Copper(II) isonicotinate metal-organic framework for reusable adsorption of salmeterol from wastewater DOI
Usman Armaya’u, Muttaqa Uba Zango, Marinah Mohd Ariffin

et al.

Deleted Journal, Journal Year: 2024, Volume and Issue: unknown, P. 100030 - 100030

Published: Oct. 1, 2024

Language: Английский

Interface molecular mineralization enables green, scalable fabrication of MOF-fabric composites DOI
Yating Ji, Weifeng Yang, Xiaoyan Li

et al.

Journal of Cleaner Production, Journal Year: 2025, Volume and Issue: unknown, P. 145094 - 145094

Published: Feb. 1, 2025

Language: Английский

Citations

0
Breakthrough developments in Metal-Organic frameworks (MOFs) for efficient C4 hydrocarbon adsorption separation DOI
Zilin Xu, Siqi Chen, Bingjie Yang

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160992 - 160992

Published: Feb. 1, 2025

Language: Английский

Citations

0
Engineering Supramolecular Binding Sites in an Ultrastable and Hydrophobic Metal–Organic Framework for C2H6/C2H4 Separation DOI

Chenyi Yu,

Keke Wang,

Beiyu Zhao

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 7, 2025

The separation of ethane (C2H6) from ethylene (C2H4) is critical for obtaining polymer-grade C2H4. Adsorptive with C2H6-selective MOFs offers a viable alternative to energy-intensive cryogenic distillation, enabling the direct production high-purity In this study, we developed an ultrastable ethane-selective metal-organic framework, UiO-67-(CH3)2, which demonstrates enhanced C2H6 adsorption (4.10 mmol g-1 at 1 bar and 298 K), higher C2H6/C2H4 selectivity 1.70, increased ratio 1.53 compared unmodified UiO-67. GCMC simulations demonstrate that forms more C-H···π interactions surrounding benzene rings C-H···C methyl groups C2H4, highlighting synergistic effects supramolecular interactions. Furthermore, hydrophobic pore environment also minimizes water interference, exceptionally low uptake (0.019 g 60% RH), ensuring robust capacity under high humid conditions. introduction not only significantly enhances performance but improves material's hydrophobicity.

Language: Английский

Citations

0
Adsorption separation of propylene/propane by pressure induced flexible porous MOF DOI
Huiping Chen, Meiling Li, Dongxu Gu

et al.

Microporous and Mesoporous Materials, Journal Year: 2025, Volume and Issue: unknown, P. 113644 - 113644

Published: April 1, 2025

Language: Английский

Citations

0
In situ conversion of ZnO anchored on porous carbon foams to antiflexible ZIF-8-X (X = Co or NH2) for sieving linear and mono-branched hexane isomers DOI
Xufei Li,

Yankang Zhou,

Weiqiu Huang

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 488, P. 151146 - 151146

Published: April 8, 2024

Language: Английский

Citations

3
Stepwise tuning carbon slits at sub-angstrom scale for dynamical separation of hydrogen isotope DOI
Yongsheng Wang, Tianyi Li,

Y. J. Song

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 354, P. 129130 - 129130

Published: Aug. 9, 2024

Language: Английский

Citations

3
Sustainable synthesis and morphology-controlled metal-organic framework for exceptional CO2 capture performance using DFT insights DOI
Amir Kazemi, Mahyar Ashourzadeh Pordsari, Mohsen Tamtaji

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 131328 - 131328

Published: Dec. 1, 2024

Language: Английский

Citations

3
Pore Environmental Modification by Amino Groups in Robust Microporous MOFs for SF6 Capturing and SF6/N2 Separation DOI
Yongpeng Li,

J.L. Ni,

Xiaojie Zhang

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(29), P. 13568 - 13575

Published: July 8, 2024

Capturing and separating the greenhouse gas SF

Language: Английский

Citations

2
An MOF-Based Single-Molecule Propylene Nanotrap for Benchmark Propylene Capture from Ethylene DOI Creative Commons
Jia‐Xin Wang, Tengfei Zhang, Jiyan Pei

et al.

Chem & Bio Engineering, Journal Year: 2024, Volume and Issue: 1(11), P. 952 - 959

Published: July 29, 2024

Highly selective capture and separation of propylene (C3H6) from ethylene (C2H4) presents one the most crucial processes to obtain pure C2H4 in petrochemical industry. The performance current physisorbents is commonly limited by insufficient C3H6 binding affinity, resulting poor low-pressure uptakes or inadequate C3H6/C2H4 selectivities. Herein, we realize a unique single-molecule nanotrap an ultramicroporous MOF material (Co(pyz)[Pd(CN)4], ZJU-74a-Pd), exhibiting benchmark capacity at regions. This MOF-based features sandwichlike strong multipoint sites perfect size match with molecules, providing ultrastrong affinity maximal Q st value (55.8 kJ mol-1). affords exhibit highest low pressures (60.5 103.8 cm3 cm-3 0.01 0.1 bar) record-high selectivity (23.4). Theoretical calculations reveal that perfectly size-matched pore cavities combined multibinding enable this maximize mainly accounting for its record selectivity. Breakthrough experiments further confirm excellent actual 1/99 50/50 mixtures, affording remarkably high productivities 17.1 3.4 mol kg-1, respectively.

Language: Английский

Citations

2
One-step purification of ethylene from ethane/ethylene mixtures by a stable vanadium-based metal-organic framework DOI
Meiling Li, Shanshan Mao, Xin Zhou

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 131049 - 131049

Published: Dec. 1, 2024

Language: Английский

Citations

1