Copper(II) isonicotinate metal-organic framework for reusable adsorption of salmeterol from wastewater DOI
Usman Armaya’u, Muttaqa Uba Zango, Marinah Mohd Ariffin

и другие.

Deleted Journal, Год журнала: 2024, Номер unknown, С. 100030 - 100030

Опубликована: Окт. 1, 2024

Язык: Английский

Interface molecular mineralization enables green, scalable fabrication of MOF-fabric composites DOI
Yating Ji, Weifeng Yang, Xiaoyan Li

и другие.

Journal of Cleaner Production, Год журнала: 2025, Номер unknown, С. 145094 - 145094

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

0
Breakthrough developments in Metal-Organic frameworks (MOFs) for efficient C4 hydrocarbon adsorption separation DOI
Zilin Xu, Siqi Chen, Bingjie Yang

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 160992 - 160992

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

0
Engineering Supramolecular Binding Sites in an Ultrastable and Hydrophobic Metal–Organic Framework for C2H6/C2H4 Separation DOI

Chenyi Yu,

Keke Wang,

Beiyu Zhao

и другие.

Inorganic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Апрель 7, 2025

The separation of ethane (C2H6) from ethylene (C2H4) is critical for obtaining polymer-grade C2H4. Adsorptive with C2H6-selective MOFs offers a viable alternative to energy-intensive cryogenic distillation, enabling the direct production high-purity In this study, we developed an ultrastable ethane-selective metal-organic framework, UiO-67-(CH3)2, which demonstrates enhanced C2H6 adsorption (4.10 mmol g-1 at 1 bar and 298 K), higher C2H6/C2H4 selectivity 1.70, increased ratio 1.53 compared unmodified UiO-67. GCMC simulations demonstrate that forms more C-H···π interactions surrounding benzene rings C-H···C methyl groups C2H4, highlighting synergistic effects supramolecular interactions. Furthermore, hydrophobic pore environment also minimizes water interference, exceptionally low uptake (0.019 g 60% RH), ensuring robust capacity under high humid conditions. introduction not only significantly enhances performance but improves material's hydrophobicity.

Язык: Английский

Процитировано

0
Adsorption separation of propylene/propane by pressure induced flexible porous MOF DOI
Huiping Chen, Meiling Li, Dongxu Gu

и другие.

Microporous and Mesoporous Materials, Год журнала: 2025, Номер unknown, С. 113644 - 113644

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0
In situ conversion of ZnO anchored on porous carbon foams to antiflexible ZIF-8-X (X = Co or NH2) for sieving linear and mono-branched hexane isomers DOI
Xufei Li,

Yankang Zhou,

Weiqiu Huang

и другие.

Chemical Engineering Journal, Год журнала: 2024, Номер 488, С. 151146 - 151146

Опубликована: Апрель 8, 2024

Язык: Английский

Процитировано

3
Stepwise tuning carbon slits at sub-angstrom scale for dynamical separation of hydrogen isotope DOI
Yongsheng Wang, Tianyi Li,

Y. J. Song

и другие.

Separation and Purification Technology, Год журнала: 2024, Номер 354, С. 129130 - 129130

Опубликована: Авг. 9, 2024

Язык: Английский

Процитировано

3
Sustainable synthesis and morphology-controlled metal-organic framework for exceptional CO2 capture performance using DFT insights DOI
Amir Kazemi, Mahyar Ashourzadeh Pordsari, Mohsen Tamtaji

и другие.

Separation and Purification Technology, Год журнала: 2024, Номер unknown, С. 131328 - 131328

Опубликована: Дек. 1, 2024

Язык: Английский

Процитировано

3
Pore Environmental Modification by Amino Groups in Robust Microporous MOFs for SF6 Capturing and SF6/N2 Separation DOI
Yongpeng Li,

J.L. Ni,

Xiaojie Zhang

и другие.

Inorganic Chemistry, Год журнала: 2024, Номер 63(29), С. 13568 - 13575

Опубликована: Июль 8, 2024

Capturing and separating the greenhouse gas SF

Язык: Английский

Процитировано

2
An MOF-Based Single-Molecule Propylene Nanotrap for Benchmark Propylene Capture from Ethylene DOI Creative Commons
Jia‐Xin Wang, Tengfei Zhang, Jiyan Pei

и другие.

Chem & Bio Engineering, Год журнала: 2024, Номер 1(11), С. 952 - 959

Опубликована: Июль 29, 2024

Highly selective capture and separation of propylene (C3H6) from ethylene (C2H4) presents one the most crucial processes to obtain pure C2H4 in petrochemical industry. The performance current physisorbents is commonly limited by insufficient C3H6 binding affinity, resulting poor low-pressure uptakes or inadequate C3H6/C2H4 selectivities. Herein, we realize a unique single-molecule nanotrap an ultramicroporous MOF material (Co(pyz)[Pd(CN)4], ZJU-74a-Pd), exhibiting benchmark capacity at regions. This MOF-based features sandwichlike strong multipoint sites perfect size match with molecules, providing ultrastrong affinity maximal Q st value (55.8 kJ mol-1). affords exhibit highest low pressures (60.5 103.8 cm3 cm-3 0.01 0.1 bar) record-high selectivity (23.4). Theoretical calculations reveal that perfectly size-matched pore cavities combined multibinding enable this maximize mainly accounting for its record selectivity. Breakthrough experiments further confirm excellent actual 1/99 50/50 mixtures, affording remarkably high productivities 17.1 3.4 mol kg-1, respectively.

Язык: Английский

Процитировано

2
One-step purification of ethylene from ethane/ethylene mixtures by a stable vanadium-based metal-organic framework DOI
Meiling Li, Shanshan Mao, Xin Zhou

и другие.

Separation and Purification Technology, Год журнала: 2024, Номер unknown, С. 131049 - 131049

Опубликована: Дек. 1, 2024

Язык: Английский

Процитировано

1