State of the Art and Prospects in Metal–Organic Framework (MOF)-Based and MOF-Derived Nanocatalysis

Chemical Reviews, Год журнала: 2019, Номер 120(2), С. 1438 - 1511

Опубликована: Июнь 27, 2019

Metal–organic framework (MOF) nanoparticles, also called porous coordination polymers, are a major part of nanomaterials science, and their role in catalysis is becoming central. The extraordinary variability richness structures afford engineering synergies between the metal nodes, functional linkers, encapsulated substrates, or nanoparticles for multiple selective heterogeneous interactions activations these MOF-based nanocatalysts. Pyrolysis MOF-nanoparticle composites forms highly N- P-doped graphitized MOF-derived that increasingly used as efficient catalysts especially electro- photocatalysis. This review first briefly summarizes this background MOF nanoparticle then comprehensively reviews fast-growing literature reported during last years. parts organic molecular reactions, electrocatalysis, photocatalysis, views prospects. Major challenges our society addressed using well-defined fields synthesis, energy, environment. In spite many achievements, enormous progress still necessary to improve understanding processes involved beyond proof-of-concept, particularly methane oxidation, hydrogen production, water splitting, CO2 reduction methanol, nitrogen fixation, depollution.

Язык: Английский

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MOF-derived electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions

Chemical Society Reviews, Год журнала: 2020, Номер 49(5), С. 1414 - 1448

Опубликована: Янв. 1, 2020

The morphology and composition design of MOF-derived carbon-based materials their applications for electrocatalytic ORR, OER HER are reviewed.

Язык: Английский

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Cu nanowires shelled with NiFe layered double hydroxide nanosheets as bifunctional electrocatalysts for overall water splitting

Energy & Environmental Science, Год журнала: 2017, Номер 10(8), С. 1820 - 1827

Опубликована: Янв. 1, 2017

3D core–shell nanostructures of few-layer NiFe LDH nanosheets grown on Cu nanowires are fabricated toward highly efficient overall water splitting.

Язык: Английский

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Nickel-Based Electrocatalysts for Energy-Related Applications: Oxygen Reduction, Oxygen Evolution, and Hydrogen Evolution Reactions

ACS Catalysis, Год журнала: 2017, Номер 7(10), С. 7196 - 7225

Опубликована: Сен. 6, 2017

The persistently increasing energy consumption and the low abundance of conventional fuels have raised serious concerns all over world. Thus, development technology for clean-energy production has become major research priority worldwide. globalization advanced conversion technologies like rechargeable metal–air batteries, regenerated fuel cells, water-splitting devices been majorly benefitted by apposite catalytic materials that can proficiently carry out pertinent electrochemical processes oxygen reduction reaction (ORR), evolution (OER), hydrogen (HER), water hydrolysis. Despite a handful superbly performing commercial catalysts, high cost stability precursors consistently discouraged their long-term viability. As promising substitute platinum-, palladium-, iridium-, gold-, silver-, ruthenium-based various transition-metal (TM) ions (for example, Fe, Co, Mo, Ni, V, Cu, etc.) exploited to develop electroactive outperform state-of-the-art properties. Among these TMs, nickel emerged as one most hopeful constituents due its exciting electronic properties anticipated synergistic effect dramatically alter surface favor electrocatalysis. This review article will broadly confer about recent reports on nickel-based nanoarchitectured applications toward ORR, OER, HER, whole splitting. On basis derivatives, futuristic outlook also presented.

Язык: Английский

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Non‐Noble‐Metal‐Based Electrocatalysts toward the Oxygen Evolution Reaction

Advanced Functional Materials, Год журнала: 2020, Номер 30(15)

Опубликована: Фев. 16, 2020

The development of low-cost, high-efficiency, and robust electrocatalysts for the oxygen evolution reaction (OER) is urgently needed to address energy crisis. In recent years, non-noble-metal-based OER have attracted tremendous research attention. Beginning with introduction some evaluation criteria OER, current are reviewed, classification metals/alloys, oxides, hydroxides, chalcogenides, phosphides, phosphates/borates, other compounds, along their advantages shortcomings. knowledge mechanisms practical applications also summarized developing more efficient electrocatalysts. Finally, states, challenges, perspectives discussed.

Язык: Английский

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Metal–organic framework-derived porous materials for catalysis

Coordination Chemistry Reviews, Год журнала: 2018, Номер 362, С. 1 - 23

Опубликована: Фев. 23, 2018

Язык: Английский

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Support and Interface Effects in Water‐Splitting Electrocatalysts

Advanced Materials, Год журнала: 2019, Номер 31(31)

Опубликована: Март 6, 2019

Water-splitting electrolyzers that can convert electricity into storable hydrogen are a fascinating and scalable energy conversion technology for the utilization of renewable energies. To speed up sluggish oxygen evolution reactions (HER OER), electrocatalysts essential reducing their kinetic barriers eventually improving efficiency. As efficient strategies modulating binding ability water-splitting intermediates on electrocatalyst surface, support effect interface drawing growing attention. Herein, some recent research progress effects in HER, OER, overall is highlighted. Specifically, correlation between electronic interaction constituent components electrocatalytic performance profoundly discussed, with aim advancing development highly electrocatalysts, which may replace noble-metal-based bring practically widespread reality.

Язык: Английский

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Metal-Organic-Framework-Based Materials as Platforms for Renewable Energy and Environmental Applications

Joule, Год журнала: 2017, Номер 1(1), С. 77 - 107

Опубликована: Сен. 1, 2017

Язык: Английский

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Metal‐Organic Frameworks Derived Nanotube of Nickel–Cobalt Bimetal Phosphides as Highly Efficient Electrocatalysts for Overall Water Splitting

Advanced Functional Materials, Год журнала: 2017, Номер 27(40)

Опубликована: Авг. 25, 2017

Abstract The design of highly efficient, stable, and noble‐metal‐free bifunctional electrocatalysts for overall water splitting is critical but challenging. Herein, a facile controllable synthesis strategy nickel–cobalt bimetal phosphide nanotubes as efficient via low‐temperature phosphorization from bimetallic metal‐organic framework (MOF‐74) precursor reported. By optimizing the molar ratio Co/Ni atoms in MOF‐74, series Co x Ni y P catalysts are synthesized, obtained Co4Ni1P has rare form that possess similar morphology to MOF exhibit perfect dispersal active sites. show remarkable hydrogen evolution reaction (HER) oxygen (OER) catalytic performance an alkaline electrolyte, affording current density 10 mA cm −2 at overpotentials 129 mV HER 245 OER, respectively. An electrolyzer with both cathode anode catalyst solutions achieves voltage 1.59 V, which comparable integrated Pt/C RuO 2 counterparts ranks among best metal‐phosphide reported date.

Язык: Английский

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Non-precious-metal catalysts for alkaline water electrolysis: operando characterizations, theoretical calculations, and recent advances

Chemical Society Reviews, Год журнала: 2020, Номер 49(24), С. 9154 - 9196

Опубликована: Янв. 1, 2020

Advances of non-precious-metal catalysts for alkaline water electrolysis are reviewed, highlighting operando techniques and theoretical calculations in their development.

Язык: Английский

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