Advanced Functional Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Ноя. 14, 2024
Abstract
Garnet‐type
solid‐state
electrolytes
with
exceptional
stability
are
believed
to
promote
the
commercialization
of
all
lithium
metal
batteries.
However,
extensive
application
garnet‐type
is
greatly
impeded
on
account
their
low
ionic
conductivity.
Herein,
a
high‐entropy
fast
lithium‐ion
conductor
Li
7
(La,Nd,Sr)
3
(Zr,Ta)
2
O
12
(LLNSZTO)
high
lattice
distortion
designed.
It
found
that
enhanced
conductivity
entropy
electrolyte
LLNSZTO
achieved
by
introducing
disorder
in
lattice,
which
creates
ion
penetration
paths
flattened
energy
landscapes
within
pristine
ordered
lattice.
Thus,
prepared
solid
exhibits
activation
for
+
migration
(0.34
eV)
and
elevated
(6.26
×
10
−4
S
cm
−1
).
Full
cells
assembled
electrolyte,
anode,
LiFePO
4
(LFP)
cathode
exhibit
excellent
capacity
retention
86.81%
after
200
cycles
at
room
temperature.
Moreover,
superior
enables
battery
high‐loading
LFP
(>12
mg
−2
),
achieving
stable
cycling
exceeding
120
cycles.
The
large
area
pouch
cell
(5.5
8
cm)
long‐term
performance,
showing
96.50%
50
Advanced Functional Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Июнь 10, 2024
Abstract
Lithium
metal
batteries
(LMBs)
are
considered
as
one
type
of
the
most
promising
next‐generation
energy
storage
devices
with
high‐energy‐density,
and
stabilizing
lithium
anodes
(LMAs)
to
overcome
LMBs’
safety
concerns
performance
degradation
has
attracted
extensive
attention.
Introducing
advanced
polymer
materials
into
critical
components
LMBs
proven
be
an
effective
approach
for
LMAs
toward
practical
application
LMBs.
In
addressing
lack
a
timely
review
on
emerging
progress
in
LMAs,
comprehensive
article
summarizing
recent
developments
multiscale
cellulose
materials,
including
micron
(MC)
nanocellulose
(NC),
is
reviewed.
First,
basic
structures
cellulose,
characteristics
comparison,
development
history
introducing
presented.
Furthermore,
roles
functional
mechanisms
various
summarized.
A
general
conclusion
perspective
current
limitations
future
research
directions
cellulose‐based
stable
proposed.
The
aim
this
not
only
summarize
but
also
lighten
pathways
realizing
application.
Angewandte Chemie International Edition,
Год журнала:
2024,
Номер
unknown
Опубликована: Июль 18, 2024
Zn
metal
as
a
promising
anode
for
aqueous
batteries
suffers
from
severe
zinc
dendrites,
anion-related
side
reactions,
hydrogen
evolution
reaction
(HER)
and
narrow
electrochemical
stable
window
(ESW).
Herein,
an
"anions-in-colloid"
hydrated
deep
eutectic
electrolyte
consisting
of
Zn(ClO
Advanced Functional Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Ноя. 14, 2024
Abstract
Garnet‐type
solid‐state
electrolytes
with
exceptional
stability
are
believed
to
promote
the
commercialization
of
all
lithium
metal
batteries.
However,
extensive
application
garnet‐type
is
greatly
impeded
on
account
their
low
ionic
conductivity.
Herein,
a
high‐entropy
fast
lithium‐ion
conductor
Li
7
(La,Nd,Sr)
3
(Zr,Ta)
2
O
12
(LLNSZTO)
high
lattice
distortion
designed.
It
found
that
enhanced
conductivity
entropy
electrolyte
LLNSZTO
achieved
by
introducing
disorder
in
lattice,
which
creates
ion
penetration
paths
flattened
energy
landscapes
within
pristine
ordered
lattice.
Thus,
prepared
solid
exhibits
activation
for
+
migration
(0.34
eV)
and
elevated
(6.26
×
10
−4
S
cm
−1
).
Full
cells
assembled
electrolyte,
anode,
LiFePO
4
(LFP)
cathode
exhibit
excellent
capacity
retention
86.81%
after
200
cycles
at
room
temperature.
Moreover,
superior
enables
battery
high‐loading
LFP
(>12
mg
−2
),
achieving
stable
cycling
exceeding
120
cycles.
The
large
area
pouch
cell
(5.5
8
cm)
long‐term
performance,
showing
96.50%
50
