resistance
R
t
while
retaining
insulation.
The
leakage‐free
functionalized
phase‐change
material
(OP)
employed
as
a
matrix.
interaction
between
aluminum
nitride
(AlN)
particles
OP
induces
highest
surface
energy
intrinsic
adhesion
energy,
compared
other
particles,
resulting
in
lowest
elastic
modulus
.
(1.7
W
m
−1
K
(80.1
mm
2
OP‐AlN
further
improved
by
AgNP
decoration
(OP‐AlN/Ag).
AlN
coalesced
exquisitely
AgNPs
(3
vol%),
suppressing
(<10
−9
S
cm
).
increased
58%
(2.7
decreased
44%
(45.0
electrical/thermal
pathway
may
prove
useful
electrically
but
thermally
highly
conducting
TIMs.
ACS Applied Materials & Interfaces,
Год журнала:
2025,
Номер
unknown
Опубликована: Апрель 8, 2025
The
demand
for
highly
sensitive
temperature-response
materials
is
critical
the
advancement
of
intelligent
temperature
sensing
and
fire
warning
systems.
Despite
notable
progress
in
thermoelectrical
(TE)
devices,
designing
TE
suitable
wide-range
monitoring
across
diverse
scenarios
remains
a
challenge.
In
this
study,
we
introduce
sensor
warnings
hot
object
recognition,
utilizing
an
all-inorganic
film
composite
reduced
graphene
oxide
(rGO)/Te
nanowires
(Te
NWs).
resulting
film,
annealed
at
high
temperature,
exhibits
distinct
response
ratios
to
varying
changes,
enabling
consistently
thermosensation.
robust
linear
relationship
between
open
circuit
voltage
difference
establishes
it
as
effective
thermoreceptor
enhanced
alerts.
Furthermore,
demonstrate
that
assembled
provides
rapid
high-temperature
with
adjustable
threshold
voltages
(1-7
mV),
achieving
ultrafast
time
approximately
4.8
s
1
mV
voltage.
Additionally,
can
be
integrated
gloves
monitor
objects
various
scenarios,
such
brewed
milk
daily
life
heating
reactors
industrial
applications.
These
results
offer
perspectives
future
innovations
monitoring.
Langmuir,
Год журнала:
2024,
Номер
40(23), С. 12059 - 12069
Опубликована: Май 31, 2024
The
growing
use
of
high-power
and
integrated
electronic
devices
has
created
a
need
for
thermal
conductive
adhesives
(TCAs)
with
high
conductivity
(TC)
to
manage
heat
dissipation
at
the
interface.
However,
TCAs
are
often
limited
by
contact
resistance
interface
between
materials.
In
this
study,
we
synthesized
MXene@Ag
composites
through
direct
in
situ
reduction
process.
Ag
nanoparticles
(Ag
NPs)
generated
MXene
interlayer
surface
formed
effective
thermally
pathways
flakes
within
an
epoxy
resin
matrix.
Various
characterization
analyses
revealed
that
adding
concentration
3
wt
%
resulted
remarkable
TC
40.80
W/(m·K).
This
value
is
8.77
times
higher
than
achieved
7.9
filler
alone.
improved
attributed
sintering
reduced
NPs
during
curing
process,
which
connection
(a
highly
material)
flakes,
thereby
reducing
resistance.
significantly
enhanced
materials
(TIMs).
study
presents
novel
approach
developing
exceptionally
TC,
opening
new
possibilities
design
fabrication
advanced
management
systems.
ACS Applied Bio Materials,
Год журнала:
2024,
Номер
7(9), С. 6297 - 6305
Опубликована: Сен. 2, 2024
Thermal
conduction
for
electronic
devices
has
attracted
extensive
attention
in
light
of
the
development
5G
communication.
Thermally
conductive
materials
with
high
thermal
conductivity
and
mechanical
flexibility
are
extremely
desirable
practical
applications.
However,
construction
efficient
interconnected
pathways
continuous
networks
is
inadequate
either
processing
or
actual
usage
existing
technologies.
In
this
work,
spherical
copper
nanoparticles
(S-CuNPs)
urchin-inspired
fractal-growth
CuNPs
(U-CuNPs),
thermally
metal
fillers
induced
by
ionic
liquids,
were
fabricated
successfully
through
electrochemical
deposition
method.
Compared
to
S-CuNPs,
U-CuNPs
shows
larger
specific
surface
contact
area,
thus
making
it
easier
build
a
pathway
network
corresponding
U-CuNPs/liquid
silicone
rubber
(LSR)
composites.
The
optimal
loading
CuNP
was
determined
evaluating
rheological
performance
prepolymer
properties
performances
When
filler
150
phr,
U-CuNPs/LSR
produces
(e.g.,
tensile
strength
modulus),
(above
1000%
improvement
compared
pure
LSR),
heating/cooling
efficiency.
enhanced
also
confirmed
finite
element
analysis
(FEA)
overall
temperature
distribution,
indicating
that
areas
exhibit
more
advantages
forming
composites
than
promising
competitive
alternative
traditional
flexible
interface
materials.
