Materials Horizons,
Год журнала:
2024,
Номер
11(22), С. 5499 - 5532
Опубликована: Янв. 1, 2024
High-performance
perovskite
materials
with
excellent
physical,
electronic,
and
optical
properties
play
a
significant
role
in
artificial
neuromorphic
devices.
However,
the
development
of
perovskites
microelectronics
is
inevitably
hindered
by
their
intrinsic
non-ideal
properties,
such
as
high
defect
density,
environmental
sensitivity,
toxicity.
By
leveraging
engineering,
integrating
various
to
leverage
mutual
strengths
presents
great
potential
enhance
ion
migration,
energy
level
alignment,
photoresponsivity,
surface
passivation,
thereby
advancing
optoelectronic
device
development.
This
review
initially
provides
an
overview
across
different
dimensions,
highlighting
physical
detailing
applications
metrics
two-
three-terminal
Subsequently,
we
comprehensively
summarize
application
combination
other
materials,
including
organics,
nanomaterials,
oxides,
ferroelectrics,
crystalline
porous
(CPMs),
develop
advanced
devices
memristors,
transistors,
photodetectors,
sensors,
light-emitting
diodes
(LEDs),
systems.
Lastly,
outline
challenges
future
research
directions
synthesizing
composites
for
Through
analysis,
aim
broaden
utilization
research,
offering
new
insights
approaches
grasping
intricate
working
mechanisms
functionalities
perovskites.
Angewandte Chemie International Edition,
Год журнала:
2024,
Номер
63(7)
Опубликована: Янв. 2, 2024
Layered
two-dimensional
(2D)
perovskites
are
emerging
as
promising
optoelectronic
materials
owing
to
their
excellent
environmental
stability.
Regulating
the
dipole
moment
of
organic
spacers
has
potential
reduce
exciton
binding
energy
(E
Advanced Energy Materials,
Год журнала:
2024,
Номер
14(10)
Опубликована: Янв. 9, 2024
Abstract
The
efficiency
of
perovskite
solar
cells
(PSCs)
is
hindered
by
substantial
defects
within
the
grain
boundaries
(GBs)
polycrystalline
films.
Conventional
post‐treatment
strategies
struggle
to
precisely
repair
these
at
GBs.
Here,
a
targeted
boundary
passivation
strategy
through
solvent
effects
incorporating
symmetrical
biphenyl
molecules
proposed,
4,4′‐diaminodiphenyl
sulfone
(DDS)
and
4,4′‐sulfodiphenol
(SDP),
aiming
mitigate
GBs
optimize
energy
level
arrangements
their
electric
dipole
effects.
Compared
pristine
device,
SDP‐modified
device
exhibits
significant
improvements,
including
champion
24.39%
an
impressive
fill
factor,
along
with
excellent
operation
stability.
This
work
provides
effective
straightforward
solution
for
improving
performance
PSCs.
Energy & Environmental Science,
Год журнала:
2024,
Номер
17(19), С. 7342 - 7354
Опубликована: Янв. 1, 2024
Tetrafluorosuccinic
acid
was
introduced
into
the
buried
interface
to
stabilize
FA
cations,
mediate
crystal
growth
of
perovskite
and
reduce
hole-transport
barrier,
delivering
a
record
efficiency
25.92%
for
RbCsFAMA-based
solar
cells.
Advanced Materials,
Год журнала:
2024,
Номер
36(31)
Опубликована: Май 23, 2024
Compared
to
3D
perovskites,
2D
perovskites
exhibit
excellent
stability,
structural
diversity,
and
tunable
bandgaps,
making
them
highly
promising
for
applications
in
solar
cells,
light-emitting
diodes,
photodetectors.
However,
the
trade-off
worse
charge
transport
is
a
critical
issue
that
needs
be
addressed.
This
comprehensive
review
first
discusses
structure
of
metal
halide
then
summarizes
significant
factors
influencing
detail
provides
brief
overview
testing
methods.
Subsequently,
various
strategies
improve
are
presented,
including
tuning
A'-site
organic
spacer
cations,
A-site
B-site
X-site
ions.
Finally,
an
outlook
on
future
development
improving
perovskites'
discussed.
Advanced Materials,
Год журнала:
2024,
Номер
36(23)
Опубликована: Фев. 20, 2024
Abstract
Wide‐bandgap
mixed‐halogen
perovskite
materials
are
widely
used
as
top
cells
in
tandem
solar
cells.
However,
serious
open‐circuit
voltage
(
V
oc
)
loss
restricts
the
power
conversion
efficiency
(PCE)
of
wide‐bandgap
(PSCs).
Herein,
it
is
shown
that
resulting
methylammonium
vacancies
induce
lattice
distortion
chloride‐assisted
film,
an
inhomogeneous
halogen
distribution
and
low
.
Thus,
a
strain
regulation
strategy
reported
to
fabricate
high‐performance
PSCs.
Rubidium
(Rb)
cations
introduced
fill
A‐site
vacancy
caused
by
volatilization,
which
alleviates
shrinkage
crystal.
The
reduced
increased
halide
ion
migration
barrier
result
homogeneous
mixed‐halide
film.
Due
improved
carrier
transport
suppressed
nonradiative
recombination,
Rb‐treated
PSC
(1.68
eV)
achieves
excellent
PCE
21.72%,
accompanied
high
1.22
V.
device
maintains
more
than
90%
its
initial
after
1500
h
under
1‐sun
illumination
conditions.
Advanced Materials,
Год журнала:
2024,
Номер
36(35)
Опубликована: Июль 7, 2024
Interface-induced
nonradiative
recombination
losses
at
the
perovskite/electron
transport
layer
(ETL)
are
an
impediment
to
improving
efficiency
and
stability
of
inverted
(p-i-n)
perovskite
solar
cells
(PSCs).
Tridecafluorohexane-1-sulfonic
acid
potassium
(TFHSP)
is
employed
as
a
multifunctional
dipole
molecule
modify
surface.
The
solid
coordination
hydrogen
bonding
efficiently
passivate
surface
defects,
thereby
reducing
recombination.
induced
positive
between
ETLs
improves
energy
band
alignment,
enhancing
interface
charge
extraction.
Additionally,
strong
interaction
TFHSP
stabilizes
surface,
while
hydrophobic
fluorinated
moieties
prevent
ingress
water
oxygen,
device
stability.
resultant
devices
achieve
power
conversion
(PCE)
24.6%.
unencapsulated
retain
91%
their
initial
after
1000
h
in
air
with
60%
relative
humidity,
95%
500
under
maximum
point
(MPP)
tracking
35
°C.
utilization
molecules
opens
new
avenues
for
high-performance
long-term
stable
devices.
ABSTRACT
Perovskite
solar
cells
(PSCs)
are
regarded
as
the
most
promising
new
generation
of
green
energy
technology
due
to
their
outstanding
device
performance
and
simple
processing
technology.
Traditional
methods,
such
thermal
annealing
evaporation,
face
significant
challenges
in
further
enhancing
stability.
In
recent
years,
laser
has
garnered
extensive
attention
from
researchers
its
notable
advantages
terms
speed,
high
efficiency,
controllability.
this
review,
we
systematically
summarize
role
active
layer,
transport
electrode
perovskite
photovoltaic
cells.
First,
elucidate
mechanism
governing
nucleation
crystallization
laser‐processed
films,
along
with
influence
on
micro‐nano
structures
these
films.
Concurrently,
a
thorough
explication
pertaining
interconnection
between
layers,
electrode,
respective
impacts
carrier
collection
efficiency
within
will
be
provided.
Most
importantly,
believe
that
approaches
provide
scientists
ways
thinking
system
schemes
for
improving
stability
Advanced Materials,
Год журнала:
2023,
Номер
35(39)
Опубликована: Июнь 16, 2023
Formamidinium
lead
iodide
(FAPbI3
)
perovskite
possesses
an
ideal
optical
bandgap
and
is
a
potential
material
for
fabricating
the
most
efficient
single-junction
solar
cells
(PSCs).
Nevertheless,
large
formamidinium
(FA)
cations
result
in
residual
lattice
strain,
which
reduces
power
conversion
efficiency
(PCE)
operational
stability
of
PSCs.
Herein,
modulation
strain
FAPbI3
crystals
via
π-conjugated
organic
amine,
i.e.,
4-pyrene
oxy
butylamine
(PYBA),
proposed.
PYBA
pairs
at
grain
boundary
serve
as
template
crystallization
perovskite,
thereby
inducing
highly
oriented
crystal
pure
α-phase
film.
The
with
strong
π-π
interactions
provide
solid
fulcrum
external
compression
thus
compensating
inherent
tension
crystals.
release
elevates
valence
band
crystals,
decreasing
trap
density.
Consequently,
PYBA-regulated
PSC
achieves
excellent
PCE
24.76%.
Moreover,
resulting
device
exhibits
improves
maintains
over
80%
its
initial
after
1500
h
under
maximum
point
tracking
conditions.
