A coopetition-driven strategy of parallel/perpendicular aromatic stacking enabling metastable supramolecular polymerization DOI Creative Commons
Zhao Gao, Xuxu Xie,

Juan Zhang

и другие.

Nature Communications, Год журнала: 2024, Номер 15(1)

Опубликована: Дек. 30, 2024

Metastable supramolecular polymerization under kinetic control has recently been recognized as a closer way to biosystem than thermodynamic process. While impressive works on metastable systems have reported, the library of available non-covalent driving modes is still small and simple yet versatile solution highly desirable design for easily regulating energy landscapes aggregation. Herein, we propose coopetition-driven metastability strategy parallel/perpendicular aromatic stacking construct polymers derived from class monomers consisting lateral indoles core. By subtly increasing strength cores phenyl anthryl, parallel face-to-face stacked aggregates are competitively formed products, which spontaneously transform into thermodynamically favorable species through cooperativity perpendicular edge-to-face offset stacking. The slow kinetic-to-thermodynamic transformation could be accelerated by adding seeds realizing desired living polymerization. Besides, this accompanied time-dependent emission change red yellow employed dynamic cell imaging, largely avoiding background interferences. coopetition relationship different expected serve an effective towards pathway-controlled functional materials.

Язык: Английский

Scaling-up molecular logic to meso-systems via self-assembly DOI Creative Commons
Ze-Qing Chen,

Brian Daly,

Chaoyi Yao

и другие.

Nature Communications, Год журнала: 2025, Номер 16(1)

Опубликована: Март 28, 2025

Язык: Английский

Процитировано

0
Algorithm in chemistry: molecular logic gate-based data protection DOI
Yu Dong, Shiyu Feng, Weiguo Huang

и другие.

Chemical Society Reviews, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

This review focuses on stimuli-responsive material (SRM)-based data protection, emphasizing the integration of intricate logic and algorithms in SRM-constructed hardware. It also discusses current challenges future directions field.

Язык: Английский

Процитировано

0
Self‐Assembled Metal Complexes in Biomedical Research DOI

Wenting Wang,

Yang Xu, Yuqi Tang

и другие.

Advanced Materials, Год журнала: 2024, Номер unknown

Опубликована: Дек. 23, 2024

Abstract Cisplatin is widely used in clinical cancer treatment; however, its application often hindered by severe side effects, particularly inherent or acquired resistance of target cells. To address these challenges, an effective strategy to modify the metal core complex and introduce alternative coordination modes valence states, leading development a series complexes, such as platinum (IV) prodrugs cyclometalated complexes. Recent advances nanotechnology have facilitated multifunctional nanomaterials that can selectively deliver drugs tumor cells, thereby overcoming pharmacological limitations metal‐based drugs. This review first explores self‐assembly complexes into spherical, linear, irregular nanoparticles context biomedical applications. The mechanisms underlying are subsequently analyzed, followed discussion their applications fields, including detection, imaging, antitumor research.

Язык: Английский

Процитировано

2
A coopetition-driven strategy of parallel/perpendicular aromatic stacking enabling metastable supramolecular polymerization DOI Creative Commons
Zhao Gao, Xuxu Xie,

Juan Zhang

и другие.

Nature Communications, Год журнала: 2024, Номер 15(1)

Опубликована: Дек. 30, 2024

Metastable supramolecular polymerization under kinetic control has recently been recognized as a closer way to biosystem than thermodynamic process. While impressive works on metastable systems have reported, the library of available non-covalent driving modes is still small and simple yet versatile solution highly desirable design for easily regulating energy landscapes aggregation. Herein, we propose coopetition-driven metastability strategy parallel/perpendicular aromatic stacking construct polymers derived from class monomers consisting lateral indoles core. By subtly increasing strength cores phenyl anthryl, parallel face-to-face stacked aggregates are competitively formed products, which spontaneously transform into thermodynamically favorable species through cooperativity perpendicular edge-to-face offset stacking. The slow kinetic-to-thermodynamic transformation could be accelerated by adding seeds realizing desired living polymerization. Besides, this accompanied time-dependent emission change red yellow employed dynamic cell imaging, largely avoiding background interferences. coopetition relationship different expected serve an effective towards pathway-controlled functional materials.

Язык: Английский

Процитировано

1