Laser & Photonics Review,
Год журнала:
2025,
Номер
unknown
Опубликована: Апрель 23, 2025
Abstract
Interfacial
molecular
engineering
of
rare
earth‐doped
nanocrystals
(RE
NCs)
by
incorporating
surface
organic
emitters
is
receiving
widespread
attention
in
the
area
functional
nanomaterials.
The
resulting
organic–inorganic
nanoconjugates
are
able
to
integrate
individual
strengths
and
show
exciting
optical/electrical/magnetic
functionalities.
However,
there
a
shortage
systematic
reviews
reporting
most
recent
progress
interfacial
RE
NCs.
Thereby,
this
review
presents
comprehensive
timely
perspective
on
advances
crucial
theoretical
knowledge
first
summarized,
ranging
from
luminescence
mechanism
molecules/RE
NCs
energy
transfer
mechanisms
at
interface.
Construction
protocols
for
coupling
molecules
then
discussed,
including
chemical
coordination
physical
adsorption
pathways.
In
particular,
beyond
traditional
bio‐imaging/therapy,
advanced
applications
enabled
interface
outlined,
not
limited
photoexcited
3D
printing,
light‐induced
photochromism/deformation,
micro‐modification,
dynamic
procedure
regulation.
Finally,
challenges
perspectives
presented
accelerate
future
provide
research
guidance
This
provides
deeper
broader
understanding
NC
pushes
technology
closer
practical
applications.
Advanced Functional Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 20, 2025
Abstract
Engineering
wearable
devices
for
in
situ
and
on‐site
monitoring
of
pesticide
residues
from
plants
a
non‐destructive
manner
is
great
research
value
but
remains
huge
challenge.
In
this
study,
plant‐wearable
fluorescence
sensor
CdTe
CDs@PVA@AG,
designed
constructed
by
embedding
QDs
polyvinyl
alcohol
(PVA)
agarose
(AG)‐co‐assembled
double‐network
hydrogel
to
transmit
on‐the‐scene
pesticides
messages.
Harnessing
red
emission
stimuli‐responsive
performance
QDs,
as
well
hydrogel's
excellent
flexibility,
high
adhesion,
porous
network,
CDs@PVA@AG
endowed
with
quantitative
response
thiram
at
≈µ
m
level
within
2
min
through
promoting
silence
conjunction
the
transformation
images
into
primary
colors
digital
signals.
More
interestingly,
capable
being
tightly
pasted
onto
various
crops’
surfaces
then
not
only
explored
appraise
residue
levels
also
profile
dynamic
degradation,
manner.
This
work
opens
up
new
avenue
engineer
situ,
on‐site,
capturing
information
crops,
favoring
accurate
health
status
rapid
healthy
development
smart
agriculture.
Advanced Functional Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 2, 2025
Abstract
Smart
hydrogels
with
multi‐fluorescent
properties
hold
great
promise
for
information
encryption.
However,
conventional
fluorescent
often
lack
adequate
mechanical
and
multiple
responsiveness,
limiting
their
range
of
applications.
In
this
study,
a
multifunctional
hydrogel
featuring
an
interpenetrating
polymer
network
(IPN)
composed
poly(vinyl
alcohol)
(PVA)
poly(acrylic
amide‐co‐2‐acrylamido‐2‐methylpropane
sulfonic
acid)
P(AM/AMPS)
chemical
cross‐linking
networks
is
designed.
Through
the
coordination
lanthanide
ions
(Eu
3+
,
Tb
)
glycine,
achieves
exceptional
stretchability
(over
900%)
adjustable
photoluminescence
properties.
Due
to
acid
groups
on
2‐acrylamide‐2‐methylpropanesulfonic
(AMPS),
which
support
various
noncovalent
interactions,
PVA‐P(AM/AMPS)‐Gly‐Ln
displays
strong
reversible
adhesive
diverse
substrates.
Ultimately,
assembled
into
multifunctional,
flexible
sensor,
boasting
satisfactory
sensitivity
(GF
=
5.3),
rapid
response
rate
(100
ms),
outstanding
characteristics,
highlighting
its
potential
applications
in
human
motion
detection
Nature Communications,
Год журнала:
2025,
Номер
16(1)
Опубликована: Март 22, 2025
Leveraging
the
rich
stimuli-response
of
polymers
represents
a
promising
direction
towards
optical
communication/encryption.
Sign
language,
which
relies
on
specific
geometric
change
for
secured
communication,
has
been
widely
used
same
purpose
since
ancient
time.
We
report
strategy
that
combines
both
in
validated
manner
with
hydrogel
not
only
carries
encrypted
information
but
also
hidden
behavior
to
morph
geometrically.
In
particular,
shape
morphing
is
programmable
by
controlling
oriented
state
polymer
chain
thermo-responsive
network.
Whether
positive
(bending)
or
negative
(flattening)
cannot
be
predicted
when
polymerization
methods
are
informed,
revealing
manner.
Through
deciphering
coupling
elastic
stresses
and
thermo-induced
deswelling
stress,
can
perform
designed
diversified
4D
evolution
3D
geometries
time
as
fourth
dimension.
Consequently,
corresponding
gated
based
these
features,
thereby
decrypting
correct
permutation
information.
Our
approach
utilizes
verification
offers
enhancing
security
communication
ways
quite
different
from
existing
strategies.
Stimuli
responsive
hydrogels
always
complex
required.
Here,
authors
use
Advanced Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Март 20, 2025
Abstract
Rare‐earth
afterglow
materials,
with
their
unique
light‐storage
properties,
show
great
promise
for
diverse
applications.
However,
broader
applicability
is
constrained
by
challenges
such
as
poor
solvent
compatibility,
limited
luminescent
efficiency,
and
monochromatic
emissions.
In
this
study,
these
limitations
are
addressed
blending
ZnS
various
rare‐earth
phosphors
including
(Sr
0.75
Ca
0.25
)S:Eu
2+
;
SrAl
2
O
4
:Eu
,
Dy
3+
Sr
MgSi
7
to
modulate
deep
trap
mechanisms
significantly
enhance
both
the
light
capture
capabilities.
Using
electrospinning,
a
large‐area
(0.4
m
×
3
m)
film
successfully
fabricated
tunable
colors
an
extended
duration
exceeding
30
h.
This
demonstrates
thermoluminescence,
enabling
potential
integration
into
fire‐rescue
protective
clothing
enhanced
emergency
visibility.
greenhouse
settings,
it
effectively
supports
chlorophyll
synthesis
optimizes
conditions
plant
growth
over
24‐h
cycle.
For
tunnel
garage
applications,
captures
stores
from
vehicle
headlights
at
distances
of
up
70
meters.
The
scalability
cost‐effectiveness
underscore
its
considerable
real‐world
applications
across
multiple
fields,
marking
significant
advancement
in
sustainable
illumination
technology.
Advanced Science,
Год журнала:
2025,
Номер
unknown
Опубликована: Фев. 14, 2025
Abstract
Supramolecular
dynamic
room
temperature
phosphorescence
(RTP)
is
the
focus
of
current
research
because
its
wide
application
in
biological
imaging
and
information
anti‐counterfeiting.
Herein,
a
time‐dependent
supramolecular
lanthanide
phosphorescent
4D
assembly
material
with
multicolor
luminescence
including
white,
which
composed
4‐(4‐bromophenyl)‐pyridine
salt
derivative
(G),
inorganic
clay
(LP)/Eu
complex
pyridine
dicarboxylic
acid
(DPA)
reported.
Compared
self‐assembled
nanoparticle
G,
lamellar
G/LP
showed
double
emission
fluorescence
at
380
nm
516
over
time.
Within
60
min,
lifetime
quantum
yield
increases
from
none
to
7.4
ms
27.53%
respectively,
achieving
emission,
due
limitation
progressive
stacking
LP
electrostatically
driven
“domino
effect.”
Furthermore,
DPA
G/LP/Eu
leads
time‐resolved
colorless
purple
successfully
applied
multi‐level
logic
anti‐counterfeiting
efficiently
antibiotic
selective
sensor.
Advanced Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Фев. 19, 2025
Abstract
Organic
room
temperature
phosphorescence
(ORTP)
polymer
materials
have
sparked
considerable
research
interests
in
recent
years,
but
their
optical
function
is
still
limited
for
multi‐mode
imaging.
Herein,
a
feasible
and
universal
approach
proposed
to
endow
ORTP
with
periodic
refractive
index
modulation
functions
by
holographic
patterning.
The
key
this
design
two‐stage
stepwise
crosslinking.
Stage‐1,
low
crosslinking
density
(≤0.75
mol
L
−1
),
phosphorescence‐silent
can
provide
greater
free
volume
monomer
diffusion
thus
facilitate
the
patterning
of
modulated
holograms
via
photopolymerization‐induced
phase
separation.
dense
at
stage‐2
turn
on
intensity
rising
144%
when
increases
from
3.77
4.12
.
enhanced
primarily
ascribed
increase
conformational
distortion
spin‐orbit
coupling
organic
phosphors
based
theoretical
calculations.
Eventually,
first
example
demonstrated
plastic
unique
capability
independently
displaying
andphosphorescent
images.
This
work
not
only
provides
novel
paradigm
impart
added
also
paves
way
development
high‐security
combat
counterfeiting.
Taking
inspiration
from
the
dynamic
memory
of
human
brain,
which
has
ability
to
spontaneously
forget
unimportant
information,
a
universal
and
straightforward
method
for
creating
spatiotemporally
regulated
hydrogels
with
electrofluorochromic
characteristics
that
exhibit
information
"memorizing-forgetting"
behavior
is
presented.
The
reversible
electrofluorochromism
blue
red
in
Eu3+-based
achieved
by
rapid
changes
fluorescence
triggered
electricity,
coupled
gradual
disappearance
associated
mass
diffusion
hydrogel.
This
process
involves
generation
H2
an
acidic
aqueous
solution
under
resulting
conversion
β-diketone
derivatives
keto
enol
forms
disruption
hydrogen
bonds
between
─COOH
polyacrylic
acid
(PAA)
N
pyridine
groups.
fluorescent
mechanical
are
facilely
tuned
power
on
time,
contents
components,
types
network
structures
as
well
derivatives.
Finally,
hydrogel
arrays
or
films
can
be
utilized
programmable
accurate
encryption,
decryption,
self-erasure.
Advanced Functional Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Март 26, 2025
Abstract
Zwitterionic
hydrogels
have
attracted
intensive
attentions
for
their
exceptional
hydration
and
anti‐fouling
properties,
while
the
exploration
rational
structural
designs
to
achieve
multi‐function
superior
anti‐freezing
capability
remains
an
ongoing
mission.
Herein,
a
new
multi‐functional
zwitterionic
monomer
(ACHPES)
is
designed
developed
from
which
novel
are
fabricated.
The
pyridinium‐sulfonate
motif
endows
hydrogel
with
discoloration
in
both
visible
light
fluorescence
response
pH
stimulus,
enabling
unique
multi‐channel
information
encryption
highly
sensitive
Cu
2+
detection
threshold
of
0.64
ppm.
design
carbamate
group
fulfils
high
bonding
capacity
water,
leading
capability.
As
such,
exhibit
extremely
low
water
freezing
point
−47.3
°C
breaking
elongation
≈500%
at
−20
°C.
outstanding
enables
sensors
electrolytes
excellent
operational
performance
temperatures.
This
innovative
strategy
offers
avenue
functionalization
application
icy
temperature.
