Visible-Light-Induced Markovnikov Hydroalkoxylation of α-Trifluoromethyl Alkenes with ortho-Diketones DOI

Qinlin Chen,

Rundong Fan,

Xuliang Deng

и другие.

The Journal of Organic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Дек. 6, 2024

We report, for the first time, a visible-light-promoted Markovnikov hydroalkoxylation of α-trifluoromethyl alkenes with 1,2-diketones. This transformation proceeded smoothly in presence tertiary amine (Et

Язык: Английский

Transition-metal-, oxidant- and additive-free multi-component synthesis of alkyl heteroaryl BCPs enabled by visible-light-induced phosphine-catalyzed halogen-atom transfer DOI
Jun Xu,

Yu Hong,

Ruiyuan Xu

и другие.

Organic Chemistry Frontiers, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

This study describes a pioneering visible-light-induced phosphine-catalyzed halogen-atom transfer (XAT) strategy that heralds new era in the difunctionalization of [1.1.1]propellane.

Язык: Английский

Процитировано

12
Photoinduced Triphenylphosphine and Iodide Salt Promoted Reductive Decarboxylative Coupling DOI Creative Commons
Jiaxin Wang, Ming‐Chen Fu,

Lu‐Yu Yan

и другие.

Advanced Science, Год журнала: 2024, Номер 11(12)

Опубликована: Янв. 17, 2024

Abstract The transient electron donor–acceptor (EDA) complex has been an emerging area in the photoinduced organic synthesis field, generating radicals without exogenous transition‐metal or dye‐based photoredox catalysts. catalytic platform to form suitable photoactive EDA complexes for photochemical reduction reactions remains underdeveloped. Herein, a general reductive alkylation via strategy is described. A simple yet multifunctional system, triphenylphosphine and iodide salt, promotes decarboxylative hydroalkylation, defluorinative of trifluoromethyl alkenes, access alkanes gem ‐difluoroalkenes. Moreover, hydroalkylation can be applied more kinds electron‐deficient alkenes as Giese addition reaction.

Язык: Английский

Процитировано

9
Visible light-promoted defluorinative alkylation/arylation of α-trifluoromethyl alkenes with thianthrenium salts DOI
Yue Zhang, Jianyou Mao, Zhihong Wang

и другие.

Green Chemistry, Год журнала: 2024, Номер 26(17), С. 9371 - 9377

Опубликована: Янв. 1, 2024

Defluorinative alkylation and arylation between thianthrenium salts α-trifluoromethyl alkene to afford gem -difluoroolefins by easily recycling thianthrene under visible light irradiation free of metal photocatalyst.

Язык: Английский

Процитировано

8
A Catalyst- and Thiol-Free Protocol for Arene C–H Thioetherification via Photoactive Electron Donor–Acceptor Complexes DOI
Ang Gao,

He-Xiang Liu,

Yanan Zhou

и другие.

Green Chemistry, Год журнала: 2025, Номер 27(8), С. 2286 - 2292

Опубликована: Янв. 1, 2025

We present a catalyst- and thiol-free protocol for arene C–H thioetherification under visible light irradiation.

Язык: Английский

Процитировано

0
Hydroazidation of trifluoromethyl alkenes with trimethylsilyl azide enabled by organic photoredox catalysis DOI

Yutao Shi,

Yuliang Zhang, Xiaochen Ji

и другие.

Chemical Communications, Год журнала: 2024, Номер 60(60), С. 7741 - 7744

Опубликована: Янв. 1, 2024

A mild hydroazidation of trifluoromethyl alkenes with trimethylsilyl azide through organic photoredox catalysis was developed, delivering a series valuable β-CF 3 -azides exclusive selectivity.

Язык: Английский

Процитировано

1
Visible-light-induced hydroxycarboxylation of α-trifluoromethylstyrenes to construct densely functionalized α-CF3 tertiary alcohols DOI

Min-Ming Lu,

Ning Deng, Shiyu Li

и другие.

Green Chemistry, Год журнала: 2024, Номер 26(15), С. 8694 - 8700

Опубликована: Янв. 1, 2024

Visible-light-induced hydroxycarboxylation of α-trifluoromethylstyrenes under an air atmosphere was developed to construct densely functionalized α-CF 3 tertiary alcohols.

Язык: Английский

Процитировано

1
Chemodivergent alkylation of trifluoromethyl alkenes via photocatalytic coupling with alkanes DOI Creative Commons
Pol Martínez-Balart, Álvaro Velasco‐Rubio, Sergio Barbeira-Arán

и другие.

Green Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

A photocatalytic methodology for the chemodivergent direct cross-coupling of simple alkanes with trifluoromethyl alkenes that enables selective formation gem -difluoroalkenes and is presented.

Язык: Английский

Процитировано

1
Facile synthesis of propargylamines by metal-free doubly decarboxylative coupling DOI Creative Commons

Junduo Hu,

Xiaofan Shi, Liliang Huang

и другие.

RSC Sustainability, Год журнала: 2024, Номер 2(9), С. 2626 - 2631

Опубликована: Янв. 1, 2024

A sustainable and catalyst-free strategy has been developed for the synthesis of propargylamines by a three-component doubly decarboxylative coupling reaction.

Язык: Английский

Процитировано

0
Visible-Light-Induced Markovnikov Hydroalkoxylation of α-Trifluoromethyl Alkenes with ortho-Diketones DOI

Qinlin Chen,

Rundong Fan,

Xuliang Deng

и другие.

The Journal of Organic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Дек. 6, 2024

We report, for the first time, a visible-light-promoted Markovnikov hydroalkoxylation of α-trifluoromethyl alkenes with 1,2-diketones. This transformation proceeded smoothly in presence tertiary amine (Et

Язык: Английский

Процитировано

0