Dramatically Enhancing Multiphoton Harvesting Metal–Organic Frameworks for NIR-II Photocatalysis through Functional Regulation of Octupolar Molecules DOI

L. Y. Zhang,

Bo Li,

Wenyao Duan

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2024, Номер 16(36), С. 47348 - 47356

Опубликована: Сен. 2, 2024

The development of effective multiphoton absorption (MPA) materials for near-infrared (NIR) light-driven photocatalysis holds great significance. In this study, we incorporated two multibranched cyclometallated iridium(III) modules with varying degrees conjugation onto MPA-inert metal–organic frameworks (MOFs) to active MPA performance. Subsequently, the MOFs were further modified Co(II) and hyaluronic acid (HA) fabricate MINCH MISCH, respectively. By introducing octupolar molecules expanding conjugation, MISCH exhibited a larger cross section efficient NIR light improved carrier transfer, leading outstanding photocatalytic hydrogen production. Moreover, HA modification enabled achieve specific therapy cancer cells. This study provides valuable insights into constructing highly photocatalysis, presenting potential platform in tumor treatment.

Язык: Английский

Microenvironment‐Activatable Probe for Precise NIR‐II Monitoring and Synergistic Immunotherapy in Rheumatoid Arthritis DOI Open Access
Yuan Zhang, Dongfang Liu, Wenwen Chen

и другие.

Advanced Materials, Год журнала: 2024, Номер 36(48)

Опубликована: Окт. 6, 2024

Rheumatoid arthritis (RA) represents an insidious autoimmune inflammatory disorder that severely lowers the life quality by progressively destructing joint functions and eventually causing permanent disability, posing a serious public health problem. Here, advanced theranostic probe is introduced integrates activatable second near-infrared (NIR-II) fluorescence imaging for precise RA diagnosis with multi-pronged treatments. A novel molecular comprising long-wavelength aggregation-induced emission unit manganese carbonyl cage motif synthesized, which enables NIR-II activation concurrently releasing therapeutic carbon monoxide (CO) gas in inflamed microenvironment. This self-assembles into biocompatible nanoprobe, subsequently conjugated anti-IL-6R antibody to afford active-targeting ability of RA. The nanoprobe exhibits significant turn-on signal at lesion, enabling highly sensitive real-time monitoring. combination ROS scavenging, on-demand CO release, IL-6 signaling blockade results potent effect synergistic immunomodulation impact, significantly alleviating symptoms preventing destruction. research introduces paradigm development high-performance, strategies facilitate detection enhanced treatment RA-related diseases.

Язык: Английский

Процитировано

19

Endogenous Melanin and Hydrogen‐Based Specific Activated Theranostics Nanoagents: A Novel Multi‐Treatment Paradigm for Rheumatoid Arthritis DOI Creative Commons

Lin Chen,

Mingxin Zhao, Weiwei Kang

и другие.

Advanced Science, Год журнала: 2024, Номер 11(25)

Опубликована: Апрель 26, 2024

Abstract Rheumatoid arthritis (RA) is a systemic autoimmune disorder characterized by excessive proliferation of rheumatoid synovial fibroblasts (RASFs) and accumulation inflammatory cytokines. Exploring the suppression RASFs modulation RA microenvironment considered comprehensive strategy for RA. In this work, specifically activated nanoagents (MAHI NGs) based on hypoxic weakly acidic are developed to achieve second near‐infrared fluorescence (NIR‐II FL)/photoacoustic (PA) dual‐model imaging‐guided multi‐treatment. Due optimal size, MAHI NGs passively accumulate in diseased joint region undergo rapid responsive degradation, precisely releasing functionalized components: endogenous melanin‐nanoparticles (MNPs), hydrogen gas (H 2 ), indocyanine green (ICG). The released MNPs play crucial role ablating within through photothermal therapy (PTT) guided accurate PA imaging. However, regional hyperthermia generated PTT may exacerbate reactive oxygen species (ROS) production response following cell lysis. Remarkably, under microenvironment, controlled release H exhibits precise synergistic antioxidant anti‐inflammatory effects with MNPs. Moreover, ICG, dye currently approved clinical use, possesses excellent NIR‐II FL imaging properties that facilitate diagnosis deep tissue diseases provide right time‐point PTT.

Язык: Английский

Процитировано

6

Optimized indocyanine green nanopreparations for biomedical applications DOI
Wei Xia, Xiao‐Yun Ran,

Kunpeng Xie

и другие.

Coordination Chemistry Reviews, Год журнала: 2025, Номер 528, С. 216422 - 216422

Опубликована: Янв. 2, 2025

Язык: Английский

Процитировано

0

Photoacoustic Imaging in Inflammatory Orthopedic Diseases: Progress toward Precise Diagnostics and Predictive Regulation DOI Creative Commons
Minli Huang, Haoyu Yu,

Rong-Yao Gao

и другие.

Advanced Science, Год журнала: 2025, Номер unknown

Опубликована: Фев. 28, 2025

Abstract With the intensification of aging issues, inflammatory orthopedic diseases almost occur in majority elderly people, which is becoming increasingly severe. Photoacoustic imaging (PAI) a non‐invasive visualization technique for clear diagnosis inflammation areas through detecting acoustic signals generated by laser irradiation. The combination “light input” and “acoustic output” provides unprecedented scalability as well high penetration depth resolution. This new technology can also present more anatomical information feedback status activity diseases. Especially imaging, this effectively supplement current clinical methods diagnosis, staging, monitoring pathophysiological processes. rapid development these technologies, goals precise predictive regulation, ultimately personalized treatment strategies are realistic. Herein, article introduces various inflammations related applications. It covers types PA nanoprobes their research progress inflammation, potential applications PAI aspects. review discusses recent researches emerging translational prospects future challenges transformation.

Язык: Английский

Процитировано

0

Bone-Targeted Novel Catalase Nanocapsules for Effective Treatment of Rheumatoid Arthritis DOI

Qian He,

Bangliu Zhao,

Jie Kang

и другие.

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0

Dramatically Enhancing Multiphoton Harvesting Metal–Organic Frameworks for NIR-II Photocatalysis through Functional Regulation of Octupolar Molecules DOI

L. Y. Zhang,

Bo Li,

Wenyao Duan

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2024, Номер 16(36), С. 47348 - 47356

Опубликована: Сен. 2, 2024

The development of effective multiphoton absorption (MPA) materials for near-infrared (NIR) light-driven photocatalysis holds great significance. In this study, we incorporated two multibranched cyclometallated iridium(III) modules with varying degrees conjugation onto MPA-inert metal–organic frameworks (MOFs) to active MPA performance. Subsequently, the MOFs were further modified Co(II) and hyaluronic acid (HA) fabricate MINCH MISCH, respectively. By introducing octupolar molecules expanding conjugation, MISCH exhibited a larger cross section efficient NIR light improved carrier transfer, leading outstanding photocatalytic hydrogen production. Moreover, HA modification enabled achieve specific therapy cancer cells. This study provides valuable insights into constructing highly photocatalysis, presenting potential platform in tumor treatment.

Язык: Английский

Процитировано

1